• 제목/요약/키워드: bipolar

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Paper-Based Bipolar Electrochemistry

  • Renault, Christophe;Scida, Karen;Knust, Kyle N.;Fosdick, Stephen E.;Crooks, Richard M.
    • Journal of Electrochemical Science and Technology
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    • 제4권4호
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    • pp.146-152
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    • 2013
  • We demonstrate that carbon electrodes screen-printed directly on cellulose paper can be employed to perform bipolar electrochemistry. In addition, an array of 18 screen-printed bipolar electrodes (BPEs) can be simultaneously controlled using a single pair of driving electrodes. The electrochemical state of the BPEs is read-out using electrogenerated chemiluminescence. These results are important because they demonstrate the feasibility of coupling bipolar electrochemistry to microfluidic paperbased analytical devices (${\mu}PADs$) to perform highly multiplexed, low-cost measurements.

양극파형의 펄스폭 변화에 따른 피에조 구동형 잉크젯 노즐의 액적 토출 특성 (Droplet Formation of a Piezoelectric Inkjet Nozzle According to the Variation of Pulse Widths in Bipolar Waveform)

  • 최성훈;성재용;이명호
    • 한국가시화정보학회지
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    • 제10권1호
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    • pp.9-14
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    • 2012
  • In this study, a piezoelectric inkjet nozzle with a rectangular shaped channel has been developed, and the characteristics of droplet formation have been investigated according to the variation of pulse widths in bipolar waveform. The channel of the nozzle was fabricated transparently by a precision machining technique. A tantalum membrane which was attached to a piezoelectric material covers the channel. By applying two types of bipolar waveforms to the piezoelectric actuators, droplet formation through the nozzle was monitored by a CCD camera. For the variety of the first and second pulse widths in the bipolar waveforms, the regimes of single and double droplet formations are presented. The change of droplet velocity which depends on the pulse width and the type of waveform is also discussed.

고분자전해질 연료전지용 새로운 타입의 복합재료 분리판의 특성연구 (A Study on the Characteristics of New Type of Composite Bipolar Plate for the PEM Fuel Cell)

  • 김종완;이진선;선경복;이중희
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.180-183
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    • 2009
  • Composite bipolar plates offer several advantages of low cost, light weight, and ease of manufacturing compared to traditional graphite plate. However, it is difficult to achieve both high electrical conductivity and high flexural strength. In this study, the hybrid carbons filled epoxy composite bipolar plates were fabricated to test electrical conductivity and flexural properties. Graphite powders were used as the main conducting filler and continuous carbon fiber fabrics were inserted to improve the mechanical properties of the composite. This hybrid composite showed improved in-plane electrical conductivity and flexural property. The moldability of the hybrid composite was also improved comparing to the continuous prepreg composite. This study suggested that the continuous carbon fiber inserted graphite/epoxy composites can be a potential candidate material to overcome the disadvantages of conventional graphite composite or continuous prepreg composite bipolar plates.

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비대칭 바이폴라 펄스 스퍼터법으로 증착된 VN 코팅막의 미세구조, 결정구조 및 기계적 특성에 관한 연구 (Microstructure, Crystal Structure and Mechanical Properties of VN Coatings Using Asymmetric Bipolar Pulsed dc Sputtering)

  • 전성용;정평근
    • 한국표면공학회지
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    • 제49권5호
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    • pp.461-466
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    • 2016
  • Nanocrystalline vanadium nitride (VN) coatings were deposited using asymmetric bipolar pulsed dc sputtering to further understand the influence of the pulsed plasmas on the crystal structure, microstructure and mechanical properties. Properties of VN coatings were investigated with FE-SEM, XRD and nanoindentation. The results show that, with the increasing pulse frequency and decreasing duty cycle, the coating morphology changed from a porous columnar to a dense structure, with finer grains. Asymmetric bipolar pulsed dc sputtered VN coatings showed higher hardness, elastic modulus and residual compressive stress than dc sputtered VN coatings. The results suggest that asymmetric bipolar pulsed dc sputtering technique is very beneficial for the reactive sputtering deposition of VN coatings.

DC 스퍼터법과 비대칭 바이폴라 펄스 DC 스퍼터법으로 증착된 TiN 코팅막의 물성 비교연구 (A Comparative Study of TiN Coatings Deposited by DC and Pulsed DC Asymmetric Bipolar Sputtering)

  • 전성용
    • 한국표면공학회지
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    • 제44권5호
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    • pp.179-184
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    • 2011
  • This work investigated the effect of duty cycle and pulse frequency on the microstructures and properties of titanium nitride thin films deposited by asymmetric bipolar pulsed DC sputtering system. Oscilloscope traces of the I-V waveforms indicate high power and high current density outputs during the asymmetric bipolar pulsed mode. The grain size decreases with decreasing duty cycle. The duty cycle has a strong influence not only on the microstructural properties but also on the mechanical properties of titanium nitride films. Comparing with the continuous DC sputtering, the titanium nitride films prepared by pulsed DC asymmetric bipolar process exhibit better properties.

DC 스퍼터법과 비대칭 바이폴라 펄스 DC 스퍼터법으로 제작된 CrN 코팅막의 물성 비교연구 (A Comparative Study of CrN Coatings Deposited by DC and Asymmetric Bipolar Pulsed DC Sputtering)

  • 전성용;백지원
    • 한국표면공학회지
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    • 제47권2호
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    • pp.86-92
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    • 2014
  • The purpose of this comparative study was to investigate the properties of chromium nitride coatings deposited by asymmetric bipolar pulsed DC sputtering and DC sputtering system. Oscilloscope traces of the I-V waveforms indicate high power and high current density outputs during the asymmetric bipolar pulsed mode. The grain size decreases with decreasing duty cycle. The duty cycle has a strong influence not only on the microstructural properties but also on the mechanical properties of chromium nitride coatings. Comparing with the continuous DC sputtering, the chromium nitride coatings prepared by pulsed DC asymmetric bipolar process also exhibit better surface roughness.

구간값 퍼지집합, Intuitionistic 퍼지집합, Bipolar-valued 퍼지집합의 비교 (Comparison of Interval-valued fuzzy sets, Intuitionistic fuzzy sets, and bipolar-valued fuzzy sets)

  • 이건명
    • 한국지능시스템학회:학술대회논문집
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    • 한국퍼지및지능시스템학회 2001년도 춘계학술대회 학술발표 논문집
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    • pp.12-15
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    • 2001
  • There are several kinds of fuzzy set extensions in the fuzzy set theory. Among them, this paper is concerned with interval-valued fuzzy sets, intuitionistic fuzzy sets, and bipolar-valued fuzzy sets. In interval-valued fuzzy sets, membership degrees are represented by an interval value that reflects the uncertainty in assigning membership degrees. In intuitionistic sets, membership degrees are described with a pair of a membership degree and a nonmembership degree. In bipolar-valued fuzzy sets, membership degrees are specified by the satisfaction degrees to a constraint and its counter-constraint. This paper investigates the similarities and differences among these fuzzy set representations.

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Bipolar Pulse Bias Effects on the Properties of MgO Reactively Deposited by Inductively Coupled Plasma-Assisted Magnetron Sputtering

  • Joo, Junghoon
    • Applied Science and Convergence Technology
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    • 제23권3호
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    • pp.145-150
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    • 2014
  • MgO thin films were deposited by internal ICP-assisted reactive-magnetron sputtering with bipolar pulse bias on a substrate to suppress random arcs. Mg is reactively sputtered by a bipolar pulsed DC power of 100 kHz into ICP generated by a dielectrically shielded internal antenna. At a mass flow ratio of $Ar/O_2$ = 10 : 2 and an ICP/sputter power ratio of 1 : 1, optimal film properties were obtained (a powder-like crystal orientation distribution and a RMS surface roughness of approximately 0.42 nm). A bipolar pulse substrate bias at a proper frequency (~a few kHz) prevented random arc events. The crystalline preferred orientations varied between the (111), (200) and (220) orientations. By optimizing the plasma conditions, films having similar bulk crystallinity characteristics (JCPDS data) were successfully obtained.

H-브리지를 이용한 양극성 금속표면 양극산화장치 개발에 관한 연구 (A study on development of bipolar metal surface anodizing equipment using H-bridge)

  • 양근호
    • 한국전자통신학회논문지
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    • 제6권3호
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    • pp.355-362
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    • 2011
  • 본 논문에서는 특정 용액 내에서 전기분해 원리를 이용하여 금속 표면을 산화시켜 절연피막을 형성하는 장치를 개발한다. 기존에는 주로 양극에만 펄스 형태로 전압을 인가하는 단극성(unipolar) 방식이지만 본 논문에서는 H-브리지를 이용하여 양극에 양(+)전압과 음(-)전압을 번갈아 가면서 공급을 하는 양극성(bipolar) 장치를 제작하여 실험하였다. 공급전류 가변은 PWM 변조를 이용하였으며, (+)와 (-)의 극성변화는 H-브리지를 이용하여 양극성 펄스전압을 공급할 수 있도록 하였다. 그 결과로써 단극성보다 균일한 기공을 갖는 피막이 형성되었다.

고분자전해질 연료전지용 금속분리판의 특성 및 코팅 기술 (Properties and coating technology of metallic bipolar plate for polymer electrolyte fuel cells)

  • 문성모;이수연;권두영
    • 한국표면공학회지
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    • 제55권3호
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    • pp.133-142
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    • 2022
  • This paper reviews bipolar plate materials and coatings for polymer electrolyte fuel cell. First, six roles and 10 requirements of the bipolar plate are described in detail. Secondly, type of materials for the bipolar plate and their advantages and disadvantages are mentioned. Thirdly, different metallic materials are introduced in terms of electrical and thermal conductivities, corrosion resistance, weight, strength and cost. Finally, various types of coating materials and methods were briefly reviewed.