• 펄프종이기술
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• 제34권3호
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• pp.46-52
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• 2002

To produce the raw material used for printing and writing paper or high quality tissue, MOWs that were consisted of white ledger, colored ledger and old newspaper were bleached with EoP and EoPY(FAS) method, the EoP bleaching process gave the improvement in brightness and a high color removal efficiency. Especially, MOW B(initial brightness: 59.1％ ISO) that contained much old newspaper showed the higher bleaching efficiency than those of MOW A(initial brightness: 68.3%). After EoPY(FAS) bleaching, MOW's brightness was increased from 68.3% ISO to 84.3∼84.0% ISO, and from 59.1% ISO to 78.7∼79.2% ISO, respectively. Also the tensile and burst index of bleached pulps decreased by 10∼30%. The tear index slightly decreased or halted at the same range as unbleached pulps.

• 한국물환경학회지
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• 제23권3호
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• pp.303-308
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• 2007

Three types dyeing wastewater (dark, medium, light color) discharged from cotton textile dyeing with reactive dye was collected at each step of process. Each process dying wastewater was analyzed and treated by ionized gas. The analysis focused on $COD_{Cr}$, SS and color. Bleaching & scouring process wastewater has the highest $COD_{Cr}$ value in the three type dyeing wastewater. SS shows the highest value at dyeing process wastewater in dark and medium color but light color has at finishing process wastewater. The result of process wastewater treatment by ionized gas was that the ionized gas was effective in $COD_{Cr}$ removing of bleaching & scouring process and finishing process wastewater but was not good at dyeing process wastewater. From that result it is estimated that the ionized gas could not work in opening the aromatic ring and react only in aliphatic component of the molecule. Because the surfactants contained in bleaching & scouring process and finishing process wastewater have only one aromatic ring in its molecular structure, in contrast with the reactive dye compounds consist of aromatic rings great part of its molecular structure. The color almost removed in 1.5 hrs reaction time but $COD_{Cr}$ removal effiency was only 30.7% through 3hrs in 1500 mL of total dyeing wastewater treated by 10 L/min ionized gas.

• 디지털융복합연구
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• 제17권1호
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• pp.357-364
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• 2019

본 연구는 모발 탈색 시 사용되어지는 탈색제 입자에 따른 모발 손상도를 비교하였으며, 주사전자현미경을 사용하여 세 가지의 탈색제 입자크기를 관찰하였다. 탈색제의 주성분은 과황산암모늄과 과황산칼륨이 주성분인 분말형 탈색제로 각 제품 입자크기는 $131{\mu}m$, $72{\mu}m$, $48.8{\mu}m$로 나타났다. 손상도 실험에서 입자가 큰 탈색제보다는 입자가 작은 시술 제품에서 큐티클 층이 일어나거나 박리현상이 거의 일어나지 않았다. 모발의 색상 측정에서 입자 큰 탈색제의 모발시료는 가장 어둡게 나왔으며, 가장 작은 입자의 탈색 결과가 가장 밝게 나왔다. 연구 결과 모발의 손상도 완화에 더 효과적인 탈색제는 작은 입자를 가진 탈색제를 이용하여 시술하고, 탈색 정도에 따라 입자를 선택하는 것이 탈색력은 높이고 손상도를 낮출 수 있다고 사료된다. 이는 탈색제 선택에 대해서 우수한 결과를 만들기 위한 방안이며, 그 결과를 토대로 현장에서 탈색 시술시 모발 손상에 대처할 수 있을 것으로 기대 된다.

• 펄프종이기술
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• 제31권4호
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• pp.49-57
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• 1999

In CLO2 delignification and bleaching process, formation of chlorate corresponds to a loss of 20-36% of the original CKO2 charge. Because chlorate is inactive and harmful to environmental, it will be of benefit to find methods that can reduce the formation of chlorate during chlorine dioxide bleaching. Chlorate is mainly formed by the reaction HCIO +ClO2 $\longrightarrow$H+ + Cl_ +ClO3-2 On the other hand, AOX in chlorine dioxide bleacing is formed also due to the in-situ produced hypochlorous acid. THus both AOX and chlorate could be reduced by addition of hypochlorous acid. Some paper son the reduction of AOX by additives appeared , but systematic data on chlorate reduction as well as pulp and effluent properties are not available. THus this paper of focused on the effects on the reduction of chlorate and chlorine dioxide bleachability. The additives, fulfamic a챵, AMSO, hydrogen peroxide, oxalic acid were found to eliminate chlorine selectively in chlorine and chlorine dioxide mixture.However, when they were added to bleaching process, sulfamic acid and DMSO showed significant reduction of chlorate formation but hydrogen peroxide and oxalic aicd did not, and significant amount ofhydrogen peroxide was found resided in the bleaching effluent , In addition, sulfamic acid and DMSO decreased the bleaching end ph values while hydrogen peroxide and oxalic acid did not, which also indicated that hydrogen peroxide and oxalic acid were ineffective. The difference might be ascribed to the competitives of hypochlorous acid with lignin, chlorite (CKO2) and additives. Sulfamic acid and DMSO showed better pulpbrightness development but less alkaline extraction efficiency than hydrogen peroxide , oxalic acid and control, which means that insitu hypochlorous acid contributes to the formation of new chromophore structures that can be easily eliminated by alkaline extraction. DMSO decreased the delignification ability of chlorine dioxide due to the elimination of hypochlorous acid, but sfulfamic acid did to because the chlroinated sulfamic acid had stable bleachability. In addition, sulfamic acid, and SMSO shwed decreased color and COD of bleaching effluents, hydrogen peroxide decreased effluent color but not COD content, and oxalic acid had no statistically significant effects. No significant decreases of pulp viocosity were found except for hydrogen peroxide. Based on our results , we suggest that the effectiveness of hydrogen peroxide on the reduction of AOX in literature might be explained by other mechanisms not due to the elimination of hypochlorous acid , but to the direct decomposition of AOX by hydrogen peroxide.

• 한국인쇄학회지
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• 제26권1호
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• pp.65-72
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• 2008

Kappa number and brightness were more increased with treatment of endo-xylanase than hydrogen-peroxide. In pulp bleaching process, endo-xylanse was most effective in the other enzyme treatment. Exo-xylanase was effective more than 4 unit treatment. Kappa number was tiny increased with enzyme ratio, but less than 4 unit treatment, increased with hydrogen peroxide treatment ratio. In more than 4 unit acetyl-estease treatment, Kappa number and brightness were not influenced with enzyme treatment ratio, but concentration of hydrogen-peroxide.

• 펄프종이기술
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• 제33권4호
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• pp.28-34
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• 2001

Korea traditional handmade paper, Hanji, has been known for more than thousand years for its high strength, high whiteness, high gloss, good ink reception and long lasting quality. Main component fiber of the Hanji is called 'Dak', which is the bast fiber of the Korea paper mulberry ($\textit{Broussonetia kazinoki}$). Dak has long fiber length, and high cellulose DP, if processed properly. The quality of Hanji is partly from the superior quality of Dak over wood fiber, and partly from the traditional papermaking process. The traditional papermaking process includes pulping, bleaching, refining, use of natural polymer, and sheet making process. Every traditional process has its special role. Comparisons between the modern papermaking technology and the traditional process were made in this study. The traditional process effectively protected cellulose DP in pulping and bleaching process, protected fiber length in refining process, and developed the high strength in the sheet forming process over the modern papermaking process.

• 한국염색가공학회지
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• 제7권1호
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• pp.32-42
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• 1995

In order to reduce the amount of waste water generated from textile dyeing process and processing water, cotton fabric was bleached with ozone in ozone/water contact system, and dyed. The results obtained from the measurement of whiteness, reflectance, tensile strength, color difference, and K/S value of treated samples were as follow : 1) In ozone bleaching, factors affect whiteness most are treatment time and ozone dosage. As treatment time is lengthened, whiteness increases. Futhermore, bleaching effect is high in acidic treatment, but low in alkaline treatment. 2) As bleaching goes on, maximum absorption wave length shifts to shoter wavelengths. 3) As treatment time is lengthened or pH of treatment is low, tensile strenth of treated fabric decrease. 4) In all cases, color difference of dyed cotton fabrics in above 2% o.w.f. dyestuff concentration don't go beyond 1∼2 AN unit, compared with standard.

• 한국잡초학회지
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• 제9권3호
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• pp.230-237
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• 1989

Bleaching herbicides(oxyfluorfen, oxadiazon, paraquat)의 작용발현에 영향을 미치는 온도 및 광의 효과를 조사한 결과 oxyfluorfen 과 oxadiazon의 제초활성은 $10-35^{\circ}C$에서 온도가 증가될수록 높았으며 온도의 효과는 제초작용 발현단계(photooxidation) 보다는 그 이전 단계에서 더욱 큰 영향이었다. 처리약제 모두 광도가 높을수록 활성이 강하였으며 paraquat 는 광질간의 활성차이가 없었으나 oxyfluorfen 및 oxadiazon 은 챙색광에서 높은 활성을 보였고 이들 두 약제에 대한 광의 효과는 광합성 및 호흡의 전자전달계나 carotenoid 생합성 보다는 chlorophyll 생합성 과정과 일정한 관련이 있다.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 1999년도 춘계학술발표논문집
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• pp.78-83
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• 1999

In this paper the extinction coefficients of molecule chlorine ($Cl_2$), chlorine dioxide (ClO$_2$), hypochlorous acid (HClO), chlorous acid ($HClO_2$$_2$) were determined using a PDA UV-VIS spectrophotometer. Based on these, the concentrations of $Cl_2$, $ClO_2$, and HClO in general chlorine dioxide bleaching liquor can be measured. The concentrations of $Cl_2$, $ClO_2$ and $HClO_2$ produced during the generation of methanol based chlorine dioxide generator can also be determined use the same method. The method was thought to be able to give more information in chlorine dioxide bleaching chemistry if combine its use with titration and ion chromatography.

• 한국염색가공학회지
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• 제8권2호
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• pp.35-42
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• 1996

Peroxodisulfates are being developed as low temperature bleaching agents for cotton fabrics to save the thermal energy. In this research we used the colar difference meter to determine the whiteness which peroxide booster will possibly make an effect on cotton fabric at the low temperature process using consist of temperature with different conditions agents, such as sodium hydroxide, sodium peroxodisulfate and potassium peroxodisulfate. The peroxide bleaching follows a laboratory experiments, using a statistical plan for three variables: the concentrations of hydrogen peroxide and sodium hydroxide and the temperature of bathing. The purpose of this research was to use the response surface analysis method to evaluate the relative importance of factors providing optimum whiteness. A ridge analysis of the data on whiteness response results in 3-D response surface diagrams for optimizing the concentrations of hydrogen peroxide and sodium hydroxide at about 42~52$^{\circ}C$.