• Computers and Concrete
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• v.19 no.6
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• pp.641-649
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• 2017

The discovery of the Interfacial Transition Zone (ITZ) by Farran in 1956 initiated a new era in the study of the behaviour of concrete. Acknowledged as the weak link, this ITZ was studied extensively, numerically as well as experimentally. While the complementary experimental tests illustrated the visual behaviour of this specimen under increasing monotonic compression loading, a perfect bond within the ITZ has also been studied by using finite element analysis for comparison purposes. Finite element analysis was used to evaluate the degree of correctness and precision of the proposed ITZ model. This paper discusses the use of the cutoff bar in finite element modeling, representing the ITZ of a single aggregate (inclusion) in a mortar matrix. Experiments were conducted to investigate the influence of the ITZ model on the single inclusion specimen's strength. The model was tested for some inclusions that varied in dimension and shape. The effect of inclusion shape on the stress concentrations of the specimens was examined. The aim of this research work is to propose a simple yet accurate ITZ model to be used in the commercially available finite element software packages.

• The Journal of the Korea Contents Association
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• v.15 no.7
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• pp.428-435
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• 2015

When I examined the corporate financing statistics in Korea, I have recognized that there are several trends of them. First, large enterprises use bank loan and direct financing like corporate bond as debt. Second, small and medium companies mainly use bank loan only. So I argue that there is sample selection bias in corporate debt choice and using sample selection methodology is more adequate when analysing the behavior in corporate debt choice. Therefore I have tested panel sample selection model, using the listed korean firm data from 1990 to 2013 and I have found that the panel sample selection model is appropriate.

• Computers and Concrete
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• v.8 no.1
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• pp.1-22
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• 2011

A numerical model that can simulate the nonlinear behavior of ultra high strength fiber-reinforced concrete (UHSFRC) structures subject to monotonic loadings is introduced. Since engineering material properties of UHSFRC are remarkably different from those of normal strength concrete and engineered cementitious composite, classification of the mechanical characteristics related to the biaxial behavior of UHSFRC, from the designation of the basic material properties such as the uniaxial stress-strain relationship of UHSFRC to consideration of the bond stress-slip between the reinforcement and surrounding concrete with fiber, is conducted in this paper in order to make possible accurate simulation of the cracking behavior in UHSFRC structures. Based on the concept of the equivalent uniaxial strain, constitutive relationships of UHSFRC are presented in the axes of orthotropy which coincide with the principal axes of the total strain and rotate according to the loading history. This paper introduces a criterion to simulate the tension-stiffening effect on the basis of the force equilibriums, compatibility conditions, and bond stress-slip relationship in an idealized axial member and its efficiency is validated by comparison with available experimental data. Finally, the applicability of the proposed numerical model is established through correlation studies between analytical and experimental results for idealized UHSFRC beams.

• Journal of the Korean Chemical Society
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• v.67 no.5
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• pp.333-338
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• 2023

In this study, the H₂O reaction with SiO clusters was investigated using ab initio Monte Carlo simulations and density functional theory calculations. Three chemistry models, PBE1/DGDZVP (Model 1), PBE1/DGDZVP (Si atom), and aug-cc-pVDZ (O and H atoms), (Model 2) and PBE1/aug-cc-pVDZ (Model 3), were used. The average bond lengths, as well as the relative and reaction energies, were calculated using Models 1, 2, and 3. The average bond lengths of Si-O and O-H are 1.67-1.75 Å and 0.96-0.97 Å, respectively, using Models 1, 2, and 3. The most stable structures were formed by the H transfer from an H₂O molecule except for Si₃O₃-H₂O-1 cluster. The Si₃O₃ cluster with H₂O exhibited the lowest reaction energy. In addition, the Bader charge distributions of the Si_nO_n and (SiO)_n-H₂O clusters with n = 1-7 were calculated using Model 1. We determined that the reaction sites between H₂O and the SiO clusters possessed the highest fraction of electrons.

• Geotechnical Engineering
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• v.13 no.2
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• pp.155-168
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• 1997

Lattice girder is a new steel support developed in Europe for the replacement of an existing H-shaped steel set, which is installed after tunnel excavation. Lattice girder has the following several advantages : 1. Lattice girder minimizes the amount of shotcrete shadow which happens to occur behind a steel support. 2. A triangular shape of lattice girder makes shotcrete placed efficiently. 3. Lattice girder provides a good bond strength for shotcrete, which makes the composite structure of lattice girder and shotcrete behave monolithic, and therefore, the rock load can be supported effectively by the lattice girder system, This paper presents the results from a model wall test, a strength test for shotcrete shot on the model wall and a strength test for the bond between lattice girder and shotcrete. These tests proved that lattice-girder system is superior to H-shaped steel-set system concerning the shotcrete rebound rate, the developed shotcrete strength and the adhesion characteristics.

• Journal of the Korean Chemical Society
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• v.14 no.1
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• pp.1-4
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• 1970

The methyl group does not possess an unshared pair of electrons. But F.A. Matsen has introduced the concept of the methyl group as a Pseudo-heteroatom which contributes a pair of electrons to ${\pi}$ system. In this heteroatom model, A. Streitwieser et al have assumed that the electrons in a methyl group behave to their approximation as a single electron pair on a single atom. But the theoretical basis on the heteroatom model hyper-conjugation has not studied yet. In this paper, Linear combination of Bond orbital and group theory is used to investigate the theoretical basis for it.

• Restorative Dentistry and Endodontics
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• v.31 no.6
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• pp.415-426
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• 2006

In this study, the changes in the degree of conversion (DC) and the microtensile bond strength (MTBS) of self-etching adhesives to dentin was investigated according to the time after curing. The MTBS of Single Bond (SB, 3M ESPE, USA), Clearfil SE Bond (SE, Kuraray, Japan), Xeno-III (XIII, Dentsply, Germany), and Adper Prompt (AP, 3M ESPE, USA) were measured at 48h, at 1 week and after thermocycling for 5,000 cycles between 5$^{\circ}$C and 55$^{\circ}$C. The DC of the adhesives were measured immediately, at 48h and at 7 days after curing using a Fourier Transform Infra-red Spectrometer. The fractured surfaces were also evaluated with scanning electron microscope. The MTBS and DC were significantly increased with time and there was an interaction between the variables of time and material (MTBS, 2-way ANOVA, p = 0.018; DC, Repeated Measures ANOVA, p < 0.001). The low DC was suggested as a cause of the low MTBS of self-etching adhesives, XIII and AP, but the increase in the MTBS of SE and AP after 48h could not be related with the changes in the DC. The microscopic maturation of the adhesive layer might be considered as the cause of increasing bond strength.

• Restorative Dentistry and Endodontics
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• v.12 no.2
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• pp.45-53
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• 1987

The purpose of this study was to evaluate the tensile bond strength between composite resin and the human enamel. Three composite resin systems, two chemical (Clearfil Posterior, and Clearfil Posterior-3) and one light cure (Photo Clearfil-A), used with and without an intermediate resin (clearfil bonding agent), were evaluated under different amounts of load (10g, 200g and 200g for a moment) for in vitro tensile bond strength to acid-eched human enamel. Clinically intact buccal or lingual surfaces of 144 freshly extracted human permanent molars, embedded in acrylic were flattened with No #600 carborundum discs. Samples were randomly assigned to the different materials and treatments using a table of random numbers. Eight samples were thus prepared for each group(Table 2) these surfaces were etched with an acid etchant (Kurarey Co. Japan) in a mode of etching for 30 seconds, washing for 15 seconds, and drying for 30-seconds. During the polymerization of composite resin on the acid-etched enamel surfaces with and without bonding agent 10-gram, 200 gram and temporary 200 gram of load were applied. The specimens were stored in 50% relation humidity at $37^{\circ}C$ for 24 hours before testing. An universal Testing machine (Intesco model No. 2010, Tokyo, Japan) was used to apply tensile loads in the vertical directed (fig 5), and the force required for separation was recorded with a cross head speed of 0.25 mm/min and 20 kg in full scale. The results were as follow: 1. The tensile bond strength was much greater in applying a bonding agent than in not doing that. 2. The tensile bond strength of chemical cure composite resin was higher than that of light cure composite resin with applying on bonding agent on the acid-etched enamel. 3. In case of not applying a bonding agents on the acid-etching enamel, the highest tensile bond strength under 200 gram of load was measured in light cure composite resin. 4. The tensile bond strength under 200-gram of load has no relation with applying the bonding agent. 5. Under the load of 10-gram, There was significant difference in tensile bond strength as applying the bonding agent.

• Restorative Dentistry and Endodontics
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• v.17 no.2
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• pp.355-364
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• 1992

This is a study on the effect of the dentinal pretreatment method to the bond strength between dentin and glass ionomer cement. In this study, 196 human molar teeth with sound crown were used. The dentin surfaces of these teeth were exposed with wet trimmer and polished with # 800 Emory paper and teeth were divided into 7 groups according to the pretreatment agent and method. Each group has 4 subroups of the kinds of glass ionomers. The shear bond strength were measured by Instron Universal Testing machine model 1122. The data of the evaluations were then subjected to statistical analysis using one way ANOVA and the result were as follows : 1. In Durelon liquid 20 sec scrubbing & Vitrebond filling subgroup, shear bond strength was highest with measurements of 72.41(kg/$cm^2$) and in no pretreatment & Shofu lining cement filling subgroup, lowest with measurements of 4.77(kg/$cm^2$). 2. In no pretreatment group, statistical significant differences were found between the subgroups of G-C lining cement and Shofu lining cement. 3. In Ketac conditioner 20 sec scrubbing group, Vitrebond were bonded stronger than others, and in Ketac conditioner 10 sec passive contact group, it has the significant difference with other glass ionomers except G-C lining cement. 4. The subgroup og G-C dentin conditioner 20 sec scrubbing & G-C lining cement filling was bonded to dentin stronger than the subgroup of no pretreatment & Shofu lining cement. In G-C dentin conditioner groups, both of 10 sec passive contact and 20 sec scrubbing, Vitrebond has highest bond strength among the subgroups. 5. The subgroup of Durelon liquid 10 sec passive contact & G-C lining cement filling was bonded to dentin stronger than the subgroup of no pretreatment & Shofu lining cement. Also in both Durelon liquid groups, Vitrebond were bonded to dentin with the highest strength among the subgroups.

• Computers and Concrete
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• v.22 no.2
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• pp.167-182
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• 2018

The modeling of loss of bond between reinforcing bars (rebars) and concrete due to corrosion is useful in studying the behavior and prediction of residual load bearing capacity of corroded reinforced concrete (RC) members. In the present work, first the possibility of using different methods to simulate the rebars-concrete bonding, which is used in three-dimensional (3D) finite element (FE) modeling of corroded RC beams, was explored. The cohesive surface interaction method was found to be most suitable for simulating the bond between rebars and concrete. Secondly, using the cohesive surface interaction approach, the 3D FE modeling of the behavior of non-corroded and corroded RC beams was carried out in an ABAQUS environment. Experimental data, reported in literature, were used to validate the models. Then using the developed models, a parametric study was conducted to examine the effects of some parameters, such as degree and location of the corrosion, on the behavior and residual capacity of the corroded beams. The results obtained from the parametric analysis using the developed model showed that corrosion in top compression rebars has very small effect on the flexural behaviors of beams with small flexural reinforcement ratio that is less than the maximum ratio specified in ACI-318-14 (singly RC beam). In addition, the reduction of steel yield strength in tension reinforcement due to corrosion is the main source of reducing the load bearing capacity of corroded RC beams. The most critical corrosion-induced damage is the complete loss of bond between rebars and the concrete as it causes sudden failure and the beam acts as un-reinforced beam.