• 한국수산과학회지
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• 제38권2호
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• pp.100-105
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• 2005

Two species of fish and five species of marine invertebrate showed different tolerances to the toxicity of composite slag and bituminaus coal. Especially, Hemicentrotus pulcherrimus and young Haliotis discus hannai displayed marked differences in tolerance from. H. pulcherrimus and young H. discus hannai showed lethal effects at higher concentrations than those concentrations of the composite slag in the 1.0 and $0.4\%$ range, respectively. H. pulcherrimus showed no lethal effects at a lower concentration of $1.0\%$ composite slag and some differences in the rate of oxygen consumption with this concentration of composite slag. The lethal effects of bituminous coal on marine and fisheries organisms, even with higher concentrations, were not observed. At a higher concentration than that of 500 mg/L (ppm) of bituminous coal, decrease effects appeared in the rate of oxygen consumption of the experimental organisms. Taking into consideration that the experimental concentration of composite slag and bituminous coal were impracticable in the ocean, the results of this experiment suggest that composite slag and bituminous coal pose no real threat to marine or fisheries organisms.

• 에너지공학
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• 제23권2호
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• pp.42-48
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• 2014

미분탄의 연소 또는 열분해 과정으로부터 발생하는 tar-soot는 복사 열전달 및 질소산화물의 추가적인 발생 원인이라는 관점에서 의미 있게 다루어지고 있다. 최근 저열량탄이 증가함에 따라 시멘트의 원료로 재활용되던 석탄회에서 다량의 미연분과 tar-soot가 포함되어 오히려 다시 반입되는 사례가 빈번해지고 있다. 따라서 본 연구에서는 저열량탄 사용 확대에 따른 혼탄연소 조건에서 tar-soot의 배출특성을 살펴보기 위해 반응기로써 LFR(Laminar Flow Reactor)을 적용하였으며, 연료로는 현재 국내발전소에서 사용 중인 역청탄 2종(MOUNTAIN, MACARHTUR)과 아역청탄(KPU)을 이용하여 단탄별 tar-soot 배출특성과 혼소비에 따른 배출특성을 화염의 구조 변화와 함께 측정하였다. 휘발분이 많은 아역청탄의 soot cloud 길이는 역청탄에 비해 길었지만 전체적인 화염 길이는 짧아졌다. 단탄별 실험결과에서는 역청탄의 tar-soot 발생량이 아역청탄의 발생률보다 높았으며 역청탄 중 휘발분 함량이 많은 MOUNTAIN탄이 상대적으로 휘발분 함량이 적은 MACARHTUR탄의 tar-soot 발생률보다 높았다. 혼소시에는 단탄의 연소특성과는 다른 새로운 특성을 나타내었으며 저열량탄과 혼소되는 역 청탄의 종에 따라 tar-soot 발생량이 지배되는 것을 확인하였으나 혼소비에 따른 평균적 특성이 아닌 완전히 차별되는 배출특성을 나타냄에 따라 석탄의 등급에 따라 최적의 혼소비를 찾아서 연소시키는 것이 tar-soot 발생량을 줄일 수 있는 방법임을 의미한다.

• 한국도로학회논문집
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• 제18권6호
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• pp.137-143
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• 2016

OBJECTIVES : Bituminous materials, such as tack coat, are utilized between pavement layers for improving the bond strength in pavement construction sites. The standards regarding the application of bituminous material are not clearly presented in the Korean construction guideline without RS(C)-4. Hence, the objective of this study is to determine the optimum content of bituminous materials by analyzing interlayer shear strength (ISS) from the direct shear tester, which was developed in this research. The shear strength of tack coat was defined with the sort of bituminous materials. METHODS : The mixtures for the shear test were made using marshall mix design. The specimens were vertically and horizontally separated for the direct shear test. The separated specimens were bonded using bituminous material. The objectives of the experiment are to determine the performance of bond and shear properties resulting from slippage, rutting, shovel, and corrugation of asphalt pavements. A machine based on the Louisiana interlayer shear strength tester (LISST) of NCHRP Report-712 was developed to determine the ISS. The applied types of tack coat were RS(C)-4, AP-3, QRS-4, and BD-coat with contents of $0.3{\ell}/m^2$, $0.45{\ell}/m^2$, $0.6{\ell}/m^2$, and $0.8{\ell}/m^2$, respectively. RESULTS : Table 2 gives the results of the direct shear test using the developed shear machine. The BD-coat type indicated the highest average ISS value compared to the others. Between the surface and binder course, optimum tack coat application rates for AP-3, RS(C)-4, QRS-4, and BD-Coat were $0.6{\ell}/m^2$, $0.3{\ell}/m^2$, $0.6{\ell}/m^2$, and $0.45{\ell}/m^2$, respectively. These optimum contents were determined using the ISS value. CONCLUSIONS : The ISS values of AP-3, RS(C)-4, and QRS-4 showed similar tendencies when ISS increased in the range $0.3{\sim}0.6{\ell}/m^2$, while ISS decreased when the applied rate exceeded $0.6{\ell}/m^2$. Similarly, the highest ISS value of the BD-coat was observed when the applied rate was $0.45{\ell}/m^2$. However, shear strength was similar to the maximum value of ISS when the tack-coat application rate of BD-Coat exceeded $0.45{\ell}/m^2$.

• Journal of Astronomy and Space Sciences
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• 제15권1호
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• pp.163-174
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• 1998

To study the origin of organic matter in meteorite, terrestrial rocks which contain or-ganic compounds similar to the ones found in carbonaceous chondrites are studied and compared with Muchison meteorite. Hydrocarbon molecules were extracted by benzene and methanol from bituminous coal and oil shale and the extracts were partitioned into aliphatic, aromatic, and polar fractions by silica gel column chromatography. Carbon isotopic ratios in each fractions were analysed by GC-C-IRMS. Molec-ular compound identifications were carried by GC-MS Engine. Bituminous coal and oil shale show the organic compound composition similar to that of meteorite. Oil shale has a wide range of ${\delta}^{13}C,-20.1%_0~-54.4%_0$ compared to bituminous coal, $-25.2%_0~34.3%_0$. Delta values of several molecular compounds in two terrestrial samples are different. They show several distinct distributions in isotopic ratios compared to those of meteorite; Murchison meteorite has a range of ${\delta}^13C\;from\;-13%_0\;to\;+30%_0$. These results provide interpretation for the source and the formation condition of each rock, in particular alteration and migration processes of organic matter. Especially, they show an important clue whether some hydrocarbon molecules observed in meteorite are indigenous or not.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.107-109
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• 2012

In Korean coal power plants, rising coal prices have recently led to the rapid utilization of low lank coals such as sub-bituminous coal with low calorific values and low ash fusion temperatures. Using these coals beyond the design range has resulted in important issues including slagging and fouling, which cause negative effects in boiler performances and unstable operations. The purpose of this study is to observe slagging and fouling characteristics resulted from burning various ranks of pulverized coals. We have tested 3 different coals: FLAME(bituminous), KCH(sub-bituminous) and MOOLARBEN(bituminous)coals in the pilot system $50kW_{th}$ scale. A stainless steel tube with preheated air inside was installed in the downstream in order to simulate water wall. Collected ash on the probe and the slag inside the furnace near burner were analyzed by SEM (scanning electron microscopy) to verify the formation degree, surface features and color changes of the pasty ash particles. Induced coupled plasma and energy dispersive X-ray spectroscopy were also performed to figure out the chemical characteristics of collected samples. As a result, KCH was observed that more slag was developed inside the walls of the furnace and on the probe than the other two kinds of coals, as shown in the calculate slagging and fouling indices as well.

• International Journal of Railway
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• 제2권1호
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• pp.1-7
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• 2009

The development of structural solutions for high-speed or very high-speed tracks that minimize total life cycle costs of the system is a key issue to improve the operational profitability of new investments. In opposition to conventional ballasted tracks, slab track solutions can be a cost-effective solution, but only in the cases where the benefits due to the increase in track availability and the reduction of track maintenance offsets its much higher construction costs. In the cases where such investment is not feasible, it is worth to evaluate possible structural improvements to ballasted track that allow reducing its maintenance needs without increasing too much its construction costs. This paper evaluates the design requirements and the impact of improving conventional high-speed ballasted tracks by using a bituminous subballast layer. It is divided into two main parts: first the design requirements of the structural solutions with bituminous subballast and its possible benefits on high-speed track deterioration, and secondly the evaluation of the economic impact, in terms of construction costs, of using this structural solution material in future Spanish high-speed lines.

• 에너지공학
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• 제17권3호
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• pp.153-160
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• 2008

유연탄, 무연탄, 그리고 두 탄종의 혼합 비율을 달리한 혼합탄에 대한 열중량 분석을 수행하여 연소반응성을 평가하였다. 무연탄과 유연탄의 혼합탄에 대한 무게 감소율이나 반응속도의 모양을 살펴볼 때 반응시 두 탄종간에 서로 영향을 미치지 않고 혼합 비율에 비례하여 두 탄종이 독립적으로 반응하는 것을 알 수 있었다. 그리고A화력 발전소에서 유, 무연탄을 50% : 50%의 비율로 혼합하고 보일러 출력을 정격대비 약 65%인 134 MW부터 정격부하인 197 MW까지 증대시키면서 보일러 내의 연소상태, 운전특성을 분석하였다. A화력발전소의 연소시험 결과 출력에 따른 보일러내의 연소상태는 전체적으로 양호한 것으로 나타났으며 출력이 증가함에 따라 공기예열기 출구의 배기가스 온도가 설계치인 $430^{\circ}C$를 훨씬 상회하여 연소용 공기의 흡인방법을 변경하여 출구 가스 온도를 조절할 수 있었다.

• 에너지공학
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• 제5권2호
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• pp.170-175
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• 1996

국내 석탄화력발전소에서 사용되고 있는 3종류의 유연탄 및 무연탄에 대해 입자 크기와 CaCO$_3$ 주입에 따른 TGA 분석을 수행하고 활성화에너지를 구하였다. 유연탄의 무게감량 시작온도는 360-38$0^{\circ}C$로 무연탄의 570~$600^{\circ}C$보다 20$0^{\circ}C$정도 낮았다. 유연탄의 활성화에너지는 입도 및 탄종에 따라 14~20kcal/mole 범위이고 무연탄은 37~55 kcal/mole로서 무연탄이 유연탄보다 활성화에너지가 매우 높았다. 석탄의 입도크기가 작아질수록 활성화에너지는 감소하였고 무게감량율과 활성화에너지값은 상관관계가 있었다. 유 무연탄의 유황분대 CaCO$_3$비율을 1:1로 주입시 유연탄은 활성화에너지 변화가 작았으나 무연탄의 경우 1~23 kcal/mole 정도로 활성화에너지가 감소하였다.

• 한국대기환경학회지
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• 제22권1호
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• pp.107-116
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• 2006

The main purpose of this study is to develop the greenhouse gas emission factor for power plant using bituminous coal. The power plant is a major source of greenhouse gases among the sectors of fossil fuel combustion, thus information of its emission factors is very essential to the establishment of control strategies for the greenhouse gas emissions. These emission factors derived in this study were compared with those of U. S. EPA, AGO and CCL. The $CO_{2}$ concentrations in the flue gas were measured using NDIR analyser and the GC-FID with a methanizer. The amount of carbon (C) and hydrogen (H) in fuel was measured using an elemental analyzer. Calorific values of fuel were also measured using a calorimeter. Caloric value of bituminous coal used in the power plants were 5,957 (as received basis), 6,591 (air-dried basis) and 6,960 kcal/kg (dry basis). Our estimates of carbon emission factors were lower than those of IPCC. The CO2 emission factors for the power plants using bituminous coal were estimated to be 0.791 Mg/MWh (by carbon contents and caloric value of the fuel) and 0.771 Mg/MWh (by $CO_{2}$ concentration of the flue gas). The $CO_{2}$ emission factors estimated in this study were $3.4\sim 5.4\%$ and $4.4\sim 6.7\%$ lower than those of CCL (2003) and U. S. EPA (2002).

• 공업화학
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• 제10권4호
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• pp.586-591
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• 1999

유연탄과 무연탄 및 유, 무연탄의 연소특성을 해석하기 위하여 내경 0.109 m의 유동층반응기에서 회분석 석탄주입에 따른 유동화특성과 연소특성 실험을 수행하였다. 온도변화곡선, 압력요동특성치를 이용하여 회분식유동층에서 유연탄과 무연탄 및 혼합석탄의 연소특성을 측정하였다. 유연탄과 무연탄의 입자크기, 두 석탄의 혼합비, 유동화매질의 입자크기에 따른 영향을 고찰하였다. 유연탄과 무연탄의 혼합연소시 무연탄의 혼합비가 30 %인 경우가 유연탄의 연소속도 및 연소거동이 최적으로 나타났다. 저품위 고회분 무연탄의 경우 유동화특성보다 연소특성에 의한 영향이 더욱 크게 나타났다. 또한 유동층의 유동화 특성에 의하여 연소거동이 변화됨을 알 수있었다.