• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.465-465
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• 2008

Conjugated polymers have attracted much scientific and technological research interest during the past few decades because of their potential use such as polymer light-emitting diodes (PLEDs).1,2 Particularly, lots of phenylene-based polymers such as polyfluorene and its derivatives have been synthesized because of their high photoluminescence quantum efficiencies and thermal stabilities. However, troublesome long wavelength emission in polymer film of polyfluorenes on heating during device formation or operation has been the crucial problem for practical applications. The source of the long wavelength emission was initially believed to be solely due to excimer emission as a result of polymer aggregation. It has also recently been correlated with emissions from ketonic defects in the fluorene units. Many efforts have been made to reduce the tendency to red-shifted emission. Here, we report for the first time the design and synthesis of novel 9,9-spiro bifluornene-based polymers containing heteroatoms such as N, S in its molecular skeleton. Especially, the 9,9-spiro bifluornene-based polymers containing N atom showed stable blue electroluminescence, which did not show spectral change upon thermal annealing.

• 한국전기전자재료학회논문지
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• 제15권5호
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• pp.429-434
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• 2002

In this paper, multiheterostructure white organic light-emitting device was fabricated by vacuum evaporation. The structure of white organic light-emitting device is ITO/CuPc/TPD/DPBi:DPA/$Alq_3/Alq_3$:DCJTB/BCT/$Alq_3$/Ca/Al. Three primary colors are implemented with DPVBi, Alq$_3$and DCJTB. The maximum EL wavelength of the fabricated white organic light-emitting device is 647nm. And the CIE coordinate is (0.33, 0.33) at 13 V. In the fabrication of white organic light-emitting devices with DCJTB, $Alq_3$, DPVBi, the EL spectrum has two peaks at 492nm, 647nm. Two peaks appeared because the blue light is combined with green light. The maximum wavelength of red light is not changed with applied voltage. After voltage applied, for the first time, the electrons met the holes in the red emission layer and emitted red light. And then the electrons moved to the green emission layer, and blue emission layer continuously. Finally, when all of the emission layer activated, the white light is emitted.

• 한국우주과학회:학술대회논문집(한국우주과학회보)
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• 한국우주과학회 1998년도 한국우주과학회보 제7권1호
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• pp.20.1-20
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• 1998

No Abstract.See Full-text

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제51권1호
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• pp.1-4
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• 2002

To obtain the blue emission of powder electroluminescent device, the emission properties of ZnS:Cu were estimated by the variation of applied frequency and the addition of dye to ZnS:Cu phosphor. The variation of applied frequency was from 400 to 4kHz and the addition ratio of dye was from 0 to 5 weight percent respectively. The increment of applied frequency made that emission peaks were shifted from 500.5nm and 460nm at 400Hz to 490nm and 450nm at 4kHz. CIE coordinate system was shifted from x=0.1647, y=0.3711 at 400Hz to x=0.1543, y=0.1856 at 4kHz. On the basis of applied voltage 100V, 400Hz, the increment of addition ratio of dye also made that emission peak was shifted from 505nm(0wt%) to 490nm(5wt%) and the CIE coordinate system was shifted from x=0.1647, y=0.3711(0wt%) to x=0.1334, y=0.2363 (5wt%). The brightness was increased from 60 cd/$m^2$(400Hz) to 174 cd/$m^2$(4kHz) with increment of frequency. When the addition ratio of dye was above 1wt%, the brightness was decreased below 42% of initial brightness and changed from 60 cd/$m^2$(0wt%) to 20.84 cd/$m^2$(5wt%).

• 한국진공학회지
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• 제21권3호
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• pp.164-170
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• 2012

청색 발광다이오드(LED) InGaN/GaN의 방사 피크 파장에 따른 LED 소자의 성능 저하를 광학적 및 전기적 특성을 고려하여 조사하였다. 방사 피크 파장이 437~452 nm인 LED 소자에 전류를 각각 60 mA, 75 mA, 그리고 90 mA로 구동하여 장시간 동안 스트레스를 주었다. 형광체의 유무에 따라서 LED 소자의 광 감쇠 특성을 관측하였다. 형광체가 없는 소자의 광 감쇠 특성은 피크 파장이 단파장일수록 급속하게 떨어진다. 형광체가 있는 소자는 형광체가 없는 것보다 감쇠 특성이 둔감해진다. 전기적 특성은 방사 피크 파장에 의존하지 않고, 스트레스 시간에 따른 LED의 내부 저항이 서서히 증가하는 현상으로 나타난다. 피크 파장에 따른 외형변화는 동일 전류 조건에서 단파장일 때 열화현상이 심하게 발생한다. 이는 청색 발광다이오드에서 발생한 빛의 파장이 단파장영역으로 갈수록 칩 외의 재료에서 단파장 광 흡수가 증가하여 열화현상이 가속화되는 것으로 분석된다. 따라서 LED 소자의 장수명을 얻기 위해서는 청색 칩의 방사 피크 파장과 소자재료의 광 열화해석이 중요하다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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• pp.129-130
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• 2000

The emission color stability of poly(fluorene) derivatives upon thermal annealing or passage of current in an electroluminescent device is affected by the structure of the main chain polymer unit and particularly by the polymer chain end substituents. Proper attention to these features leads to colorfast blue emission in both photo- and electoluminescence. Furthermore, the spectral emission characteristics can be tuned by the incorporation of various comonomers. Preliminary single layer device studies validate the potential utility of poly(fluorene) homo and copolymers for OLED applications.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.435-438
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• 2008

We demonstrated the efficient blue organic light-emitting diodes (OLEDs) by employing diarylamino-fluorene derived blue fluorescent molecules as dopants. Among those, a device exhibited blue emission with the luminous efficiency of 11.2 cd/A at $20\;mA/cm^2$, the external quantum efficiency of 9.7% at $20\;mA/cm^2$, and the $CIE_{x,y}$ coordinates of (x=0.163, y=0.259) at 8V.

• 한국전기전자재료학회논문지
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• 제22권4호
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• pp.323-326
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• 2009

We have developed blue-emitting phosphorescent organic light emitting diodes (OLEDs) using 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) and tris (8-quinolinolato)aluminum ($Alq_3$) electron transport layers. As blue dopant and host materials, bis[(4,6-di-fluorophenyl)-pyridinate-N,C2']picolinate (FIrpic) and N,N'-dicarbazolyl-3,5-benzene (mCP) were used, respectively. The driving voltage, current efficiency and emission characteristics of devices were investigated. While the driving voltage was about $1{\sim}2$ V lower in the device with an $Alq_3$ layer, the current efficiency was about 66 % higher in the device with BCP electron transport layer. the blue phosphorescent OLED with BCP layer exhibited higher purity of color, resulting from a relatively weak electroluminescence intensity at 500 nm.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.775-778
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• 2009

Novel blue host material, 4,4'-(dinaphthalen-2-yl)-1,1'-binaphthyl (DNBN), was designed and synthesized for OLEDs. In order to test the electroluminescent properties of DNBN, DNBN was used as the host materials for a blue emitter, PCVtPh. The device exhibited deep-blue emission with the CIEx,y coordinates (x=0.15, y=0.08) at 8.0 V, a luminous efficiency of 1.66 cd/A, a power efficiency of 0.77 lm/W and an external quantum efficiency of 2.30 % at 20 mA/$cm^2$, respectively.

• 한국재료학회지
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• 제28권6호
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• pp.355-360
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• 2018

$LuNbO_4:0.2Yb^{3+},xTm^{3+}$ powders were prepared using a solid-state reaction process. The effects of the amount of Tm on up-conversion(UC) and down-conversion(DC) luminescence properties are investigated. X-ray diffraction patterns confirm that $Yb^{3+}$ and $Tm^{3+}$ ions are successfully incorporated into Lu sites. Under 980 nm excitation, the UC spectra of the powders predominantly exhibit strong near-infrared emission bands that peak at 805 nm, whereas weak 480 nm emission bands are observed as well. The emission bands are assigned to the $^1G_4{\rightarrow}^3H_6$ (480 nm) and 3 $^3H_4{\rightarrow}^3H_6$ (805 nm) transitions of the $Tm^{3+}$ ions via an energy transfer from $Yb^{3+}$ to $Tm^{3+}$; two- and three-photon UC processes are responsible for the 805 and 480 nm emissions, respectively. The DC emission spectra exhibit blue emission ($^1D_2{\rightarrow}^3F_4$) of $Tm^{3+}$ at 458 nm. The amount of Tm affects the emission intensity with the strongest emissions at x = 0.007 and 0.02 for the UC and DC luminescence, respectively. The results demonstrate that $LuNbO_4:Yb^{3+},Tm^{3+}$ phosphors are suitable for bio-applications.