• Clean Technology
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• v.11 no.4
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• pp.165-170
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• 2005

The aim of this study is to provide vapor-liquid equilibrium (VLE) information for the study of process which directly synthesize dimethyl carbonate (DMC) from $CO_2$. For this study we collected some necessary VLE systems data of Methanol-Water, Methanol-DMC, $CO_2$-DMC, $CO_2$-Methanol, $CO_2$-Methanol, and performed VLE calculation with Peng-Robinson equation of state, Wong-Sandler mixing rules that widely used in chemical industry. These calculation results relatively agreed with VLE data well. Optimized Parameters of EoS given through this calculation will be used as some valuable information for fundamental study, process development and process optimization of DMC direct synthesis.

• Korean Journal of Food Science and Technology
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• v.27 no.4
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• pp.439-444
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• 1995

Preparative conditions and characteristics of six-vegetable and fruit juice were studied for the effects of mixing ratio, heat treatment and addition of sugar, salt and organic acid. The vegetables and fruit used were carrot(Ct), cabbage(Cg), pear(Pr), cucumber(Cr), celery(Cy) and dongchimi(Di). From the sensory results of mixing ratio of three of binary mixtures of Cg-Pr(1:3):Ct-Di(1:4):Cr-Cy(3:1), two ratios of 5.0:2.5:2.5(V-6A) and 6.0:2.0:2.0(V-6B) were suggested optimal for six-vegetable and fruit juice. Addition of 2% sucrose and 0.3% NaCl improved the preference significantly. The pH 4.0 for V-6A and pH 3.5 for V-6B were more prefered when pH was adjusted by citric acid. Heating the juice at $100^{\circ}C$ for 100 minutes slightly decreased pH and increased the acidity. Total solids and viscosity were also decreased by heating. All of those changes were more significant in V-6B than V-6A, probably due to lower pH. Heating the juice resulted in a slight decrease in L value and an increase in a and b values. Heating at $100^{\circ}C$ caused an increase in moldy flavor and a decrease in fresh vegetable flavor while heating at $80^{\circ}C$ for 20 minutes changed them little.

• Journal of the Korean Chemical Society
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• v.40 no.5
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• pp.327-332
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• 1996

The rates of solvolylsis of methyl chloroformate, phenyl chloroformate and 1-adamantyl derivatives in binary solvent mixtures have been measured by conductometric method at various temperatures and pressures. The activation parameters were estimated from the rate constants. The activation volume (${\Delta}V_o^{\neq}$) and the activation entropy (${\Delta}S^{\neq}$) are both negative, but the activation enthalpy (${\Delta}H^{\neq}$) is positive. This behavior is discussed in terms of electrostriction of solvation. The reactivities of these reactions were also estimated from the correlation of the activation volumes with the activation entropies. From these results, it could be estimated that the solvolyses of 1-adamantyl fluoroformate (in aqueous TFE) and 1-adamantyl tosylate have pathway involving unimolecular reaction, while the reaction of methyl chloroformate, phenyl chloroformate and 1-adamantyl fluoroformate (in aqueous alcohol) proceed through a bimolecular reaction.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.10
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• pp.883-890
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• 2005

In this study, 2 pure hydrocarbon refrigerants of R1270 (Propylene) and R290 (Propane) and 3 binary mixtures composed of R1270, R29O and R152a were tested in a refrigerating bench tester with a scroll compressor in an attempt to substitute R502 used in most of the low temperature applications. The test bench provided 3\sim3.5$ kW capacity and water and water/glycol mixture were employed as the secondary heat transfer fluids. All tests were conducted under the same external conditions resulting in the average saturation temperatures of -28 and $45^{\circ}C$ in the evaporator and condenser, respectively. Test results showed that all refrigerants tested had $9.6\sim18.7\%$ higher capacity and $17.1\sim27.3\%$ higher COP than R502. The compressor discharge temperature of R1270 was similar to that of R502 while those of all other refrigerants were $23.7\sim27.9\%$ lower than that of R502. For all alternative refrigerants, the amount of charge was reduced up to $60\%$ as compared to R502. Overall, these alternative refrigerants offer better system performance and reliability than R502 and can be used as long term substitutes for R502 due to their excellent environmental properties.

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.205-211
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• 2010

The water-sewage cohesion agent(polyaluminumchloride(PAC)) and NaOH were used to synthesize $Al(OH)_3$. For various additions of NaOH, characteristics of the synthesized $Al(OH)_3$ was analysed by XRD, SEM and PSA. According to XRD analysis, small amount of NaOH(NaOH:PAC=15g:100g) resulted in amorphous form of $Al(OH)_3$. By increasing NaOH(NaOH:PAC=20g:100g), the mixture of gibbsite(37%), bayerite(35%) and boehmite(28%) were produced. By adding more NaOH(NaOH:PAC=25g:100g), binary mixtures of gibbsite(67%) and bayerite(33%) were formed. Finally, high addition of NaOH(NaOH:PAC=30g:100g) gave the high concentration of gibbsite(gibbsite:bayerite=83:17). Also, SEM analysis indicated that the product featured the plate form with 20 and 30g of NaOH addition. Furthermore it was found that the particle size of the product decreased with the addition of NaOH.

• Journal of the Korean Institute of Gas
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• v.19 no.5
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• pp.54-60
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• 2015

The autoignition temperature (AIT) of a material is the lowest temperature at which the material will spontaneously ignite. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs of n-decane+ethylbenzene system by using ASTM E659 apparatus. The AITs of n-decane and ethylbenzene which constituted binary system were $210^{\circ}C$ and $430^{\circ}C$, respectively. The experimental AITs of n-decane+ethylbenzene mixture were a good agreement with the calculated AITs by the proposed equations with about $11^{\circ}C$ A.A.D.(average absolute deviation).

• Resources Recycling
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• v.7 no.4
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• pp.64-75
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• 1998

The purpose of this study is to produce high putity composite powder composed of Fe-oxide, Mn-oxide and Mn-ferrite having superior homogencity in composition and particle size distribution by co-roasting process. Binary component metal (Fe, Mn) chloride solutions were produced by dissolving mill scale and ferro-mangancse alloy in hydrochloric acid. These chloride solutions contained the impurities such as SiO$_{2}$, P, Al, Ca and Na, which were originated from the Fe/Mn source materials. The neutralization and polymeric coagulant method were adoped to refine the hydrochloric liquor. When pH is far below the isoelectric point (pH 2-3), the SiO$_{2}$ was the most effectively reduced element, while other impurities remained unchanged. By increasing pH above 3, most of the impurities could be reduced effectively due to the coprecipitation reaction. The polymeric coagulants such as poly vinyl alcohol, resin amine and ammonium molybdate were found to have no effect on the spray roaster designed by the authors. The produced oxide powders were confirmed to be mixtures of Fe-oxide, Mn-oxide and mn-ferrite. the powders were homogeneously mixed and the particle size increased sleeply with increasing co-roasting temperature.

• Elastomers and Composites
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• v.39 no.4
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• pp.318-323
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• 2004

Cloud-point and bubble-point curves for poly(ethylene-co-13.8 mol% octene) ($PEO_{13.8}$) and Poly(ethylene-co-15.3 mol% octene) ($PEO_{15.3}$) were determined up to $150^{\circ}C$ and 450 bar in hydrocarbons which have different molecular size and structure. Whereas ($PEO_{15.3}$+ n-pentane) system has cloud-point and bubble-point type transitions, ($PEO_{15.3}$+ n-propane) and ($PEO_{15.3}$+ n-butane) systems do only cloud-point type transition. In cyclo-pentane, -hexane, -heptane, and -octane, $PEO_{15.3}$ has a bubble-point transition. ($PEO_{13.8}$+ n-butane) mixture has a critical mixture concentration at 5 wt% PEO. (PEO + hydrocarbon) mixtures exhibit LCST type behavior. Solubility of PEO increases with hydrocarbon size due to increasing dispersion interaction which is favorable to dissolve PEO.

• Korean Journal of Materials Research
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• v.31 no.9
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• pp.532-538
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• 2021

In this study, a spray dryer is used to make granules of Y₂O₃ and YF₃, and then Y₅O₄F₇ is synthesized following heat treatment of them under Ar gas atmosphere at 600 ℃. Single and binary monomer mixtures are compared and analyzed to optimize photocurable monomer system for DLP 3D printing. The mixture of HEA and TMPTA at 8:2 ratio exhibits the highest photocuring properties and low viscosity with shear thinning behavior. The optimized photocurable monomer and synthesized Y₅O₄F₇ are therefore mixed and applied to printing process at variable solid contents (60, 70, 80, & 85 wt.%) and light exposure times. Under optimal light exposure conditions (initial exposure time: 1.2 s, basic exposure time: 5 s), YOF composites at 60, 70 & 80 wt.% solid contents are successfully printed. As a result of measuring the size of the printed samples compared to the dimensions of the designed bar type specimen, the deviation is found to increase as the YOF solid content increases. This shows that it is necessary to maximize the photocuring activity of the monomer system and to optimize the exposure time when printing using a high-solids ceramic slurry.

• Journal of the Korean Chemical Society
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• v.47 no.5
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• pp.479-486
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• 2003

In this study, poly(DL-lactide-co-glycolide) nanoparticles loaded with water-insoluble vitamins such as vitamin A (Retinol) and vitamin E acetate were prepared by the emulsification diffusion method. Polymer solution was prepared by the two water-miscible organic solvent, such as ethanol and acetone. Because of its biocompatible property, polyethyleneglycol-polypropyleneglycol diblock copolymer was used as surfactant and stabilizer. The influence of some preparative variables on the nanoparticle formation and on the loading efficiency of active agents, such as the type and concentration of stabilizing agent, the stirring methods, the water/oil phase ratio and the polymer concentration were investigated in order to control and optimize the process. After preparation of nanoparticles loaded with active agent, particle size and distribution were evaluated by the light scattering particle analyzer. The loading efficiency of active agents was evaluated by the UV-visible spectroscopy. As the results, particle size were 50-200 nm and dispersibility was monodisperse. The optimum loading efficiency of active agents was observed 50-60%. It was found that the appropriate of selections of binary solvent mixtures and polymeric concentrations in both organic and aqueous phases could provide good yield and favorable physical properties of PLGA nanoparticles.