• 한국건설순환자원학회논문집
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• 제8권1호
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• pp.1-10
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• 2013

본 연구에서는 OPC 및 BFS 혼입 콘크리트의 초기재령 압축강도 향상을 위해 산업부산물인 티탄석고, 정수오니를 활용하여 경제성을 만족하면서 콘크리트의 조기강도(재령 1, 3일)를 향상시킬 수 있는 촉진제(이하 HSB) 개발을 위한 기초적 연구를 실시하였다. 조강형 분체의 제조를 위한 산업부산물의 조합 비율은 기초 실험 및 성분분석을 통해 티탄석고(4) : 석회석(3) : 정수오니(3)의 비율로 조합을 확정하였으며, HSB의 혼입률은 사전시험을 거쳐(7~9) %가 적정한 것으로 나타났다. 페이스트 경화체의 SEM 촬영 결과 HSB 혼입을 통한 자극으로 인해 수화반응이 촉진되어 수화생성물이 다량 분포한 것을 SEM 측정을 통해 확인 할 수 있었으며, HSB 혼입 콘크리트 압축강도 측정결과 HSB를 혼입함에 따라 Plain 배합에 비해 초기재령에서 높은 압축강도 발현율을 나타내는 것을 확인할 수 있었다. 또한 GHSB에 비해 FHSB 배합이 더욱 우수한 강도를 나타내었으며, FHSB 치환율이 증가함에 따라 압축강도는 소폭 상승하는 결과를 나타내었다. 한편, HSB 및 혼합시멘트를 사용한 콘크리트의 경우 촉진재 종류에 관계없이 촉진재 치환율 9 %에서 Plain 배합 이상의 조기강도를 발현하는 것으로 나타났으며, 촉진재 종류에 따른 영향을 알아본 결과, GHSB에 비해 FHSB가 재령 1, 3일에는 더욱 우수한 조기강도 발현성능을 나타내었다.

• 공업화학
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• 제23권1호
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• pp.18-22
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• 2012

투명 섬유복합체용 광경화성 바인더로 지환족 골격과 플루오렌계 골격을 갖는 아크릴계 수지 혼합물을 제조하여, 개시제의 종류 및 농도, 광량 등이 바인더의 전환율에 미치는 영향을 조사하였다. ANOVA 분석에 의하면, 바인더의 전환율 증가에는 광량, 개시제의 농도가 주요하였다. 광량에 대해 바인더의 전환율은 거의 선형적으로 증가하였고, 개시제 농도가 증가하게 되면 광량 증가에 따른 전환율 증가는 둔화되었다. FTIR-ATR을 이용하여 측정된 바인더의 평균 전환율은 개시제 농도 5 wt%, 광량 $5\;J/cm^2$의 조건에서는 87% 수준이었다. 옥심 에스테르계 개시제는 전환율 측면에서는 효과적이었으나, 황변현상을 초래하였다. 광경화 필름은 열처리에 의해 전환율이 증가하고, 휘발성 유기물이 제거되어 열안정성이 향상되었다. 한편, 트리메틸벤조일디페닐포스핀 옥시드와 메틸 벤조일포르메이트 혼합개시제 5 wt%, 광량 $5\;J/cm^2$ 조건에서 광경화된 필름은 $230^{\circ}C$, 5분 열처리로 TG% (@$260^{\circ}C$)가 95.4에서 99.0%로 증가하였다.

• 한국결정성장학회지
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• 제31권5호
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• pp.212-217
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• 2021

Silica sol에 YAG 형광체를 첨가량별로 spin 코팅 후, 코팅막의 blue LED에서 백색광이 발현되는 정도와 표면 및 곡면 코팅용 binder로써, 적용가능성을 확인하였다. SEM, PSA를 통해YAG의 입자 크기는 D₅₀: 9~10 ㎛ 내외이며, XRD를 통해 YAG의 결정구조가 garnet(Y₃Al₅O₁₂), cubic인 것을 확인하였다. 코팅막은 crack이 없고 동시에 silica sol이YAG 형광체를 균질하게 도포된 형상을 보였으며, 첨가량 증가와 비례하게 코팅막 내에서 YAG 첨가량과 두께는 최대 40 ㎛까지 증가하는 추세를 보였다. 그리고 YAG 첨가량이 증가할수록 PL emission intensity 증가와 chromatic locus 곡선 끝 방향으로 색좌표 이동을 확인하였다. Soda-lime 유리기판 표면에 코팅 후, crack이 없으며 YAG 형광체가 균질하게 도포된 코팅성과 코팅막의 백색광 발현특성을 확인할 수 있었고 이는 직접적으로 LED에 다양한 형태의 형광 형상의 구현이 가능하다는 것을 의미한다.

• Journal of Information Display
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• 제7권2호
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• pp.6-11
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• 2006

New photopolymers were designed and prepared using the photosensitive polymer binders. Holographic gratings were successfully fabricated in these photopolymer samples by a conventional optical interference method. We also investigated the effect of photocrosslink in the polymer binder on the diffraction behavior of a new photopolymer. The dynamic behavior of the grating formation was monitored by changing exposure intensity in terms of the diffraction efficiency. Particularly, we focused our efforts in observing the variation of diffraction efficiency during a post UV curing process. The surface topographical change of photopolymer layer before and after Vis/UV light exposure was observed by atomic force microscope (AFM). We inscribed the gratings of the glass diffuser on the surface of the photopolymer and investigated their diffusing properties. The diffusers with photopolymer with the main chain polymer binder showed relatively good viewing angle of around ${\pm}30{\circ}$. Two kinds of photopolymer showed similar uniformity of around 47-54%.

• Computers and Concrete
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• 제5권2호
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• pp.89-100
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• 2008

This research examines the engineering properties and color intensities of mortar containing different amounts of fly ash (0, 5, 10 and 20%) mixed at different water-to-binder ratios (w/b = 0.23, 0.47 and 0.59) and exposed at different temperatures (T = 25, 100, 200, 400, 600 and $800^{\circ}C$). Results show that there is greater mass loss on ignition with high w/b and higher temperatures. In addition, the color channel image analyzer (Windows software written in Delphi) is utilized to study the relationship between the curing temperature and intensity of three primary colors, red, green and blue (RGB), of the fly ash mortar specimens. The results show that the RGB intensities on the specimen surface increases from that at $25^{\circ}C$. The mortar specimen becomes white with increase in w/b but without the addition of fly ash. Moreover, for mortar specimens with greater content of fly ash, red on the specimen surface has the greatest increase in intensity at elevated temperature. Observation the variations in color on the specimen surface may help estimate the highest elevated temperatures that concrete structures can withstand.

• Advances in concrete construction
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• 제6권1호
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• pp.29-45
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• 2018

This paper investigates the effect of inclusion of glass fibers on mechanical and fracture properties of binary blend geopolymer concrete produced by using fly ash and ground granulated blast furnace slag. To study the effect of glass fibers, the mix design parameters like binder content, alkaline solution/binder ratio, sodium hydroxide concentration and aggregate grading were kept constant. Four different volume fractions (0.1%, 0.2%, 0.3% and 0.4%) and two different lengths (6 mm, 13 mm) of glass fibers were considered in the present study. Three different notch-depth ratios (0.1, 0.2, and 0.3) were considered for determining the fracture properties. The test results indicated that the addition of glass fibers improved the flexural strength, split tensile strength, fracture energy, critical stress intensity factor and critical crack mouth opening displacement of geopolymer concrete. 13 mm fibers are found to be more effective than 6 mm fibers and the optimum dosage of glass fibers was found to be 0.3% (by volume of concrete). The study shows the enormous potential of glass fiber reinforced geopolymer concrete in structural applications.

• 한국의류산업학회지
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• 제16권2호
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• pp.319-325
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• 2014

This article describes a method for producing chitosan non-woven fabrics by just hot pressing without the use of a binder. A study has been made of the wet spinning of chitosan fiber. The fibers were rinsed thoroughly in running water and chopped wet into staples of with a length of approximately 5-10 mm. The chopped chitosan staples were dispersed uniformly in water and fabricated using a non-woven making machine. This study examined the formation and the characteristics of chitosan non-woven fabrics manufactured by hot pressing without the use of a binder. The effects of the non-woven fabrication conditions on the thermal, morphological, structural, and physical properties of chitosan non-woven fabric with and without water as a plasticizer were studied. The temperature of the exothermic peak, decomposition of chitosan fibers increased with increasing heating rate. Water in the chitosan fiber effectively plasticized the chitosan fiber. The thermal bonded structure of the wet chitosan fiber with water as a plasticizer was clearly found in many parts of the non-woven fabric at a fabrication temperature of $200^{\circ}C$. The intensity and profile of the (100) plane($2{\theta}=10.2^{\circ}$) and (040) plane($2{\theta}=20.9^{\circ}$) in the chitosan non-woven fabric decreases and became smooth in the non-woven fabric formation by melting.

• Journal of Information Display
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• 제5권1호
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• pp.22-27
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• 2004

Photopolymers are quite promising candidates for holographic data storage and diffusers because of their high sensitivity and high refractive index modulation. New photopolymers were prepared using the cellulose ester binder bearing different kinds of monomer. The holographic gratings were elaborated successfully in these photopolymer samples by conventional optical interference method. We investigated the dynamic behavior of the diffraction efficiency and the effect of the functionality of the monomer doped into the polymer binder. Triacrylate monomer doped photopolymer showed the highest diffraction efficiency of around 80-90 %, even under low intensity of writing beam (I=2 mW/$cm^2$). We inscribed the gratings of the glass diffuser on the surface of the photopolymer and investigated their diffusion properties.

• 한국디지털건축인테리어학회논문집
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• 제12권3호
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• pp.59-66
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• 2012

Autoclaved Lightweight Concrete(ALC) features such as a high performance insulation, the fire resistance, the advantage of easy handing construction, and lightweight panels applied the curtain wall system. ALC materials are certified as non-toxic environmental and eco-friendly productions. But ALC external panels mixed with blast furnace slag pounder and silica fume have to be coated with a stucco compound or plaster because of resisting the ambient environment. This study is that mixing tests to evaluate a performance analysis of exterior paints to be make-up pigments(organic or inorganic) coated with panel surface. Testing compared by KS F 2476; flow test, KS F 2426; compression strength test, KS F 2762; bond strength test. In results, the case of the inorganic binder, ratio of alumina cement : anhydrite is 90:10 to 80:20 at the highest level of intensity. In the case of the organic binder, adhesive strength rating at surface of ALC, the pullout strength is below 0.5 $N/mm^2$ but the normal concrete is over 2.0$N/mm^2$. A contents ratio of EVA resin is more than 3% and then bond strength is effectively.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.230-233
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• 2003

New photopolymers were designed and prepared using the photosensitive polymer binders. The photochemical reaction of the photosensitive polymer binder was studied by virtue of UV absorption and infrared spectroscopy. The holographic gratings were successfully fabricated in these photopolymer film samples by conventional optical interference method. We also investigated the effect of photocrosslink in the polymer binder on the diffraction behavior of the photopolymer. The dynamic behaviors of the grating formation were studied with the change of exposure intensity in terms of the diffraction efficiency. Particularly, we focused our efforts to observe the variation of the diffraction efficiency during post UV curing process.