• 펄프종이기술
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• 제44권1호
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• pp.65-73
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• 2012

Nowadays, the concern on the environmental load of bleaching process gave rise to the process of ECF(elemental chlorine free) and TCF(total clorine free). These sequences are based on oxygen-derived compounds such as oxygen, ozone, and hydrogen peroxide which is used as a typical eco-friendly bleaching agent. In this study, paper mulberry pulp was bleached with hydrogen peroxide and some bleaching process were accompanied with ultrasonication in order to increase the bleaching efficiency. The best bleaching efficiency of paper mulberry pulp was obtained in the condition of hydrogen peroxide and ultrasonication(20 kHz) bleaching system at $45^{\circ}C$ for 30 min. The brightness and kappa number of paper mulberry pulp were gained to 5.09% and 3.52 respectively. and yield was slightly loosed to 2%. Therefore, the efficiency of hydrogen peroxide and ultrasonication bleaching system of paper mulberry pulp was superior to the conventional hydrogen peroxide bleaching system. Magnesium sulfate acted as a bleaching stabilizer for the increasement of yield. As a result, the yield and viscosity were increased to 2.2% and 12% respectively.

• 한국광학회지
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• 제2권2호
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• pp.89-95
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• 1991

은염건판을 반전표백 처리하여 위상형 홀로그래픽 회절격자를 제작하였다. 반전표백에 적합한 화학적 현상액을 사용하고, 표백 후 isopropyl alcohol에 의한 급속탈수 방법으로 회절격자의 효율을 높일 수 있었다. 현상액의 종류와 표백액의 조성 변화 그리고 건조 방법에 따른 회절효율의 변화를 실험적으로 측정하였으며, 각각의 경우에 제작된 회절격자의 특성을 이론적으로 분석하였다. 제작된 회절격자는 최적 조건에서 최고 88%의 효율을 보여, 상용표백 방법으로 제작된 회절격자에 비해 산란이 적으면서도 효율이 높은 결과를 얻었다.

• 펄프종이기술
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• 제47권1호
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• pp.66-74
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• 2015

DIP(deinked pulp) was bleached by FAS, $Na_2S_2O_4$ and $H_2O_2$, which are widely used in DIP bleaching process, in order to improve optical properties of DIP, and the bleaching efficiencies of DIP and environmental loads of waste water were compared, depending on bleaching chemical dosages. With the application of different bleaching chemicals, some positive improvements were shown in optical and physical properties of bleached pulp. However, the physical properties of bleached DIP and their characteristics of wastewater were remarkably different, depending on dosages and bleaching reagents. DIP chemicals with FAS and $Na_2S_2O_4$ have higher improvement in optical and physical properties than $H_2O_2$. Also, environmental loads such as pH, turbidity, SCODcr and cationic demand were decreased in reductive bleaching process. Despite of higher effectiveness of reductive bleaching process, there were some environmental problems caused by sulfur ions from FAS and $Na_2S_2O_4$. With the method of sulfur ion controls, it would be more effective than $H_2O_2$ bleaching process.

• 대한심미치과학회지
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• 제7권1호
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• pp.6-17
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• 1998

치아미백은 100여년전 이상부터 시행되어 왔으나, 지난 4반세기 동안의 생활치아 미백술의 표준적인 방법은 과산화수소와 열원을 사용하거나, 열원과 광원을 복합해서 사용하는 것이었다. 이 술식의 단점은 술식의 복잡성, 많은 비용, 결과의 불확실성과 환자의 불편이었다. 1989년 3월에 치과계에서는 Haywood와 Heyman에 의해 발표된 새로운 생활치아 미백술(Night Guard Vital Bleaching)을 도입했다. 치아구조에 대한 carbamide peroxide의 화학적 효과를 알고 있었으면 수년 전에 개발되었을 아주 간단한 치료술식이다. 이 방법은 시술이 쉽고, 사용 되는 재료의 높은 안전성, 낮은 치료비, 높은 성공률로 최근 다시 치아미백 붐을 일으키는데 일조를 하고 있으며, 생활치아 미백술의 표준적인 방법으로 신속히 자리잡아가고 있다.

• 패션비즈니스
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• 제10권1호
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• pp.94-105
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• 2006

Hair bleaching is a treatment process in which the melanic pigment is oxidized by hydrogen peroxide. With the increase of the number of treatments, $1{\sim}10$ levels of various colors develop, the hair luster diminishes, and the appearance becomes very rough. In this study, by changing the number of hair bleaching and bleaching conditions, the changes in the degree of hair damage and its process were observed through the use of scanning electron microscopy. The color changes were also compared through the use of spectrophotometer. In order to study the physical changes of the bleached hairs and to search for the optimum conditions to keep the hair damages minimum during bleaching, tensile properties were measured and reviewed. By increasing the number of hair bleaching and by the severe conditions, the scales became eroded and the protection layers were decreased, and the oxidation reached the inner sectors resulting in rough surface and fibrillation. The surface of the hairs became bright yellowish and transparent by the bleaching of melanic pigments or by the destruction of pigments. With the increase of bleaching degree, in terms of physical changes, the breaking strength decreased while the elongation increased a little.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2010년도 춘계학술발표회 논문집
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• pp.195-206
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• 2010

Xylan can be applied to improve the strength properties of paper; however the optical properties, such as brightness, are decreased significantly. To solve that problem, an applicable bleaching process is therefore desired. The aim of this research was to investigate the impact of hydrogen peroxide bleaching on hardwood kraft pulp pretreated with birchwood xylan by measuring optical properties (whiteness, brightness, opacity) as well as physical properties (tensile index, tearing index, bulk) of handsheets made from the bleached pulp. Hydrogen peroxide bleaching, as a kind of totally chlorine free (TCF) bleaching method, is quite important industrially for chemical pulp. In our work, the process variables of peroxide bleaching including bleaching temperature, time, initial pH and $MgSO_4$ dosage were studied. The results showed that both good mechanical properties and optical properties could be achieved when the operating parameters were controlled properly and therefore hydrogen peroxide bleaching was proved to be a suitable method for bleaching hardwood kraft pulp with adsorption of birchwood xylan.

• Preventive Nutrition and Food Science
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• 제3권4호
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• pp.374-378
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• 1998

The objectives of this study are to determine the optimum process conditions of Korean beeswax and discuss the parameter of adsorption . Purification conditions, such as time, temperature and the type of adsorbents were investigated using the relationship between the properties of refined products and process conditions and theiptimum bleaching condition of Korean beeswax were determined for the first time. The various bleaching conditions were examined by observing the result of Lovibond color, photometric color, methods provided by the American Oil Chemists '(A.O.C.S).The iptimum bleaching temperature was 8$0^{\circ}C$ and the bleaching agents (5% of the weight of beeswax) which consisted of activated clay and activated carbon and a vacuum system were also necessary.

• 한국가금학회지
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• 제34권2호
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• pp.99-104
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• 2007

본 연구는 식용유 정제 폐백토(spent bleaching clay)를 육계 사료 원료로 가치를 평가하기 위해서 실시하였다. 식용유 정제 폐백토(spent bleaching clay)는 대두유의 정제 과정에서 생산되어지며, 생 식용유 정제 폐백토(spent bleaching clay)속에는 조지방(26.0%)과 조회분(68.3%)은 풍부하나, 수분(5.2%)과 조단백질(0.5%)의 함량은 낮게 평가되었다. 식용유 정제 폐백토(spent bleaching clay)와 대두유의 산가는 각각 9.72 및 0.001로 유의한 차이가 인정되었다(P<0.05). 뿐만아니라 식용유 정제 폐백토(spent bleaching clay)의 과산화물가는 대두유보다 유의하게 높아서(P<0.05) 식용유 정제 폐백토(spent bleaching clay)의 빠른 산패 가능성을 시사한 결과이다. 그러나 식용유 정제 폐백토(spent bleaching clay)의 산패는 인공적인 방법으로 막을 수 있을 것이다. 한편 식용유 정제 폐백토(spent bleaching clay)의 육계 사육에서의 $2.0{\sim}4.0%$의 첨가는 사료 섭취량, 증체량 및 사료 효율을 개선시켰다. 결론적으로 육계 사료에 $2.0{\sim}4.0%$의 식용유 정제 폐백토(spent bleaching clay)의 이용이 가능할 것으로 사료된다.

• 분석과학
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• 제12권4호
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• pp.318-325
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• 1999

한지를 만들 때 발생하는 폐수로부터 분리하여 얻은 슬러지를 분석하여 본 결과 잿물 삶기 공정과 최종 화학 및 미생물처리 공정의 슬러지는 섬유질이 아니고, 표백 공정, 표백제 씻기 공정, 그리고 지통으로 옮기기 공정의 슬러지는 섬유질이었다. 고형분의 양은 표백 공정에서 가장 많았다. 수분 함량은 표백, 표백제 씻기 및 최종 화학 및 미생물 처리 공정의 슬러지 시료가 80~90% 정도로 많은 것으로 나타났다. 각 공정에서 발생되는 슬러지의 pH를 냉수와 열수를 이용하여 측정한 결과 표백 시료가 하이포아염소산 이온으로 인해 다른 시료보다 높은 pH를 나타내었다. 슬러지의 무기물 성분 함량은 잿물 삶기 시료에서는 Na, 표백제 씻기 시료에서는 Ca, 최종 화학 및 미생물 처리 슬러지에서는 Ca 와 Al을 주로 포함하고 있었으며, 그 외에도 Mg, Fe, K, P, Mn, Ti 등도 적은 양을 포함하고 있었다. 회분의 함량은 표백 공정의 슬러지일 경우에 가장 많은 것으로 나타났다. 슬러지를 주사 전자현미경으로 관찰한 결과 섬유질 모양과 결정성 모양으로 존재함을 알 수 있었는데 섬유질의 폭은 $5{\sim}50{\mu}m$ 정도이었다. 냉수와 온수에서 녹아 나오는 가용분과 알코올-벤젠 가용분 모두 표백 공정의 슬러지에서 가장 많았다.

• 한국의류학회지
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• 제30권2호
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• pp.338-347
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• 2006

Due to the complex environment in the ground, most of excavated costumes undergo deterioration and color change. To reduce the extent and intensity of the staining and to recover the original color or gray fabrics of excavated costumes, bleaching would be required. Excavated historical costumes are very delicate in nature, therefore, special care is needed in bleaching process. Several bleaching agents were selected and applied to the control cotton fabric and pre-deteriorated cotton fabrics to examine the change of color and physical properties after bleaching. A dual bleaching using hydrogen peroxide and sodiumborohydride showed the superior bleaching effect to the other bleaching agents. The strength of pre-deteriorated fabrics slightly increased after dual bleaching. The six historical costumes which belonged to General Duk-Ryung Kim's nephew's wife were dual bleached. They became remarkably cleaned and brightened. The treatments improved the appearance of costumes. By microscopic investigation, it is found that costumes did not show the damage after treatment. In conclusion, it is possible to bleach historical textiles without damage using appropriate bleaching agents like hydrogen peroxide and sodiumborohydride.