• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.135-140
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• 2014

A bent-shape triazolyl derivative was synthesized via click chemistry, and its photophysical property was investigated in various solvents. In contrast to the invisible ultraviolet emission of other solutions, the chloroform solution exhibited a blue light emission at 460 nm. Furthermore, the blue fluorescence intensified as the UV exposure time at 365 nm increased. On the basis of $^1H$-NMR, pH paper, and acid-addition studies, we confirmed that chloroform was decomposed into HCl with the aid of the triazolyl derivative. The density functional theory calculations suggested that the eye-detectable blue fluorescence was attributed to an intramolecular charge transfer process of the protonated triazolyl derivative in the chloroform solution.

• 한국연소학회지
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• 제6권1호
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• pp.29-35
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• 2001

The surface flames in porous ceramic burner are experimentally characterized to investigate the effects of equivalence ratio and firing rates. The results show that the surface flames are classified into green, red radiant and blue surface flame as decrease of equivalence ratio. And each flame is maintained very stably and shows the same flame characteristics at any orientation of ceramic burner. Particularly the blue surface flame was found to be very stable at very lean equivalence ratio at 200 to $800\;kw/m^2$ firing rates. And the exhausted NOx was analysed to find out which flame has lower NOx emission. The blue surface flame showed the lowest NOx emission regardless of the location of burner since it sustained very stable at lean mixture ratio.

• 대한전자공학회논문지TE
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• 제39권1호
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• pp.9-15
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• 2002

본 논문은 청색 유기 EL 소자를 진공증착법으로 제작하여 그 특성을 분석하였다. 발광층 물질(A1q/sub 3/)에 게스트물질(Type I-TPB와 Type II-DPA)의 도핑농도(0.5∼2 wt%)를 변화시켜 청색발광소자를 제작하여 전기적, 광학적 특성을 조사하였다. Alq3에 도펀트의 농도를 증가함에 따라 청색에 해당하는 색좌표 점으로 이동하였다. Type I이 Type II의 경우보다 동작개시전압 및 구동전압이 낮게 나타났으며 휘도에서는 Type II가 밝게 나타났다. Alq/sub 3/에 DPA(2wt%)를 도펀트로 사용한 소자의 경우 인가전압 15V에서 휘도는 1282cd/m/sup 2/, 최대발광 파장은 476nm, 색좌표는(0.1273, 0.0672)으로 우수한 특성을 나타내었다.

• 경영과정보연구
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• 제33권3호
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• pp.93-104
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• 2014

본 연구는 탄소배출권거래제가 국내에서 시행되기 전에 EU ETS에서 거래되고 있는 탄소배출권 선물시장이 현물시장에 대해 가격발견기능이 존재하는 지에 대해 실증분석을 수행하였다. 동시에 서로 다른 거래소에서 거래되고 있는 선물시장과 현물시장 간의 정보교환이 효율적으로 이뤄지고 있는 지에 대해서도 알아보았다. 실증분석에 사용된 자료는 2009년 4월 1일부터 2012년 11월 30일까지 총 899개의 일일 자료이다. VECM의 오차수정계수를 이용하여 분석했을 때 탄소배출권 EUA 선물시장은 BlueNext 현물시장에 대해 가격발견기능이 존재하는 것으로 나타났다. 추가적인 검정에서도 GG와 Hasbrouck의 정보비율이 0.5보다 높은 값을 가지는 것으로 나타나서 EUA 선물시장은 현물시장에 대해 가격발견기능이 존재한다는 결론을 얻었다. 그리고 이러한 결과는 서로 다른 거래소에서 거래되더라도 탄소배출권과 관련된 정보 교환이 효율적으로 이뤄지고 있음을 알 수 있다.

• 한국재료학회지
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• 제32권11호
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• pp.449-457
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• 2022

Halide perovskites are emerging materials for next-generation display applications, thanks to their narrow emission linewidth and band gap tunability, capable of covering the entire range of visible light. Despite their short period of research, perovskite light emitting diodes (PeLEDs) have shown rapid progress in device external quantum efficiency (EQE) in the near-infrared (NIR), red, and green emission wavelengths, and the record EQE has exceeded over 20 %. However there has been limited progress with blue emission compared to the red and green counterparts. In this review, the current status and challenges of blue PeLEDs are introduced, and strategies to produce spectrally stable blue PeLEDs are discussed. The strategies include 1) a mixed halide system in the form of 3-dimensional (3D) perovskites, 2) colloidal perovskite nanocrystals and 3) low dimensional perovskites, known as quasi-2D perovskites. In the mixed halide system, previous reports based on the compositional engineering of 3D perovskites to reduce spectral instability (i.e., halide segregation) will be discussed. Since spectral instability issue originate from the mixed halide composition in perovskites, the two other strategies are based on enlarging the band gap with a single halide composition. Finally, the prospects for each strategy are discussed, for further improvement in spectrally stable blue PeLEDs.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.820-822
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• 2009

Tandem white organic light emitting diodes (WOLEDs) are fabricated by using a transparent interconnecting layer of Al:LiF composite/molybdenum oxides ($MoO_3$). We demonstrate two types of tandem WOLEDs consisting of two color emissions (red and blue emission) and three color emissions (red, green and blue emission). Tandem WOLED consisting of three color emission shows higher external quantum efficiency and current efficiency.

• Bulletin of the Korean Chemical Society
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• 제35권2호
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• pp.513-517
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• 2014

Two donor-acceptor-donor monomers such as 3,5-bis(4-bromophenyl)-1,2,4-oxadiazole (BOB) and 3,5-bis(5-bromothiophen-2-yl)-1,2,4-oxadiazole (TOT) incorporating electron transporting and hole blocking 1,2,4-oxadiazloe moiety were copolymerized with light emitting fluorene derivative via Suzuki polycondensation to afford two new polymers, PFBOB and PFTOT, respectively. The optical studies for polymers PFBOB and PFTOT revealed that the band gaps are 3.10 eV and 2.72 eV, respectively, and polymer PFBOB exhibited a deep-blue emission while polymer PFTOT showed blue emission in chloroform and as thin film. The photoluminescence quantum efficiencies (${\Phi}_f$) of polymers PFBOB and PFTOT in chloroform calculated against highly blue emitting 9,10-diphenylanthracene (DPA, ${\Phi}_f=0.90$) were 1.00 and 0.44, respectively.

• 한국산림과학회지
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• 제99권5호
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• pp.750-754
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• 2010

Among the environmental conditions employed in micropropagation, light quality plays an important role in growth, specially morphogenesis and photosynthesis. The effect of radiation quality (350-740 nm) on the development and growth of zygotic embryos and in vitro plantlets of open-pollinated chestnut (Castanea crenata S. et Z.) were studied. Two types of explants were exposed for 4 weeks to cool white (W, as control), monochromatic red (R, peak emission 650 nm), monochromatic blue (B, peak emission 440 nm), red+blue (R+B, 1:1), or red+far-red (R+Fr, 1:1, far-red peak emission 720 nm) radiation from a light-emitting-diode (LED) system. While the zygotic embryos showed positive photoblastic behavior, their germination was inhibited by blue radiation. Hypocotyl elongation and root development were promoted by red radiation. The emergence of primary leaf and its expansion were faster under blue than under red radiation. In the plantlets, red and red+far-red radiation significantly increased the formation and growth of the root, whereas blue light reduced rooting. Therefore, radiation quality appears to influence some steps in the development of zygotic embryos and plantlets in the chestnut.

• 한국전기전자재료학회논문지
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• 제19권6호
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• pp.568-573
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• 2006

We have synthesized new blue light emitting random copolymers, poly(9,9'-n-dioctylfluorene-co-perfluorobenzene-1,4-diyl)s (PFFBs), via Ni(0)-mediated coupling reactions. The weight-average molecular weights ($M_w$) of the PFFB copolymers ranged from 9,000 to 15,000. The PFFB copolymers dissolved in common organic solvents such as THF and toluene. The PL emission peaks of the PFFB copolymers were at around 420, 440, and 470 nm. EL devices were fabricated in ITO/PEDOT/polymer/Ca/Al configurations using these polymers. These EL devices were found to exhibit pure blue emission with approximate CIE coordinates of (0.15, 0.11) at $100cd/m^2$. The blue emissions of these devices might be due to the restriction of the polymer chains to aggregation by introducing of the highly electronegative fluorine moieties. The maximum brightnesses of the PFFB copolymer devices ranged from 140 to $3600cd/m^2$ with maximum efficiencies from 0.2 to 0.6 cd/A. The enhanced efficiency of the PFFB (8/2) copolymer device results from the inhibition of excimer formation by the introduction of the electronegative fluorine moieties into the copolymers.

• Journal of Advanced Marine Engineering and Technology
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• 제29권7호
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• pp.795-800
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• 2005

The optical properties of $ZnS_{y}Se_{1-x-y}:Te_x\;(x\;<\;0.08,\;y\∼0.11$) alloys grown by molecular beam epitaxy (MBE) have been investigated by photoluminescence (PL) and PL-excitation (PLE) spectroscopy. Good optical properties and high crystal quality were established with lattice match condition to GaAs substrate. At room temperature, emission in the visible spectrum region from blue to green was obtained by varying the Te content of the ZnSSe:Te alloy. The efficient blue and green emission were assigned to $Te_{1}$Tel and $Te_{n}$ (n$\geq$2) cluster bound excitons, respectively. Bright blue (462 nm) and green (535 nm) light emitting diodes (LEDs) have been developed using ZnSSe:Te system as an active layer.