• 제목/요약/키워드: bilayer film

검색결과 108건 처리시간 0.028초

Pentacene based organic thin film transistor on aqueous media for biosensor

  • 이동준;채승근;권오준;정병준
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.210.2-210.2
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    • 2015
  • 유기 박막 트랜지스터(Organic Thin Film Transistor, OTFT)기반의 바이오센서는 저비용 제작 및 플렉서블 소자 제작이 가능하여 많은 주목을 받아오고 있다. 본 연구에서는, hexamethyldisilazane (HMDS) 표면 처리된 $Si/SiO_2$ 기판 위에 진공 증착 공정을 이용하여 pentacene 기반의 OTFT를 제작한 후, 수용성 매체에 대한 안정성을 향상시키기 위하여 저분자 물질인 tetratetracontane (TTC)를 진공 증착 공정을 이용하여 증착하였으며, cyclized perfluoropolymer (CYTOP)을 용액 공정으로 코팅하여 bilayer의 passivation 층을 형성하였다. 실제 제작된 OTFT의 수용성 매체에 대한 안정성을 테스트하기 위하여 소자에 수용성 phosphate buffered saline (PBS)용액을 투하하여 10분에 걸쳐 1분 간격으로 transistor의 transfer 특성을 측정하였다. 또한 측정된 $I_d-V_g$ 곡선 데이터를 이용하여 시간에 따른 드레인 전류, 이동도, 문턱 전압, 점멸비 등의 수치를 산출하였다. 그리고, 그 $I_d-V_g$ 곡선 데이터와 산출된 데이터들을 증류수가 투하된 OTFT 소자의 $I_d-V_g$ 곡선 데이터와 산출된 데이터들과 비교하였다. 결론적으로, TTC/Cytop bilayer passivation 층이 형성된 OTFT 소자는 인체 내 혈액의 pH와 유사한 PBS 용액 하에서도 안정적인 구동 성능을 보여 바이오센서로 응용될 수 있는 가능성이 있다는 결론을 얻었다.

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메탈 이중층 전극을 이용한 유기 박막 트랜지스터의 성능향상 (High-Performance Organic Thin-Film Transistors with Metal Bilayer Electrodes)

  • 형건우;양진우;이호원;구자룡;황진하;김영관
    • 한국응용과학기술학회지
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    • 제27권1호
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    • pp.50-55
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    • 2010
  • 본 논문은 메탈 이중층 전극을 이용한 유기 박막 트랜지스터를 제작하여 Au나 Ag 금속만으로 제작한 일반적인 유기 박막 트랜지스터와의 전기적 특성을 비교하였다. 전기적 특성에서 게이트 절연층은 높은 K 값을 갖는 $Al_2O_3$를 사용하였고, 유기 반도체층은 펜타센을 사용하였다. 본 실험에서 제작한 유기 박막 트랜지스터는 $1.6 \;{\times}\;10^{-1}\;cm^2$의 포화영역 이동도를 얻을 수 있었으며, 또한 드레인 전압을 -5V로 하고, 게이트 전압을 3 V에서 -10 V 까지 인가하였을 때 $3{\times}10^5$의 전멸 비를 얻을 수 있었다.

감마선 검출을 위한 초전도 상전이 센서 (Development of Superconducting Transition Edge Sensors for Gamma Ray Detection)

  • 이영화;김용함
    • Progress in Superconductivity
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    • 제9권2호
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    • pp.162-166
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    • 2008
  • We are developing a sensitive gamma ray spectrometer based on superconducting transition edge sensors. The detector consists of a small piece of high purity Sn as an absorber and a Ti/Au bilayer as a temperature sensor. It is designed to measure the thermal signal caused by absorption of gamma rays. The mechanical support and the thermal contact between the absorber and the thermometer were made with Stycast epoxy. The bilayer was formed by e-beam evaporation and patterned by wet etching on top of a $SiN_X$ membrane. A sharp superconducting transition of the film was measured near 100 mK. When the film was biased to the edge of the transition, signals were observed due to single photon absorption emitted from an $^{241}Am$ source. The measured spectrum showed several characteristic peaks of the source including 59.5 keV gamma line. The full with at half maximum was about 900 eV for the 59.5 keV gamma line. The background was low enough to resolve low energy lines. Considerations to improve the energy resolution of the gamma ray spectrometer are also discussed.

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Ga 극초박막의 계면특성과 초전도 물성제어에 대한 연구 (Interface Engineering in Superconducting Ultra-thin Film of Ga)

  • 이년종;김태희
    • 한국자기학회지
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    • 제20권6호
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    • pp.212-215
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    • 2010
  • 비정질 Ga 박막은 벌크에 비해 높은 초전도 임계온도와 임계자기장 값을 보이나 그 특성은 불안정하여 상온에 한번 노출되면 그 초전도 특성을 잃어버리게 된다. 이 논문에서는 Ga/Al 두층 박막을 제작하여 이러한 비정질 Ga 박막의 불안정한 초전도 특성을 개선할 뿐만 아니라 기존의 스핀검출에 응용되고 있는 Al 박막을 대체할 수 있는 가능성을 연구하였다. 극초진공 분자빔박막 증착장비(UHV-MBE)를 사용하여 Ga/Al 두층 박막을 제작하고, 표면의 적절한 플라즈마 산화 처리에 의한 Ga/Al/$Al_2O_3$/Fe의 터널 접합구조를 제작하여 Ga/Al 박막의 초전도 특성을 측정하였다. 한편, Ga/Al 박막의 표면 특성은 Auger 전자 분광기를 이용하여 분석하였다.

The Interfacial Electronic Structure of Organic-organic Heterojunction: Effect of Molecular Orientation

  • 조상완
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.114.2-114.2
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    • 2014
  • The orientation of the constituent molecules in organic thin film devices can affect significantly their performance due to the highly anisotropic nature of ${\pi}$-conjugated molecules. We report here an angle dependent x-ray absorption study of the control of such molecular orientation using well-ordered interlayers for the case of a bilayer heterojunction of chloroaluminum phthalocyanine (ClAlPc) and C60. Furthermore, the orientation-dependent energy level alignment of the same bilayer heterojunction has been measured in detail using synchrotron radiation-excited photoelectron spectroscopy. Regardless of the orientation of the organic interlayer, we find that the subsequent ClAlPc tilt angle improves the ${\pi}-{\pi}$ interaction at the interface, thus leading to an improved short-circuit current in photovoltaic devices based on ClAlPc/C60. The use of the interlayers does not change the effective band gap at the ClAlPc/C60 heterointerface, resulting in no change in open-circuit voltage.

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이중층 몰리브데늄을 후면전극으로 적용한 비진공법 CuInSe2 태양전지의 특성 (Characterization of Non-vacuum CuInSe2 Solar Cells Deposited on Bilayer Molybdenum)

  • 황지섭;윤희선;장윤희;이장미;이도권
    • Current Photovoltaic Research
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    • 제8권2호
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    • pp.45-49
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    • 2020
  • Molybdenum (Mo) thin films are widely used as back contact in copper indium diselenide (CISe) solar cells. However, despite this, there are only few published studies on the properties of Mo and characteristics of CISe solar cells formed on such Mo substrates. In this studies, we investigated the properties of sputter deposited Mo bilayer, and fabricated non-vacuum CISe solar cells using bilayer Mo substrates. The changes in surface morphology and electrical resistivity were traced by varying the gas pressure during deposition of the bottom Mo layer. In porous surface structure, it was confirmed that the electrical resistivity of Mo bilayer was increased as the amount of oxygen bonded to the Mo atoms increased. The resulting solar cell characteristics vary as the bottom Mo layer deposition pressure, and the maximum solar cell efficiency was achieved when the bottom layer was deposited at 7 mTorr with a thickness of 100 nm and the top layer deposited at 3 mTorr with a thickness of 400 nm.

신축성있는 Ag 나노와이어 전극의 제조 및 전기변색 응용 (Fabrication of Stretchable Ag Nanowire Electrode and its Electrochromic Application)

  • 이진영;한송이;나윤채;박종운
    • 한국재료학회지
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    • 제29권2호
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    • pp.87-91
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    • 2019
  • We report on stretchable electrochromic films of poly(3-hexylthiophene) (P3HT) fabricated on silver nanowire (AgNW) electrodes. AgNWs electrodes are prepared on polydimethylsiloxane (PDMS) substrates using a spray coater for stretchable electrochromic applications. On top of the AgNW electrode, poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is introduced to ensure a stable resistance over the electrode under broad strain range by effectively suppressing the protrusion of AgNWs from PDMS. This bilayer electrode exhibits a high performance as a stretchable substrate in terms of sheet resistance increment by a factor of 1.6, tensile strain change to 40 %, and stretching cycles to 100 cycles. Furthermore, P3HT film spin-coated on the bilayer electrode shows a stable electrochromic coloration within an applied voltage, with a color contrast of 28.6 %, response time of 4-5 sec, and a coloration efficiency of $91.0cm^2/C$. These findings indicate that AgNWs/PEDOT:PSS bilayer on PDMS substrate electrode is highly suitable for transparent and stretchable electrochromic devices.

Silver Nanowire 기반 Stretchable 투명 전극 (Silver Nanowire-based Stretchable and Transparent Electrodes)

  • 이진영;김수연;정다혜;신동균;유수호;서화일;박종운
    • 반도체디스플레이기술학회지
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    • 제14권3호
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    • pp.51-55
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    • 2015
  • We have fabricated silver nanowire (AgNW) films as a stretchable and transparent electrode on polydimethylsiloxane (PDMS) substrates using a spray coater. Inherently, they show poor surface roughness and stretchability. To tackle it, we have employed a conductive polymer, poly (3,4-ethylenedioxythiophene) : Poly(styrene sulfonate) (PEDOT : PSS). PEDTO : PSS solution is mixed with AgNWs or spin-coated on the AgNW film. Compared with AgNW film only, PEDOT : PSS film only, and polymer-mixed AgNW films, the AgNW/polymer bilayer films exhibit much better surface roughness and stretchability. It is found that spray-coating of AgNWs on uncured PDMS and spin-coating of PEDOT : PSS solution on the AgNW films enhance the surface roughness of electrodes. Such a bilayer structure also provides a stable resistance under tensile strain due to the fact that each layer acts as a detour route for carriers. With this structure, we have obtained the peak-to-peak roughness ($R_{pv}$) as low as 76.8nm and a moderate increase of sheet resistance (from $10{\Omega}/{\Box}$ under 0% strain to $30{\Omega}/{\Box}$ under 40% strain).

고유전율 절연체를 활용한 저 전압 유연 유기물 박막 트랜지스터 (Low-voltage Organic Thin-film Transistors with Polymeric High-k Gate Insulator on a Flexible Substrates)

  • 김재현;배진혁;이인호;김민회
    • 센서학회지
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    • 제24권3호
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    • pp.165-168
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    • 2015
  • We demonstrated low-voltage organic thin-film transistors (OTFTs) with bilayer insulators, high-k polymer and low temperature crosslinkable polymer, on a flexible plastic substrate. Poly (vinylidene fluoridetrifluoroethylene) (P(VDF-TrFE)) and poly (2-vinylnaphthalene) are used for high-k polymer gate insulator and low temperature crosslinkable polymer insulators, respectively. The mobility of flexible OTFTs is $0.17cm^2/Vs$ at gate voltages -5 V after bending operation.