• Title/Summary/Keyword: bleaching process

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Enzymatic degumming of edible fats and oils (효소를 이용한 식용유지의 탈검 공정)

  • Yoon, Suk Hoo
    • Food Science and Industry
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    • v.51 no.2
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    • pp.100-113
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    • 2018
  • To obtain an edible grade oil from crude oil extracted from oil-bearing materials, it is generally necessary to carry out a refining process composed with degumming, deacidification, bleaching, and deodorization, to remove undesirable matters which affect the quality and shelf life of oils. The main purpose of degumming is to remove gum material mainly consisted with phospholipids. Phospholipases convert nonhydratable phospholipids into their hydratable forms which can be removed by centrifugation. In comparison with conventional water and acid degumming processes, enzymatic degumming can result the lower phosphatide content in oil than conventional processes. The enzymatic degumming can be conducted with the reduced amount of acid, and contributes to generate less amount of wastewater, decrease of operating cost, and increase oil recovery yield. The phospholipases used in enzymatic degumming process are phospholipase A1, A2, B, and C.

Synthesis and Evaluation of Novel Organic Bleach Activator (Decanoyloxyethoxycarbonyloxybenzenesulfonate) for Laundry Detergents (세탁세제를 위한 신규 유기 표백활성제인 Decanoyloxyethoxycarbonyloxybenzenesulfonate의 합성과 평가)

  • Cho, Wan Goo;Lee, Chang Woo;Oh, Kyung Hee
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.168-172
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    • 2008
  • Not all types of soil occurring on household fabrics can be removed by simple washing with normal surfactants. In order to achieve a satisfactory cleaning effect, an additional treatment step, called bleaching, is required in such cases. Currently, the best known bleach activator is tetraacetylethylenediamine (TAED). In this study, we synthesized a novel organic bleach activator (OBA), decanoyloxyethoxycarbonyloxybenzenesulfonate. For stabilizing the OBA, it was coated with zeolite and polyethylene glycol. It is found that the stability was enhanced and OBA shows good cleansing and bleaching effects even in cold water ($20^{\circ}C$). OBA also shows easy biodegradability with 88% in the condition of OECD standard. During the cleansing process, OBA shows excellent microbiological effect against T. mentagrophytes and S. aureus.

Studies on the Pulping Characteristics of Larchwood (Larix leptolepis Gordon) by Alkaline Process with Additives (첨가제(添加劑) 알칼리 법(法)에 의한 일본 잎갈 나무의 펄프화(化) 특성(特性)에 관(關)한 연구(硏究))

  • Lim, Kie-Pyo;Shin, Dong-Sho
    • Journal of the Korean Wood Science and Technology
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    • v.7 no.2
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    • pp.3-30
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    • 1979
  • Larch ($\underline{Larix}$ $\underline{leptolepis}$ GORDON), one of the major afforestation species in Korea in view of its growing stock and rate of growth, is not favored as a raw material for pulp due to its low yield of pulp and difficulties with bleaching arising from the high content of extractives in wood, and the high heartwood ratio and the active phenolics, respectively. The purpose of this study is to investigate the characteristics of firstly pulping with various additives of cellulose protector for the yield of pulp, and secondly bleaching with oxygen for chlotination-alkali extraction of five stage-sequence to reduce chlorine compounds in bleaching effluents. The kraft cooking liquor for five age groups of larchwood was 18 percent active alkali with 25 percent sulfidity and 5 : 1 liquor-to-wood ratio, and each soda liquor for sap-and heart-wood of the 15-year-old larchwood was 18 percent alkali having one of the following cellulose protectors as the additive; magnesium sulfate ($MgSO_4$, 2.5%), zinc sulfate ($ZnSO_4$, 2.5%), aluminium sulfate ($Al_2(SO_4)_3$, 2.5%), potasium iodide (KI, 2.5%), hydroquinone (HQ, 2.5%), anthraquinone (AQ, 0.1%) and ethylene diamine (EDA, 2.5%). Then each anthraquinone-soda liquor for the determination of suitable cooking condition was the active alkali level of 15, 17 and 19 percent with 1.0, 0.5 and 0.1 percent anthraquinone, respectively. The cooking procedure for the pulps was scheduled to heat to 170$^{\circ}C$ in 90 minutes and to cook 90 minutes at the maximum temperature. The anthraquinone-soda pulps from both heartwood and sapwood of 15-year-old larchwood prepared with 0.5 percent anthraquinone and 18 percent active alkali were bleached in a four-stage sequency of OCED. (O: oxygen bleaching, D: chlorine dioxide bleaching and E: alkali extraction). In the first stage oxygen in atmospheric pressure was applied to a 30 percent consistency of pulp with 0.1 percent magnesium oxide (MgO) and 3, 6, and 9 percent sodium hydroxide on oven dry base, and the bleached results were compared pulps bleached under the conventional CEDED (C: chlorination). The results in the study were summarized as follows: 1. The screened yield of larch kraft pulp did not differ from particular ages to age group, but heartwood ratio, basic density, fiber length and water-extractives contents of wood and the tear factor of the pulp increased with increasing the tree age. The total yield of the pulp decreased. 2. The yield of soda pulp with various chemicals for cellulose protection of the 15-year-old larchwood increased slightly more than that of pure soda pulp and was slightly lower than that of kraft pulp. The influence of cellulose protectors was similar to the yield of pulps from both sapwood and heartwood. The effective protectors among seven additives were KI, $MgSO_4$ and AQ, for which the yields of screened pulp was as high as that of kraft pulp. Considering the additive level of protector, the AQ was the most effective in improving the yield and the quality of pulp. 3. When the amount of AQ increased in soda cooking, the yield and the quality of the pulp increased but rejects in total yield increased with decreasing the amount of active alkali from 19 to 15 percent. The best proportion of the AQ seemed to be 0.5 percent at 17 percent active alkali in anthraquinone-soda pulping. 4. On the bleaching of the AQ-soda pulp at 30 percent consistency with oxygen of atomospheric pressure in the first stage of the ODED sequence, the more caustic soda added, the brighter bleached pulp was obtained, but more lignin-selective bleaching reagent in proportion to the oxygen was necessary to maintain the increased yield with the addition of anthraquinone. 5. In conclusion, the suitable pulping condition for larchwood to improve the yield and quality of the chemical pulp to the level for kraft pulp from conventional process seemed to be. A) the selection of young larchwood to prevent decreasing in yield and quality due to the accumulation extractives in old wood, B) the application of 0.5 percent anthraquinone to the conventional soda cooking of 18 percent active alkali, and followed, C) the bleaching of oxygen in atmospheric pressure on high consistency (30%) with 0.1 percent magnesium oxide in the first stage of the ODED sequence to reduce the content of chlorine compounds in effluent.

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Characteristics of wastewater from unit systems of automative process for manufacture of paper mulberry pulp fibers (닥 펄프 제조공정 자동화에 따른 단위공정 폐수의 특성)

  • Hwang, Ji-Hyun;Hwang, Sung-Jun;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.3
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    • pp.55-62
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    • 2015
  • Paper mulberry fibers have been used as fibrous raw materials for manufacturing traditional handmade paper, hanji for a long time. Compared to wood pulp fibers, pulp fibers from mulberry bast tissue have some benefits in physical and chemical properties due to their high D.P (degree of polymerization), M.W (molecule weight) and long fiber length. Specially, Korean handmade hanji shows outstanding characteristics in mechanical tensile strength, folding endurance, flexibility and long sustainable conservation properties. Therefore, hanji is widely applied to daily supplies, hygienic goods, medical supplies, clothing industries and so on. Recently, the potential demand of mulberry pulp fibers is more and more increased on the strength of high application fields. This study was focused on the possibility of wastewater recycling in unit operation systems for the development of automated mass production line. The properties and environmental loads of wastewater from debarking, cooking, bleaching and screening process were analyzed by means of COD, conductivity, turbidity and solid materials. The wastewater from debarking and cooking process was comparatively high in pollution load, and would be treated by additional approaches of chemico-physical method.

Effect of Operating Parameters on Ozone Generation in Dielectric Barrier Discharge Process (무성방전내에서 오존 발생에 미치는 운전변수의 영향)

  • 이현돈;이은영;이용환;최유리;정재우
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.383-384
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    • 2003
  • 오존은 산업적으로 널리 활용되고 있으며 특히, 매우 넓은 환경공학적 응용분야를 가지고 있다. 오존의 산업적 적용은 1900년대 초부터 음용수 처리를 위해 시작되었으며 현재까지 폐수처리, 화학물질 합성, 재료의 부식 정도 측정, 수영장 소독, 치료용 목적, 냉각수 살균, pulp bleaching, 악취 및 대기 오염물질 처리 등의 광범위한 산업적 응용분야를 가지고 있다. 오존을 생성시키기 위한 대표적인 공정으로는 무성방전(dielectric barrier discharge, DBD) 공정, 전기 분해법(electrolysis), 자외선 조사법(UV irradiation)을 들 수 있으며 가장 널리 활용되고 있는 공정은 1857년 Simens에 의해 개발된 DBD 공정이다. (중략)

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효소처리에 의한 제지적성 개선

  • 김형진;조병묵
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.04a
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    • pp.39-46
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    • 2000
  • In pulp and papermaking process, enzymatic treatment of pulp fibres has been a topic of increasing interest in last decade. Lots of patents, papers and research reports were published on the application of enzymes in the fields of enzymatic bleaching, deinking, slime control, pitch control, waste water treatment and fibre modification. Cellulase and hemicellulase are the principal enzymes used for the modification of fibre property. This study was carried out for determinating the behaviors of enzyme to pulp fibres. A commercial enzyme, Denimax BT which is consisted with cellulase and hemicellulase, was treated to the kraft pulp produced from domestic hardwood mixtures. Results were mainly concentrated on the behaviors of freeness, drainability and fines content of fibres, and physical properties of paper with enzyme treatment. The freeness levels and dewatering ability were developed, and the fines contents were decreased. The creation of fines were controlled by the method of pre-enzyme treatment prior to fibre beating. The mechanical strength of paper, like tensile, burst, tear strength and folding endurance, were remarkably improved by the pre-enzyme treatment.

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Analysis of brightness decrease originated from mixing of flexo printed ONP and OCC in ONP recycling process (플렉소 인쇄 신문지와 OCC 배합에 따른 ONP 탈묵펄프의 백색도 변화)

  • Ryu, Jeong-Yong;Song, Bong-Keun
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.119-123
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    • 2011
  • The application of flexo printed ONP and OCC leads to brightness decrease of deinked stock in ONP recycling system. The largest problems are due to accumulation of flexo ink & introduction of brown fibers. All these are emphasized by variations in the amount of flexo printed ONP and OCC in recovered ONP stock. Most of the brightness problems caused by flexo ink can be helped and solved by applying a proper polyelectrolytes as coagulation agent and flocculation agent. This requires exact evaluation of sedimentation or dissolved air flotation potentials of flexo ink and polyelectrolytes. Effect of bleaching chemical (H2O2) addition level on the increase of brightness of OCC included stock has been investigated by lab scale test.

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Effect of Urea Addition on Soda Pulping of Oak Wood

  • Cho, Nam-Seok;Matsumoto, Yuji
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.285-290
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    • 2006
  • As an alternative method to solve air pollution problem and difficulty of pulp bleaching of kraft pulping process, NaOH-Urea pulping was applied. The properties of NaOH-Urea pulp were compared to those of NaOH and kraft pulps. Addition of urea in low alkali charges retarded delignification rate compared to NaOH pulping. But, in high alkali application, delignification was significantly enhanced not from the addition of urea but from the high alkalinity. It was disclosed that urea did not participate on delignification reaction by the experiment using lignin model compound. Compared to paper strengths at the same level of sheet density, NaOH-Urea pulp gave as almost same breaking length and tensile index as those of kraft pulp. Especially tensile energy absorption and burst index were higher than those of kraft pulp.

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Autohydrolysis and Enzymatic Saccharification of Lignocellulosic Materials(III) - Recycling and Reutilization of Cellulase Enzyme - (목질 재료의 자기가수분해 및 효소당화에 관한 연구 (Ⅲ) - Cellulase 효소의 회수 및 재사용 -)

  • Cho, Nam-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.17 no.3
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    • pp.45-51
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    • 1989
  • A major problem in the enzymatic hydrolysis of lignocellulosic substrates is the very strong bonding of cellulase to lignin and even cellulose in the hydrolysis residues. This phenomenon inhibits recycle of the cellulase which is a major expense of the enzymatic hydrolysis process. In this paper, autohydrolyzed wood was delignified by two-stage with a 0.3% Na OH extraction and oxygen-alkali bleaching and was subjected to enzymatic hydrolysis with cellulase. Also, an improved almost quantitative recycle process of cellulase enzyme was discussed. In enzyme recovery by affinity method. the first recycling showed relatively high hydrolysis rate of 97.4%. Even at the third recycle. hydrolysis rate was 86.7 percents. In the case of cellulase recovery by ultrafiltration method, first 2 recycling treatments resulted very high hydrolysis rate(97.0-97.7%). Even the third recycling showed about 94.2%. Authoydrolysis of oak wood followed by 2-stage delignification with alkali and oxygen-alkali produced a substrate for enzymatic hydrolysis that allowed almost quantitative recycle of cellulase.

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Effects of Heat Treatment and Viologen Incorporation on Electrochromic Properties of TiO2 Nanotubes (열처리 및 바이올로젠 도입에 따른 TiO2 나노튜브의 전기변색 특성)

  • Cha, Hyeongcheol;Nah, Yoon-Chae
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.102-107
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    • 2016
  • We demonstrate the electrochromic properties of $TiO_2$ nanotubes prepared by an anodization process and investigate the effects of heat treatment and viologen incorporation on them. The morphology and crystal structure of anodized $TiO_2$ nanotubes are investigated by scanning electron microscopy and X-ray diffraction. As-formed $TiO_2$ nanotubes have straight tubular layers with an amorphous structure. As the annealing temperature increases, the anodized $TiO_2$ nanotubes are converted to the anatase and rutile phases with some cracks on the tube surface and irregular morphology. Electrochemical results reveal that amorphous $TiO_2$ nanotubes annealed at $150^{\circ}C$ have the largest oxidation/reduction current, which leads to the best electrochromic performance during the coloring/bleaching process. Viologen-anchored $TiO_2$ nanotubes show superior electrochromic properties compared to pristine $TiO_2$ nanotubes, which indicates that the incorporation of a viologen can be an effective way to enhance the electrochromic properties of $TiO_2$ nanotubes.