• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2005년도 제24회 춘계학술대회논문집
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• pp.106-111
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• 2005

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2-8wt.\% Y_{2}O_3$ ceramic coating during cyclic oxidation. $Al_{2}O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_{2}O_4 and Ni(Al,Cr)_{2}O_4$ during cyclic oxidation It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr,Al)_{2}O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• The Korean Journal of Ceramics
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• 제4권4호
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• pp.340-344
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• 1998

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2$-8wt.% $Y_2O_3$ ceramic coating during cyclic oxidation. $Al_2O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_2O_4$ and $Ni(Al, Cr)_2O_4$ during cyclic oxidation. It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr, Al)_2O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• KCI Concrete Journal
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• 제13권2호
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• pp.19-25
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• 2001

A simple expression to predict bond strength of reinforcing bars with rib deformation to the surrounding is derived for the case of splitting bond failure. Finite element analysis is used to model the confining behavior of concrete cover. The roles of the interfacial properties, specifically, the friction coefficient, cohesion, the relative rib area and the rib face angle are examined. Values of bond strength obtained using the analytical model are in good agreement with the bond test results from the previous studies. The analytical model provides insight into interfacial bond mechanisms and the effects of the key variables on the bond strength of deformed bars to concrete. Based on the comparison between the analytical results and the test results, the values of cohesion, coefficient of friction, and the effective rib face angle are proposed.

• Steel and Composite Structures
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• 제7권5호
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• pp.377-390
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• 2007

In the design of concrete filled composite columns, it is assumed that the load transfer between the steel tube and concrete core has to be achieved by the natural bond. However, it is important to investigate the mechanisms of shear transfer due to the possibility of steel-concrete interface separation. This paper deals with the contribution of headed stud bolt shear connectors and angles to improve the shear resistance of the steel-concrete interface using push-out tests. In order to determine the influence of the shear connectors, altogether three specimens of concrete filled composite column were tested: one without mechanical shear connectors, one with four stud bolt shear connectors and one with four angles. The experimental results showed the mechanisms of shear transfer and also the contribution of the angles and stud bolts to the shear resistance and the force transfer capacity.

• Computers and Concrete
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• 제16권3호
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• pp.449-466
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• 2015

This paper aims to study the local bond stress-slip behavior of reinforcing bars embedded in lightweight aggregate concrete (LWAC). The experimental variables of the local bond stress-slip tests include concrete strength (20, 40 and 60 MPa), deformed steel bar size (#4, #6 and #8) and coarse aggregate (normal weight aggregate, reservoir sludge lightweight aggregate and waterworks sludge lightweight aggregate). The test results show that the ultimate bond strength increased with the increase of concrete compressive strength. Moreover, the larger the rib height to the diameter ratio ($h/d_b$) of the deformed steel bars is, the greater the ultimate bond stress is. In addition, the suggestion value of the CEB-FIP Model Code to the LWAC specimen's ultimate bond stress is more conservative than that of the normal weight concrete.

• Steel and Composite Structures
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• 제42권2호
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• pp.191-207
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• 2022

Undoubtedly, the employment of direct bond interaction between steel and concrete is preceding the other mechanisms because of its ease of construction. However, the large scatter in the experimental data about the issue has hindered the efforts to characterize bond strength. In the following research, the direct bond interaction and bond-slip behavior of CFTs with circular cross-section were examined through repeated load-reversed push-out tests until four cycles of loading. The influence of different parameters including the diameter of the tube and the use of shear tabs were assessed. Moreover, the utilization of expansive concrete and external spirals was proposed and tested as ways of improving bond strength. According to the results section dimensions, tube slenderness, shrinkage potential of concrete, interface roughness and confinement are key factors in a natural bond. Larger diameters will lead to a considerable drop in bond strength. The use of shear tabs by their associated bending moments increases the bond stress up to eight times. Furthermore, employment of external spirals and expansive concrete have a sensible effect on enhancing bonds. Macro-locking was also found to be the main component in achieving bond strength.

• Structural Engineering and Mechanics
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• 제7권1호
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• pp.35-52
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• 1999

Realistic steel-concrete bond/slip relationships proposed in the literature are usually uniaxial. They are based on phenomenological theories of deformation and degradation mechanisms, and various pull-out tests. These relationships are usually implemented using different analytical methods for solving the differential equations of bond along the anchored portion, for particular situations. This paper justifies the concepts, and points out the assumptions underlying the construction and use of uniaxial bond laws. A finite element implementation is proposed using 2-D membrane elements. An application example on an interior beam-column joint illustrates the possibilities of this approach.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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• pp.546-551
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• 1997

New typology of failure mechanisms for uniform compression fields are presented based on the classical theory of plasticity, in particular th normality rule, and the limit theorem. The concrete is assumed as a rigid-perfectly plastic material obeying the modified Coulomb failure criteria with zero tension cut-off. The failure mechanisms are capable of explaining flexural types of crushing failure in uniaxial uniform compression stress fields which are called struts in truss models. The failure mechanisms consist of sliding failure along straight failure lines or hyperbolic failure curves and rigid body rotation. The failure mechanisms involving straight failure lines are explained by constant strain expansion in the first principal direction and rigid body rotation motion. The failure mechanisms presented are applied to the explanation of bond failure of bar combined with concrete crushing failure and flexural crushing failure of concrete.

• Smart Structures and Systems
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• 제13권4호
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• pp.685-709
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• 2014

Carbon nanotubes are due to their outstanding mechanical properties destined for a wide range of possible applications. Since the knowledge of the material behavior is vital regarding the possible applications, experimental and theoretical studies have been conducted to investigate the properties of this promising material. The aim of the present research is the calculation of mechanical properties and of the mechanical behavior of single wall carbon nanotubes (SWCNTs). The numerical simulation was performed on basis of a molecular mechanics approach. Within this approach two different issues were taken into account: (i) the nanotube geometry and (ii) the modeling of the covalent bond. The nanotube geometry is captured by two different approaches, the roll-up and the exact polyhedral model. The covalent bond is modeled by a structural molecular mechanics approach according to Li and Chou. After a short introduction in the applied modeling techniques, the results for the Young's modulus for several SWCNTs are presented and are discussed extensively. The obtained numerical results are compared to results available in literature and show an excellent agreement. Furthermore, deviations in the geometry stemming from the different models are given and the resulting differences in the numerical findings are shown. Within the investigation of the deformation mechanisms occurring in SWCNTs, the basic contributions of each individual covalent bond are considered. The presented results of this decomposition provide a deeper understanding of the governing deformation mechanisms in SWCNTs.

• Bulletin of the Korean Chemical Society
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• 제10권6호
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• pp.600-604
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• 1989

In order to find the rational methods for improving the thermal stability of subtilisin Carlsberg, the mechanisms of irreversible thermoinactivation of the enzyme were studied at $90^{\circ}C.$ At pH 4, the main process was hydrolysis of peptide bond. This process followed first order kinetics, yielding a rate constant of $1.26\;{\times}\;10^{-1}h^{-1}$. Hydrolysis of peptide bond of PMS-subtilisin occurred at various sites, which produced new distinct fragments of molecular weights of 27.2 KD, 25.9 KD, 25.0 KD, 22.3 KD, 19.0 KD, 17.6 KD, 16.5 KD, 15.7 KD, 15.0 KD, 13.7 KD, and 12.7 KD. Most of the new fragments originated from the acidic hydrolysis at the C-side of aspartic acid residues. However 25.0 KD, 15.7 KD, and 13.7 KD which could not be removed in purification steps stemmed from the autolytic cleavage of subtilisin. The minor process at pH 4 was deamidation at asparagine and/or glutamine residues and some extend of aggregation was also observed. However, the aggregation was main process at pH 7 with a first order kinetic constant of $16 h^{-1}.$ At pH 9, the main process seemed to be combination of deamidation and cleavage of peptide bond.