• 제목/요약/키워드: boiling point

검색결과 331건 처리시간 0.028초

한국형 지열발전 타당성 연구 (A Feasibility Study on Geothermal Power Plant in Korea)

  • 임효재;권정태;김금수;장기창
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.39-44
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    • 2009
  • Geothermal energy is the heat contained in the earth and its internal fluids. Geothermal energy is stored as sensible or latent heat. Supplied by both internal and external sources, it represents a vast supply which is only started to be tapped for generation of electric power. In general, this is natural dry or wet medium to high enthalpy steam at temperatures above $150^{\circ}C$. For some time, binary systems employing substances with a lower boiling point than water in a secondary circuit have been used to generate vapor for driving turbines at a lower temperature level. The utilization of binary plants and the possibility of production from enhanced geothermal systems can expand its availability on a worldwide basis. The geothermal electricity installed capacity is approaching the 10,000GW threshold. Geothermal energy is not present everywhere, but its baseload capability is a very important factor for its success.

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자동차용 가솔린과 디젤 연료의 증류특성에 관한 연구 (A Study on Distillation Property of Automotive Gasoline and Diesel Fuel)

  • 염광욱;김상진
    • 동력기계공학회지
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    • 제18권5호
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    • pp.11-15
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    • 2014
  • Currently, there are active researches being conducted on a new combustion technology that can reduce emission quantity while enhancing vehicle performance as well as Improving fuel quality. In a gasoline engine that uses petroleum, high volatility makes it easy to jump spark ignition and prevent knocking phenomenon that occurs inside an engine. In a diesel engine that uses diesel fuel, high volatility reduces combustion residues and toxic gas and is therefore good for protecting the environment. Therefore, for fuel used in a vehicle, volatility is an important factor that influences not only engine performance but also environmental protection. This research conducted a distillation experiment using gasoline and diesel fuel for vehicles produced by domestic oil companies. The test was conducted in accordance with the method of distillation experiment described in KS M ISO3405. In addition, it used the result of analysis from the experiment to examine visual distillation characteristics of each fuel and developed a formula based on distillation temperature.

건오징어 추출물의 유기산 조성에 관한 연구 (Studies on the Nonvolatile Organic Acids in the Extracts of Dried Squid)

  • 김동수;김영명;우상규
    • 한국식품영양과학회지
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    • 제19권4호
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    • pp.305-310
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    • 1990
  • 건조오정어의 추요 유기산생분올 조사하고 이들 성분의 추출용매와 추출시간에 따른 함량의 변화를 조사하였다. 건조오징어의 주요 유기산 성분은 lactic acid, pyroglutamic acid, succinic acid 및 citric acid였고 이들중 lactic acid와 pyrogluta­-mic acid가 전체 유기산의 85% 이상을 차지 하였다. 물로써 추출했을 때 추출 2시간에 310.1mg%로 가장 높았고 70% 에탄올로 추출했을 때 동일 추출시간에서 347.6mg%로 까장 높게 냐타났으며 그 이후에는 점차 감소하는 경향올 보였다. 한편 추출시간의 경과에 따라 천채척언 유기산의 총량은 다소 차이가 있었으나 개별 유기산의 조성비는 큰 차이가 없었다.

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복합고체절연물의 극저온 절연성능 평가를 위한 임펄스 내전압시험 (Impulse Tests for a Composite Solid Insulator for High Voltage Superconducting Power Applications)

  • 김우석;유승덕;현옥배;김혜림;임성우;양성은;김희선
    • Progress in Superconductivity
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    • 제13권1호
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    • pp.24-27
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    • 2011
  • High voltage insulation in cryogenic environment is one of big issues for development of superconducting power application, such as superconducting fault current limiter, transformer, transmission cable, and so on. We had proposed a composite solid insulator composed of plastics and polymer insulation sheets for a use of high voltage superconducting power applications. It is well known that the G10 FRP keeps its mechanical strength at very low temperature and the PPLP is very good insulator adopted as insulations for superconducting transmission cables. The composition of these two materials will show very good electrical and mechanical properties adequate for the insulation components of superconducting power applications, such as bushing, insulation barrier, and even for a cryostat. Dielectric strengths of prepared samples were measured at the temperature of boiling point of liquid nitrogen at atmospheric pressure, which will be presented in this paper to show a usefulness of this technique.

Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry

  • Kim, Eun-Kyoung;No, Myoung-Han;Koh, Jae-Suk;Kim, Sung-Whan
    • Mass Spectrometry Letters
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    • 제2권2호
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    • pp.41-44
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    • 2011
  • Molecular compositions of two types of heavy oil were studied using positive atmospheric pressure photoionization (APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Vacuum gas oil (VGO) was generated from vacuum distillation of atmospheric residual oil (AR), and slurry oil (SLO) was generated from catalytic cracking of AR. These heavy oils have similar boiling point ranges in the range of 210-$650^{\circ}C$, but they showed different mass ranges and double-bond equivalent (DBE) distributions. Using DBE and carbon number distributions, aromatic ring distributions, and the extent of alkyl side chains were estimated. In addition to the main aromatic hydrocarbon compounds, those containing sulfur, nitrogen, and oxygen heteroatoms were identified using simple sample preparation and ultra-high mass resolution FT-ICR MS analysis. VGO is primarily composed of mono- and di-aromatic hydrocarbons as well as sulfur-containing hydrocarbons, whereas SLO contained mainly polyaromatic hydrocarbons and sulfur-containing hydrocarbons. Both heavy oils contain polyaromatic nitrogen components. SLO inludes shorter aromatic alkyl side chains than VGO. This study demonstrates that APPI FT-ICR MS is useful for molecular composition characterization of petroleum heavy oils obtained from different refining processes.

친화막의 L-tryptophan 흡착특성 (Adsorption Characteristic of L-tryptophan of Affinity Membrane)

  • 변홍식;홍병표
    • 멤브레인
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    • 제18권3호
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    • pp.214-218
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    • 2008
  • 전기방사를 이용하여 polyethersulfone (PES)-bovin albumin serum (BSA) 단백질 친화막을 제조하였으며, 이때 전기방사에 의한 공정상의 문제점을 용해도가 높고, 끓는점이 높은 2,2,3,4,4,4-Hexafluoro-1-butanol (HFB)를 공용매로 사용함으로써 해결하였다. 또한 공용매는 최적의 온도, 습도 범위를 확대시켜줌으로써 친화막의 대량 생산이 용이하리라 생각한다. 제조된 친화막은 biuret test를 통하여 친화막의 색깔이 무색에서 보라색으로 변함으로써 PES 섬유 내 BSA가 존재함을 확인할 수 있었다. 완충용액의 조성 성분 중 dimethyl sulfoxide (DMSO)는 세척과정에서 BSA와 L-tryptophan사이의 해리를 제어함으로써 용출과정에서 비교실험보다 약 5배의 높은 용출량을 보여주었다.

Comparison between Head Space Gas Sampling and Purge & Trap Sampling in Water Analysis

  • Nagayanagi, Yutaka;Nakagawa, Katsuhiro;Saito, Yoshihiro;Kim, Poongzag
    • 분석과학
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    • 제8권4호
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    • pp.739-744
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    • 1995
  • The two main methods to prepare water samples for analyzing volatile organic compounds(VOC's) were investigated. One is the purge and trap(PT) method and another is the head space(HS) sampling method. Both methods were effective to transfer the low boiling point components from the water sample onto the capillary column. The cryo-focusing at the top of the main capillary column was an effective way to obtain the sharpness of the chromatographic peaks but could be avoided when a semi-wide bore column was used. The recovery from the same amount of the sample was better in PT than in HS but a larger sample volume in HS method could compensate the lower efficiency. Therefore PT is suitable to the analysis of drinking water where the very low concentration must be determined. HS is suitable to waste water analysis because of the easiness of the operation. The repeatability was good and similar in both methods. For the contamination of the former sample, both methods were tough and could be used without any problems. The matrix effect which could change the equilibrium parameters in HS method was find negligible in many components. The actual samples such as tap water and river water were analyzed with both methods concerning 16 components regulated in Korea.

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PVP의 전기방사 섬유 제조에서 용매에 따른 구조 변화 (Effect of Solvents on the Structure of Electrospun PVP Fiber)

  • 박주영;이인화
    • 공업화학
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    • 제19권5호
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    • pp.484-490
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    • 2008
  • 폴리비닐피로디온을 서로 다른 끓는점, 유전상수, 쌍극자모멘트를 갖는 다양한 용매(메탄올, 에탄올, 2-프로판올, 부탄올, 아세톤, 메틸렌클로라이드 및 DMF)에 용해시켜 전기방사를 시도하여 섬유의 특성을 연구하였다. 전기 방사된 폴리비닐피로디온은 방사용액의 점도, 전기전도도 및 표면장력에 영향을 받는다. 점도가 $0.114kg/m{\cdot}s$ 이상, 전기전도도는 1.02 mS/m 이상, 표면장력은 30.0 mN/m 이하에서 섬유가 형성되었다. 에탄올 용매계에서 폴리비닐피로디온의 평균직경은 인가전압이 10 kV에서 20 kV 증가시킴에 따라 1710에서 5454 nm까지 증가하였다.

함산소연료(Diglyme, DEE)와 EGR 방법을 이용한 간접분사식 디젤기관의 배기가스 배출 특성 (The Characteristics of Exhaust Emissions by using Oxygenated Fuels and EGR in IDI Diesel Engine)

  • 유경현;오영택
    • 한국자동차공학회논문집
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    • 제10권6호
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    • pp.108-116
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    • 2002
  • The diesel engine is one of the most effective transport options available in all sizes and covering a wide range of applications. But, many researchers developing the diesel engine are facing tough challenges in view of the increasingly lower emissions standards. Thus, this study will explore the possible fuel additive technology to further reduce the emissions from the IDI diesel engine. The purpose of this study is to investigate the effects of oxygenated fuels on the exhaust emissions and to attain a better trade-off relation between smoke and NOx in four cylinder diesel engine. Experiments were conducted with oxygenated fuels as an effective way to improve the combustion efficiency. Some of oxygenated fuel(Diglyme and DEE) were added to the conventional diesel fuel which had no an oxygen content. Also, EGR was adopted for reducing NOx without any strong adverse effects on other exhaust emissions. This study concluded that exhaust emissions in diesel engine could be reduced by adding the oxygenated fuels which had lower boiling point, and the combustion efficiency was also improved as the oxygen content in fuel increased.

고순도.미립 $TiO_2$분말 제조에 관한 연구 -고순도화 연구(I)- (Studies on Preparation of $TiO_2$Powder with Purity and Fine Particle -A Study of High Purifying(I)-)

  • 이미재;지미정;김환;이철태;최병현
    • 한국세라믹학회지
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    • 제37권10호
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    • pp.933-937
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    • 2000
  • 고기능성 전자재료용 TiO$_2$분말 및 박막제조에 사용되는 중간생성물인 TiCl$_4$는 99% 이상의 고순도가 요구된다. 고순도.미립의 TiO$_2$분말 및 TiCl$_4$는 황산법으로 제조한 저순도 TiO$_2$원료를 사용하여 염소화법으로 Ti-염화물 및 염화불순물로 제조한 후, 대부분의 염화불순물들은 3단계 과정을 거쳐 고순화 하였다. 대부분의 염화불순물은 분리.응축 및 분별증류로, VOCl$_3$는 mineral oil을 첨가하여 비등점을 변화시켜, 그리고 미량의 염화불순물은 열가수분해하여 침전시킨 후 유기용제 처리하여 제거하였다. 유기용제 처리는 TiO$_2$분말의 고순도화에 도움이 되었으며, 입자간의 응집을 적게 하여 TiO$_2$입자크기도 작아졌다. 또한 anatase에서 rutile 결정구조로의 전이온도도 낮아지는 부수적인 효과를 보였다.

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