• Title/Summary/Keyword: blending effect

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Effect of PFO/Coal-tar Blending Ratio on Yield and Physical Properties of Pitch-based Activated Carbon (열분해유/콜타르 혼합비가 피치계 활성탄의 수율 및 물성에 미치는 영향)

  • Tae Ung Yoo;Sang Wan Seo;Ji Sun Im;Soo Hong Lee;Woo Jin Song;Seok Chang Kang
    • Applied Chemistry for Engineering
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    • v.35 no.2
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    • pp.107-114
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    • 2024
  • In order to produce high-yield pitch-based activated carbon, pitch was synthesized by blending pyrolysis fuel oil (PFO) and coal-tar. Pitch was synthesized by varying the amount of coal-tar from 0~20% compared to PFO and reacting at 380~420 ℃ for 3 h. The synthesized pitch had a softening point between 80 and 260 ℃, and yields ranged from 10 to 40%. At all synthesis temperatures, as the coal-tar blending ratio increased, the yield increased and the softening point decreased. After considering the selected pitches (softening points: 230~260 ℃), pitches containing coal-tar were more volatile at a low boiling point and had a higher residual carbon content. This is a difference in the composition of coal-tar and PFO, and it was con- firmed that coal-tar has a lot of aromatics and PFO has a lot of aliphatics. The selected pitch was heated to 950 ℃ in a tubular reactor and physically activated with steam for 1 hour. Activated carbon containing coal-tar showed higher yield and microporosity compared to only PFO. In this study, the effect of increasing activated carbon yield by blending pitch raw materials was confirmed, and the physical activation characteristics according to the coal-tar mixing ratio were examined.

Linear Free Energy Relationship on the Chemical Shift of Imidoyl Proton in N-benzylideneaniline Derivatives by PMR Spectrometry (核磁氣 共鳴分光法에 義한 N-Benzylideneaniline 誘導體중 Imidoyl Proton 의 Chemical Shift 에 미치는 自由에너지 關係)

  • Nack Do Sung;Cheon Kyu Park;Moon kyu Park;Ki Sung Kwon;Kim, Tae Rin
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.277-282
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    • 1985
  • The effects of linear free energy relationship (LFER) on the imidoyl proton (H${\alpha}$)-substituent chemical shift (SCS) in case of varying para-substituted C-phenyl group in N-benzylideneaniline derivatives were studied. The H${\alpha}$-SCS values and LFER parameters such as ${\sigma}$,${\sigma}^+$, ${\sigma}_I$,${\sigma}_R, F and R were applied to the Hammett, Okamoto-Brown, and Taft, Swain-Lupton's dual substituents parameter (DSP) equations. The results were: (1) the blending coefficient values, ${\lambda}$ = 2.8∼3.2, it's means that the resonance effect (R) was larger than inductive effect (I) and field effect (F), and (2) the values of percent resonance and percent field effects were %R = 66.6 and %F = 33.4, respectively, yielding the ratio of resonance effect (R) to field effect (F) of 2 : 1.

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Preparation of Semi-Solid Apple-Based Baby Food (반고형 사과 이유보충식의 제조)

  • Sohn, Kyung-Hee;Kim, Mi-Ran;Yim, Sung-Kyoung;Park, Hyun-Kyung;Park, Ok-Jin
    • Korean Journal of Food Science and Technology
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    • v.34 no.1
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    • pp.43-50
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    • 2002
  • To develop commercial semi-solid apple baby food, the physicochemical characteristics of apple puree in relation to different preparing methods and the effect of the addition methods of ascorbic acid on browning reaction were investigated. The preparing methods were classified into 3 groups by initial heating treatment: no heating (A), steaming at $120^{\circ}C$ (B), and blancing at $100^{\circ}C$ (C). The viscosity of tested apple puree was $2,600{\sim}5,856\;cp$, and contents of anhydrogalaturonic acid (AGA) and neutral sugar ranged $4.15{\sim}11.92\;mg%$ and $6.18{\sim}10.65\;mg%$, respectively. Among free sugars tested, level of fructose was the highest $(5.43{\sim}8.87%)$, followed by glucose $(2.11{\sim}4.23%)$, sucrose $(1.64{\sim}2.94%)$, in that order. Since small amounts of ascorbic acid were detected $(1.54{\sim}1.83\;mg%)$, it seemed to be lost by heating process in preparing of apple puree. For apple puree A, its lightness was lower and redness was higher than those of apple puree B and C. Its degree of browning of apple puree was so high that sodium ascorbic acid was added as a antibrowning agent. Puree had low sensory score and nutrient quality. The adding methods of ascorbic acid were classified into 4 groups by adding time: dipping, blending (2), heating (3), and blending + heating (4). Considering color and preference evaluation, preparing method B and adding method 2 showed the highest inhibitory activity on apple puree browning and desirable color for retort baby food. After retort sterilization, the viscosity of apple baby food was decreased from 3,477 cp to 2,294 cp, thiamin was destroyed completely, and the contents of riboflavin and ascorbic acid were decreased 41% and 21%, respectively. However, contents of free sugar and free amino acid and sensory parameter were not influenced by retort sterilization. In overall, the preparing method B-adding method 2 was a good processing condition for the retort apple baby food.

Reality Enhancement Method of Virtual Reality Based Simulator by Mutual Synergy Effect between Stereoscopic Image and Three-Dimensional Sound (입체영상과 3차원음향의 상호 상승효과에 의한 가상현실기반 시뮬레이터 현실감 증대방법)

  • Yim, Jeong-Bin;Kim, Hyeon-Ra
    • Journal of Navigation and Port Research
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    • v.27 no.2
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    • pp.145-153
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    • 2003
  • The presence-feeling enhancement method of a Virtual Reality (VR) simulator is proposed in this paper. The method is to increase realistic human feeling by mutual synergy effect between stereoscopic image and three-dimensional (3D) sound. In order to test the influence of mutual synergy effect, subject assessment with five university students is carried out using VR ship simulator having PC monitor and LCD shutter glasses. It I found that the averaged scale value of image naturalness is increased by 0.5 from $I_{nat}$=3.1 to 3.6 when blending stereoscopic images with 3D sound, and the averaged score value of sound localization is increased by 10% from $A_{SL}$ = 70~75% to $A_{SL}$ = 80~85% when blending 3D sound with stereoscopic image. In conclusion, the results show that the proposed method is able to increase the presence feeling in the VR simulator.

Effect of Co-firing PKS and Coal on Flame Structure in a Pulverized Coal Swirl Burner (미분탄 스월버너에서 PKS와 석탄 혼소가 화염 구조에 미치는 영향)

  • Shin, Minho;Sung, Yonmo;Choi, Minsung;Lee, Gwangsu;Choi, Gyungmin;Kim, Duckjool
    • Journal of the Korean Society of Combustion
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    • v.21 no.4
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    • pp.30-38
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    • 2016
  • Flame structure of co-firing coal and palm kernel shell (PKS) was investigated in a pulverized coal swirl burner by particle image velocimetry (PIV). The pulverized coal swirl flame is operated with a PKS blending ratio of 10%, 20%, and 30%. For all operating conditions, flame structures such as internal recirculation zone (IRZ), outer recirculation zone (ORZ), and exhaust tube vortex (ETV) were observed. In the center of flame, the strong velocity gradient is occurred at the stagnation point where the volatile gas combustion actively takes place and the acceleration is increased with higher PKS blending ratio. OH radical shows the burned gas region at the stagnation point and shear layer between IRZ and ORZ. In addition, OH radical intensity increases for a co-firing condition because of high volatile matter from PKS. Because the volatile gas combustion takes place at lower temperature, co-firing condition (more than 20%) leads to oxygen deficiency and reduces the combustibility of coal particle near the burner. Therefore, increasing PKS blending ratio leads to higher OH radical intensity and lower temperature.

Electrical Breakdown Properties of Extrusion Blended Low Density Polyethylene (사출 블렌드 저밀도 폴리에틸렌의 절연파괴 특성)

  • 조돈찬;김형주;신현택;이충호;이수원;홍진웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.593-596
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    • 2001
  • In the previous work, the effect of blending with two kinds of low density polyethylene (LDPE) on physical and electrical properties have been investigated. From the results, blending with two kinds of LDPE was effective method on changing the morphology of LDPE and improving the high-field characteristics in high temperature region. Especially, it suggested that the F$\_$BImp/ was associated with the changes of the crystal size. In this work, the relationship between the morphology and the high-field characteristics of blended LDPE was discussed. In addition, the physical and electrical properties of blended LDPE with extrusion treatment were investigated. The two groups of specimen were prepared; Group 1 was prepared by passing 1 time through the extruder included in the film-blowing process, and Group 2 was prepared by passing 2 times through the extruder. From the relation between the crystal size which was perpendicular to the (020) plane and the F$\_$BImp/ of blended LDPE, it was confirmed that the F$\_$BImp/ was associated with the changes of crystal size due to the blending. Moreover, the F$\_$BImp/ of blended LDPE in Group 2 was higher than that of blended LDPE in Group 1. The crystal size of the (020) plane became smaller according to the extrusion treatment. These results suggest that the uniform distribution and dispersion of crystalline occurred due to the extrusion treatment and the morphological change due to the extrusion treatment influenced on the electrical properties of blended LDPE.

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Effect of Blending Rate of Waste Rockwool in Nursery Media on Growth of Marygold Plug Seedlings (육묘용 상토내의 폐암면 혼합비율이 메리골드 플러그묘의 생육에 미치는 영향)

  • Jun, Ha-Joon;Hwang, Jin-Gyu
    • Journal of Bio-Environment Control
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    • v.16 no.1
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    • pp.27-31
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    • 2007
  • The experiment has investigated the effects of blending rate of waste rockwool in nursery media on growth of Marygold 'Yellow boy' plug seedlings. A commercial plug medium containing 10% zeolite, 10% vermiculite, 5% perlite, 10% peatmoss and 65% cocopeat was used as the control, and the other media compounded with 10% of zeolite, vermiculite, perlite and peatmoss and 10, 30, and 50% of waste rock-wool. There was not significant difference in germination rate ot Marygold between treatments. Plant height, number of leaves, stem diameter and leaf area were higher in commercial plug medium and compound nursery media containing 50% of waste rockwool than 30 or 10% of waste rockwool. Fresh weight and dry weight of shoot and root increased in the treatment of commercial plug medium and the medium of 50% waste rockwool than 10 and 30% of waste rockwool. These results suggested the possibility of utilization of waste rockwool for medium components of plug seedlings.

Derivation of Optimal Conditions and Effect of Treated Water Quality for Treatment of Drinking Water using Inorganic Membrane (무기막을 사용한 먹는물 처리 시 최적의 조건 도출 및 처리수질에 미치는 영향)

  • Won, Chan-Hee
    • Journal of the Korean Society for Environmental Technology
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    • v.19 no.6
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    • pp.543-549
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    • 2018
  • In this study, the treatment efficiency of inorganic membrane according to the flux that blending raw water was investigated at the laboratory level. Based on the results of each blending and flux, we obtained the best efficiency according to each measurement item. The treatment efficiencies were different depending on the raw water and treatment amount of the treated water. Especially, turbidity removal efficiency was high. In the case of $UV_{254}$, the removal efficiency according to the concentration of the raw water and the removal efficiency according to the flux of the treated water showed a maximum of 69 % to minimum of 48 %. In the case of TOC and DOC, the processing efficiency was 22 % and 28 %, respectively, because the organic value of the raw water was low. These results suggest that there is an optimal process to effectively remove contaminants from the inorganic membrane process, and it is necessary to optimize it according to operating conditions.

Analysis of Quality and Processing Suitability of Mixed Seeding and Flour Blending between Wheat Varieties (밀 품종 혼파와 밀가루 혼합에 따른 품질 및 가공적성 분석)

  • Kim, Kyeong-Min;Kim, Kyeong-Hoon;Kang, Chon-Sick;Jeong, Han young;Choi, Chang-Hyun;Park, Jinhee;Son, Jae-Han;Yang, Jinwoo;Kim, Young-Jin;Park, Tae-Il;Kweon, Meera
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.64 no.3
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    • pp.225-233
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    • 2019
  • This study was conduct to investigate the effect of mixed seed sowing and flour blending on the uniformity of flour quality of Korean domestic wheat. Two wheat varieties (Keumkang and Baegjoong) were selected for sowing mixed seeds, and their growth characteristics and flour quality were analyzed. Quality of flour blending with the same varieties was also evaluated. The ratios for mixed seed sowing and flour blending were from 0 to 100% with a 10% increase of interval for each treatment. On increasing the portion of Baegjoong in mixed seed sowing, the heading time was a little delayed, however, yield increased. The results of the flour quality showed lower damaged starch content and sodium carbonate SRC (solvent retention capacity) value for Keumkang than for Baegjoong. Protein quantity by protein content and quality by SDSS (Sodium Dodecyle Sulfate-Sedimentation) volume, lactic acid SRC, and mixograph pattern of Keumkang were superior to those of Baegjoong. Compared with mixed seed sowing, overall quality characteristics of flours with different ratios showed predictable and proportional change by flour blending. This demonstrated the successful application of flour blending, compared with mixed seed sowing, for improving the uniformity of flour quality.

Dimensional Stability of Single Jersey Fabrics of $LincLITE^{(R)}$ and Conventional Yarns. I.

  • Park, Shin-Woong;Collie, Stewart;Herath, C.N.;Kang, Bok-Choon
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.398-403
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    • 2006
  • Dimensional constants (k values) of single jersey fabrics made from $LincLITE^{(R)}$ and conventional yams are calculated under dry, steam, full relaxation treatments. Fabrics were made under different tightness factors such as high, medium and low with different twist factors, twist directions and feeder blending. $LincLITE^{(R)}$ yarns made to get soft and bulkier effects with yam count of 39 tex and conventional yams made into 39 tex and 48 tex yam counts. Various effects on K values are analysed using correlation coefficients. K-values are increased with relaxation progression and have shown some differences between in $LincLITE^{(R)}$ and conventional fabrics, and feeder blended fabrics. Loop shape factor is highly affected by tightness factor, relaxation and feeder blending in $LincLITE^{(R)}$ fabrics, whereas twist factor not significantly effects on loop shape factor in conventional fabrics. Stitch density significantly increases with relaxation in conventional fabrics and no significant effect shows with $LincLITE^{(R)}$ fabrics.