• Title/Summary/Keyword: bilayer

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Performance Characterization of Polyaniline Coated Electro-Active Paper Actuator (폴리아닐린이 코팅된 Electro-Active Paper 작동기 성능평가)

  • Ko, Hyun-U;Mun, Seong Cheol;Zhai, Lindong;Kim, Ki-Baek;Kim, Jaehwan
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.6
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    • pp.658-664
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    • 2013
  • Bending actuators composed of cellulose with an electrically conducting polymer (CP) are fabricated and their performance is characterized in the air. Two different counter ions, perchlorate and tetrafluoroborate are used as dopant ions in the polyaniline CP processing. CP-cellulose-CP trilayer and CP-cellulose bilayer samples are fabricated with different dopant ions, and their actuation performance is evaluated in terms of tip displacement, blocked force and electrical power consumption along with the humidity level and actuation frequency. The trilayer samples substantially enhanced the tip displacement compared to the bilayer ones. The actuation performance of the trilayer actuator is three times better than that of original cellulose electro-active paper (EAPap) actuator. The displacement and blocked force of CP-EAPap actuators are dependent on the humidity and frequency.

Solution processed organic photodetector utilizing an interdiffused polymer/fullerene bilayer

  • Shafian, Shafidah;Jang, Yoonhee;Kim, Kyungkon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.348-348
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    • 2016
  • Low dark current (off-current) and high photo current are both essential for a solution processed organic photodetector (OPD) to achieve high photo-responsivity. Currently, most OPDs utilize a bulk heterojunction (BHJ) photo-active layer that is prepared by the one-step deposition of a polymer:fullerene blend solution. However, the BHJ structure is the main cause of the high dark current in solution processed OPDs. It is revealed that the detectivity and spectral responsivity of the OPD can be improved by utilizing a photo-active layer consisting of an interdiffused polymer/fullerene bilayer (ID-BL). This ID-BL is prepared by the sequential solution deposition (SqD) of poly(3-hexylthiophene) (P3HT) and [6,6] phenyl C61 butyric acid methyl ester (PCBM) solutions. The ID-BL OPD is found to prevent undesirable electron injection from the hole collecting electrode to the ID-BL photo-active layer resulting in a reduced dark current in the ID-BL OPD. Based on dark current and external quantum efficiency (EQE) analysis, the detectivity of the ID-BL OPD is determined to be $7.60{\times}1011$ Jones at 620 nm. This value is 3.4 times higher than that of BHJ OPDs. Furthermore, compared to BHJ OPDs, the ID-BL OPD exhibited a more consistent spectral response in the range of 400 - 660 nm.

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Pentacene based organic thin film transistor on aqueous media for biosensor

  • Lee, Dong-Jun;Chae, Seung-Geun;Gwon, O-Jun;Jeong, Byeong-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.210.2-210.2
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    • 2015
  • 유기 박막 트랜지스터(Organic Thin Film Transistor, OTFT)기반의 바이오센서는 저비용 제작 및 플렉서블 소자 제작이 가능하여 많은 주목을 받아오고 있다. 본 연구에서는, hexamethyldisilazane (HMDS) 표면 처리된 $Si/SiO_2$ 기판 위에 진공 증착 공정을 이용하여 pentacene 기반의 OTFT를 제작한 후, 수용성 매체에 대한 안정성을 향상시키기 위하여 저분자 물질인 tetratetracontane (TTC)를 진공 증착 공정을 이용하여 증착하였으며, cyclized perfluoropolymer (CYTOP)을 용액 공정으로 코팅하여 bilayer의 passivation 층을 형성하였다. 실제 제작된 OTFT의 수용성 매체에 대한 안정성을 테스트하기 위하여 소자에 수용성 phosphate buffered saline (PBS)용액을 투하하여 10분에 걸쳐 1분 간격으로 transistor의 transfer 특성을 측정하였다. 또한 측정된 $I_d-V_g$ 곡선 데이터를 이용하여 시간에 따른 드레인 전류, 이동도, 문턱 전압, 점멸비 등의 수치를 산출하였다. 그리고, 그 $I_d-V_g$ 곡선 데이터와 산출된 데이터들을 증류수가 투하된 OTFT 소자의 $I_d-V_g$ 곡선 데이터와 산출된 데이터들과 비교하였다. 결론적으로, TTC/Cytop bilayer passivation 층이 형성된 OTFT 소자는 인체 내 혈액의 pH와 유사한 PBS 용액 하에서도 안정적인 구동 성능을 보여 바이오센서로 응용될 수 있는 가능성이 있다는 결론을 얻었다.

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Multiferroic properties of $Fe/BaTiO_3$ bilayer films ($Fe/BaTiO_3$ 이중박막의 다강성 연구)

  • Kim, Kyung-Man;Lee, Jai-Yeoul;Lee, Hee-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.175-175
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    • 2009
  • 최근 전자 소자의 소형화 집적화에 따른 대응 방안으로 한 개의 소자에 두가지 이상의 물리적 특성을 갖는 다기능성 소재의 개발에 많은 연구가 진행되고 있다. 다강체는 강유전성 (ferroelectricty ), 강자성 (ferromagnetism), 강탄성 (ferroelasticity) 중에서 두 개 이상의 현상을 나타내는 재료로, 이중에서도 특히 강유전성과 강자성을 동시에 나타내는 다강체가 학계 및 산업계로부터 집중적인 관심을 받으면서 최근 이 분야 연구가 국내 외적으로 매우 활발하게 이루어지고 있다. 이는 다강체를 이용하면 기존의 강유전 현상을 이용한 메모리소자인 FRAM이나 차세대 메모리소자로 주목을 받고 있는 MRAM을 결합한 새로운 방식의 메모리소자의 탄생이 가능할 수도 있기 때문이다. 즉, 일부 다강체가 나타내는 magnetoelectric (ME) 현상을 이용하면 자기적으로 신호를 인가하여 전기신호로 데이터를 저장하거나 또는 전기적으로 신호를 인가하여 자기적으로 데이터를 저장하는 것이 가능해지기 때문이다. 이 연구에서는 다강체 특성을 가지는 $Fe/BaTiO_3$ 이중박막을 IBSD(Ion Beam Sputter Deposition)을 이용하여 (111)Pt/Ti/$SiO_2/Si$ 기판에 증착을 하여 구조적, 전기적, 자기적 특성을 토론할 것이다.

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A solid-state NMR study on the activity of an antimicrobial peptide, magainin 2 (항균성 펩타이드인 magainin 2의 활성에 대한 고체 핵자기 공명 분광 연구)

  • Kim, Chul
    • Analytical Science and Technology
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    • v.24 no.6
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    • pp.460-466
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    • 2011
  • The activity of an antimicrobial peptide, magainin 2, on lipid membranes was investigated using solid-state NMR and a new sampling method that employed mechanically aligned bilayers between thin glass plates. The experiments were performed at two hydration levels. At 95% hydration about 15% of the lipid bilayers were disrupted and at full hydration 20% were disrupted. From the comparison of two equilibrium states established by two sampling methods the importance of peptide binding to the lipid bilayer for whole membrane disruption was demonstrated.

Morphology and Electrical Properties of Back Electrode for Solar Cell Depending on the Mo : Na/Mo Bilayer Thickness (Mo : Na/Mo 이중층 구조 두께에 따른 태양전지 후면전극의 조직 및 전기적 특성)

  • Shin, Younhak;Kim, Myunghan
    • Korean Journal of Materials Research
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    • v.23 no.9
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    • pp.495-500
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    • 2013
  • Mo-based thin films are frequently used as back electrode materials because of their low resistivity and high crystallinity in CIGS chalcopyrite solar cells. Mo:Na/Mo bilayer thin films with $1{\mu}m$ thickness were deposited on soda lime glass by varying the thickness of each layer using dc-magnetron sputtering. The effects of the Mo:Na layer on morphology and electrical property in terms of resistivity were systematically investigated. The resistivity increased from $159{\mu}{\Omega}cm$ to $944{\mu}{\Omega}cm$; this seemed to be caused by increased surface defects and low crystallinity as the thickness of Mo:Na layer increased from 100 nm to 500 nm. The surface morphologies of the Mo thin films changed from a somewhat coarse fibrous structures to irregular and fine celled structures with increased surface cracks along the cell boundaries as the thickness of Mo:Na layer increased. Na contents varied drastically from 0.03 % to 0.52 % according to the variation of Mo:Na layer thickness. The change in Na content may be ascribed to changes in surface morphology and crystallinity of the thin films.

Dual Effects of Nitric Oxide on the Large Conductance Calcium-activated Potassium Channels of Rat Brain

  • Lee, Ji-Eun;Kwak, Ji-Yeon;Suh, Chang-Kook;Shin, Jung-Hoon
    • BMB Reports
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    • v.39 no.1
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    • pp.91-96
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    • 2006
  • Previously, we have shown that nitric oxide (NO) directly activates the Maxi-K channels. In the present study, we have investigated whether NO has prolonged effects on the Maxi-K channels reconstituted in lipid bilayer. Application of S-nitroso-N-acetyl-D, L-penicillamine (SNAP), a NO donor, induced an immediate increase of open probability (Po) of Maxi-K channel in a dose-dependent manner. When SNAP was removed from the cytosolic solution, the Po did not simply returned to, but irreversibly decreased to a level lower than that of the control Po. At 0.2 mM, (Z)-[N-(3-Ammoniopropyl)-N-(n-propyl)amino] diazen-1-ium-1,2-diolate (PAPA-NO), another NO donor, produced a similar increase of Po and decrease of Po upon washout. The increasing effects of SNAP on Po were not blocked by either 50 U/ml superoxide dismutase (SOD) or 2 mM N-ethylmaleimide (NEM) pre-treatments. However, NEM appears to be ineffective when applied after SNAP. These results suggest that NO can modulate Maxi-K channel via direct interaction and chemical modification, such as S-nitrosylation in the brain.

Control of Surface Energy using Bilayer Metallic Film Heterostructures

  • Kim, Chang-Lae;Kim, Dae-Eun;Kim, Hae-Jin
    • Tribology and Lubricants
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    • v.35 no.6
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    • pp.350-355
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    • 2019
  • Surface energy is an important factor in determining the performance of application components in terms of preventing adhesion failure between thin films. In this regard, numerous attempts have been made to acquire the desired surface energy through chemical treatment or by using micro/nanostructures. However, such approaches are expected to provide extreme values of surface energy, which may not be suitable in achieving the enhanced performance of applications. In this study, we propose a method to control surface energy by using bilayer metallic film heterostructures. We measure the water contact angle of incompatible (Ni/Ag) and compatible (Zn/Ag) metal pairs under several experimental factors, including thickness, time, and temperature. Furthermore, we conduct Auger electron spectroscopy measurements to investigate the atomic concentration with respect to depth after the change in the water contact angle. The experimental results reveal that three parameters, namely, compatibility, film thickness, and environmental temperature, are major factors in controlling the water contact angle. Thus, we experimentally demonstrate that controlling these three parameters can provide the approximate desired water contact angle. This result is expected to aid in the performance enhancement of a wide range of application components, where control of surface energy is required.

Synthesis and Characterization of Intercalation Compounds of Alkylsulfonate into Hydrated and Dehydrated Zinc (수화된 아연과 탈수된 아연에 알킬술폰이 층간 삽입된 화합물의 합성과 구조)

  • Huh, Young Duk;Park, Sung Hun;Jun, Tae Hyun;Park, Yong Jun;Park, Yang Sun
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.338-345
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    • 2000
  • The intercalated compounds of alkylsulfonate into hydrated and dehydrated zinc were synthesized. From the XRD, FT-IR, TGA, elemental analysis data, and the molecular size, the orientation of the intercalated alkylsulfonates was determined. For the hydrated compounds, alkylsulfonates were intercalated into hexaqua zinc layer with the bilayer structure of $32.9^{\circ}$ angle of inclination. For the dehydrated compounds, alkylsulfonates were directly bonded to zinc ion with the bilayer structure of $51.4^{\circ}$ angle of inclination.

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High-Performance Organic Thin-Film Transistors with Metal Bilayer Electrodes (메탈 이중층 전극을 이용한 유기 박막 트랜지스터의 성능향상)

  • Hyung, Gun-Woo;Yang, Jin-Woo;Lee, Ho-Won;Koo, Ja-Ryong;Hwang, Jin-Ha;Kim, Young-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.1
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    • pp.50-55
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    • 2010
  • 본 논문은 메탈 이중층 전극을 이용한 유기 박막 트랜지스터를 제작하여 Au나 Ag 금속만으로 제작한 일반적인 유기 박막 트랜지스터와의 전기적 특성을 비교하였다. 전기적 특성에서 게이트 절연층은 높은 K 값을 갖는 $Al_2O_3$를 사용하였고, 유기 반도체층은 펜타센을 사용하였다. 본 실험에서 제작한 유기 박막 트랜지스터는 $1.6 \;{\times}\;10^{-1}\;cm^2$의 포화영역 이동도를 얻을 수 있었으며, 또한 드레인 전압을 -5V로 하고, 게이트 전압을 3 V에서 -10 V 까지 인가하였을 때 $3{\times}10^5$의 전멸 비를 얻을 수 있었다.