• Title/Summary/Keyword: bias error

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Simulation of Air Quality Over South Korea Using the WRF-Chem Model: Impacts of Chemical Initial and Lateral Boundary Conditions (WRF-Chem 모형을 이용한 한반도 대기질 모의: 화학 초기 및 측면 경계 조건의 영향)

  • Lee, Jae-Hyeong;Chang, Lim-Seok;Lee, Sang-Hyun
    • Atmosphere
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    • v.25 no.4
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    • pp.639-657
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    • 2015
  • There is an increasing need to improve the air quality over South Korea to protect public health from local and remote anthropogenic pollutant emissions that are in an increasing trend. Here, we evaluate the performance of the WRF-Chem (Weather Research and Forecasting-Chemistry) model in simulating near-surface air quality of major Korean cities, and investigate the impacts of time-varying chemical initial and lateral boundary conditions (IC/BCs) on the air quality simulation using a chemical downscaling technique. The model domain was configured over the East Asian region and anthropogenic MICS-Asia 2010 emissions and biogenic MEGAN-2 emissions were applied with RACM gaseous chemistry and MADE/SORGAM aerosol mechanism. Two simulations were conducted for a 30-days period on April 2010 with chemical IC/BCs from the WRF-Chem default chemical species profiles ('WRF experiment') and the MOZART-4 (Model for OZone And Related chemical Tracers version 4) ('WRF_MOZART experiment'), respectively. The WRF_MOZART experiment has showed a better performance to predict near-surface CO, $NO_2$, $SO_2$, and $O_3$ mixing ratios at 7 major Korean cities than the WRF experiment, showing lower mean bias error (MBE) and higher index of agreement (IOA). The quantitative impacts of the chemical IC/BCs have depended on atmospheric residence time of the pollutants as well as the relative difference of chemical mixing ratios between the WRF and WRF_MOZART experiments at the lateral boundaries. Specifically, the WRF_MOZART experiment has reduced MBE in CO and O3 mixing ratios by 60~80 ppb and 5~10 ppb over South Korea than those in the WRF-Chem default simulation, while it has a marginal impact on $NO_2$ and $SO_2$ mixing ratios. Without using MOZART-4 chemical IC, the WRF simulation has required approximately 6-days chemical spin-up time for the East Asian model domain. Overall, the results indicate that realistic chemical IC/BCs are prerequisite in the WRF-Chem simulation to improve a forecast skill of local air quality over South Korea, even in case the model domain is sufficiently large to represent anthropogenic emissions from China, Japan, and South Korea.

Development of Predictive Mathematical Model for the Growth Kinetics of Staphylococcus aureus by Response Surface Model

  • Seo, Kyo-Young;Heo, Sun-Kyung;Lee, Chan;Chung, Duck-Hwa;Kim, Min-Gon;Lee, Kyu-Ho;Kim, Keun-Sung;Bahk, Gyung-Jin;Bae, Dong-Ho;Kim, Kwang-Yup;Kim, Cheorl-Ho;Ha, Sang-Do
    • Journal of Microbiology and Biotechnology
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    • v.17 no.9
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    • pp.1437-1444
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    • 2007
  • A response surface model was developed for predicting the growth rates of Staphylococcus aureus in tryptic soy broth (TSB) medium as a function of combined effects of temperature, pH, and NaCl. The TSB containing six different concentrations of NaCl (0, 2, 4, 6, 8, and 10%) was adjusted to an initial of six different pH levels (pH 4, 5, 6, 7, 8, 9, and 10) and incubated at 10, 20, 30, and $40^{\circ}C$. In all experimental variables, the primary growth curves were well ($r^2=0.9000$ to 0.9975) fitted to a Gompertz equation to obtain growth rates. The secondary response surface model for natural logarithm transformations of growth rates as a function of combined effects of temperature, pH, and NaCl was obtained by SAS's general linear analysis. The predicted growth rates of the S. aureus were generally decreased by basic (pH 9-10) or acidic (pH 5-6) conditions and higher NaCl concentrations. The response surface model was identified as an appropriate secondary model for growth rates on the basis of correlation coefficient (r=0.9703), determination coefficient ($r^2=0.9415$), mean square error (MSE=0.0185), bias factor ($B_f=1.0216$), and accuracy factor ($A_f=1.2583$). Therefore, the developed secondary model proved reliable for predictions of the combined effect of temperature, NaCl, and pH on growth rates for S. aureus in TSB medium.

A $2{\times}2$ Microstrip Patch Antenna Array for Moisture Content Measurement of Paddy Rice (산물벼 함수율 측정을 위한 $2{\times}2$ 마이크로스트립 패치 안테나 개발)

  • 김기복;김종헌;노상하
    • Journal of Biosystems Engineering
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    • v.25 no.2
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    • pp.97-106
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    • 2000
  • To develop the grain moisture meter using microwave free space transmission technique, a 10.5GHz microwave signal with the power of 11mW generated by an oscillar with a dielectric resonator is transmitted to an isolator and radiated from a transmitting $2{\times}2$ microstrip patch array antenna into the sample holder filled with the 12 to 26%w.b. of Korean Hwawung paddy rice. the microwave signal, attenuated through the grain with moisture, is collected by a receiving $2{\times}2$ microstrip patch array antenna and detected using a Shottky diode with excellent high frequency characteristic. A pair of light and simple microstrip patch array antenna for measurement of grain moisture content is designed and implemented on atenflon substrate with trleative dielectric constant of 2.6 and thickness of 0.54 by using Ensemble ver. 4.02 software. The aperture of microstrip patch arrays is 41 mm width and 24mm high. The characteristics of microstrip patch antenna such as grain. return loss, and bandwidth are 11.35dBi, -38dB and 0.35GHz($50^{\circ}$ at far-field pattern of E and H plane. The width of the sample holder is large enough to cover the signal between the antennas temperature and bulk density respectively. The calibration model for measurement of grain moisture content is proposed to reduce the effects of fluectuations in bulk density and temperature which give serious errors for the measurements . From the results of regression analysis using the statistically analysis method, the moisture content of grain samples (MC(%)) is expressed in terms of the output voltage(v), temperature (t), and bulk density of samples(${\rho}b$)as follows ;$$MC(%)\;=\;(-3.9838{\times}10^{-8}{\times}v^{3}+8.023{\times}10^{-6}{\times}v^{2}-0.0011{\times}v-0.0004{\times}t+0.1706){\frac{1}{{\rho}b}}{\times}100$ Its determination coefficient, standard error of prediction(SEP) and bias were found to be 0.9855, 0.479%w.b. and -0.0.369 %w.b. respectively between measured and predicted moisture contents of the grain samples.

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Determination of Free Acid in U(VI)-Al(III) Solutions by Gran Plot Titration (Gran Plot 적정법을 이용한 U(VI)-AI(III) 용액의 자유산 농도 측정)

  • Suh, Moo-Yul;Lee, Chang-Heon;Sohn, Se-Chul;Kim, Jung-Suk;Kim, Won-Ho;Eom, Tae-Yoon
    • Analytical Science and Technology
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    • v.12 no.3
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    • pp.177-183
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    • 1999
  • The determination method of free acid in spent U-Al nuclear fuel solutions by Gran plot titration was described. Effect of U(VI) and Al(III) on the alkalimetric titration of nitric acid was investigated in oxalate complexing media as well as in noncomplexing media. Positive biases were observed in both titration media when the end-point was estimated by the Gran plot method. It was found that the cause of the bias was U(VI) in the oxalate complexing media, but Al(III) in the noncomplexing media. The relative error was less than 1% in the titration of 0.1 M $HNO_3$ at a U(VI) : Al(III) : $H^+$ mole ratio of up to 2:12:1 as long as the pH of the oxalate titration media was sustained to be below 5.0 at the beginning of titration. The method was successfully applied to the determination of nitric acid in a solution of HANARO reactor fuel with U:Al mole ratio of 1:6.

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Description of Kinetic Behavior of Pathogenic Escherichia coli in Cooked Pig Trotters under Dynamic Storage Conditions Using Mathematical Equations

  • Ha, Jimyeong;Lee, Jeeyeon;Oh, Hyemin;Kim, Hyun Jung;Choi, Yukyung;Lee, Yewon;Kim, Yujin;Lee, Heeyoung;Kim, Sejeong;Yoon, Yohan
    • Food Science of Animal Resources
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    • v.40 no.6
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    • pp.938-945
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    • 2020
  • A dynamic model was developed to predict the Escherichia coli cell counts in pig trotters at changing temperatures. Five-strain mixture of pathogenic E. coli at 4 Log CFU/g were inoculated to cooked pig trotter samples. The samples were stored at 10℃, 20℃, and 25℃. The cell count data was analyzed with the Baranyi model to compute the maximum specific growth rate (μmax) (Log CFU/g/h) and lag phase duration (LPD) (h). The kinetic parameters were analyzed using a polynomial equation, and a dynamic model was developed using the kinetic models. The model performance was evaluated using the accuracy factor (Af), bias factor (Bf), and root mean square error (RMSE). E. coli cell counts increased (p<0.05) in pig trotter samples at all storage temperatures (10℃-25℃). LPD decreased (p<0.05) and μmax increased (p<0.05) as storage temperature increased. In addition, the value of h0 was similar at 10℃ and 20℃, implying that the physiological state was similar between 10℃ and 20℃. The secondary models used were appropriate to evaluate the effect of storage temperature on LPD and μmax. The developed kinetic models showed good performance with RMSE of 0.618, Bf of 1.02, and Af of 1.08. Also, performance of the dynamic model was appropriate. Thus, the developed dynamic model in this study can be applied to describe the kinetic behavior of E. coli in cooked pig trotters during storage.

Assessment of Applicability of Portable HPGe Detector with In Situ Object Counting System based on Performance Evaluation of Thyroid Radiobioassays

  • Park, MinSeok;Kwon, Tae-Eun;Pak, Min Jung;Park, Se-Young;Ha, Wi-Ho;Jin, Young-Woo
    • Journal of Radiation Protection and Research
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    • v.42 no.2
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    • pp.83-90
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    • 2017
  • Background: Different cases exist in the measurement of thyroid radiobioassays owing to the individual characteristics of the subjects, especially the potential variation in the counting efficiency. An In situ Object Counting System (ISOCS) was developed to perform an efficiency calibration based on the Monte Carlo calculation, as an alternative to conventional calibration methods. The purpose of this study is to evaluate the applicability of ISOCS to thyroid radiobioassays by comparison with a conventional thyroid monitoring system. Materials and Methods: The efficiency calibration of a portable high-purity germanium (HPGe) detector was performed using ISOCS software. In contrast, the conventional efficiency calibration, which needed a radioactive material, was applied to a scintillator-based thyroid monitor. Four radioiodine samples that contained $^{125}I$ and $^{131}I$ in both aqueous solution and gel forms were measured to evaluate radioactivity in the thyroid. ANSI/HPS N13.30 performance criteria, which included the relative bias, relative precision, and root-mean-squared error, were applied to evaluate the performance of the measurement system. Results and Discussion: The portable HPGe detector could measure both radioiodines with ISOCS but the thyroid monitor could not measure $^{125}I$ because of the limited energy resolution of the NaI(Tl) scintillator. The $^{131}I$ results from both detectors agreed to within 5% with the certified results. Moreover, the $^{125}I$ results from the portable HPGe detector agreed to within 10% with the certified results. All measurement results complied with the ANSI/HPS N13.30 performance criteria. Conclusion: The results of the intercomparison program indicated the feasibility of applying ISOCS software to direct thyroid radiobioassays. The portable HPGe detector with ISOCS software can provide the convenience of efficiency calibration and higher energy resolution for identifying photopeaks, compared with a conventional thyroid monitor with a NaI(Tl) scintillator. The application of ISOCS software in a radiation emergency can improve the response in terms of internal contamination monitoring.

Simulation of Agricultural Water Supply Considering Yearly Variation of Irrigation Efficiency (연단위 관개효율 변화를 고려한 관개지구 용수 공급량 모의)

  • Song, Jung Hun;Song, Inhong;Kim, Jin Taek;Kang, Moon Seong
    • Journal of Korea Water Resources Association
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    • v.48 no.6
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    • pp.425-438
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    • 2015
  • The objective of this study was to evaluate simulation of agricultural water supply considering yearly variation of irrigation efficiency. The water supply data of the Idong reservoir from 2001 through 2009 was collected and used for this study. Total 6 parameters including irrigation efficiency (Es), drainage outlet height, and infiltration, were used for sensitivity analysis, calibration, and validation. Among the parameters, the Es appeared to be the most sensitivity parameter. The Es was calibrated on a yearly basis considering sensitivity and time-varying characteristic, while other parameters were set to fixed values. The statistics of percent bias (PBLAS), Nash-Sutcliffe efficiency (NSE), and root means square error to the standard deviation of measured data (RSR) for a monthly step were 2.7%, 0.93, and 0.26 for the calibration, and 3.9%, 0.89, and 0.32 for the validation, correspondently. The results showed a good agreement with the observations. This implies that the modeling only with appropriate parameter values, apart from modeling approaches, can simulate the real supply operation reasonably well. However, the simulations with uncalibrated parameters from previous studies produced poor results. Thus, it is important to use calibrated values, and especially, we suggest the Es's yearly calibration for simulating agricultural water supply.

Improving Initial Abstraction Method of NRCS-CN for Estimating Effective Rainfall (유효우량 산정을 위한 NRCS-CN 모형의 초기손실량 산정방법 개선)

  • Park, Dong-Hyeok;Ajmal, Muhammad;Ahn, Jae-Hyun;Kim, Tae-Woong
    • Journal of Korea Water Resources Association
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    • v.48 no.6
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    • pp.491-500
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    • 2015
  • In order to improve the runoff estimation accuracy of the Natural Resources Conservation Service (NRCS) curve number (CN) model, this study incorporated rainfall and maximum potential retention as contributors for initial abstraction. The modification was proposed based on 658 rank-order data of rainfall and subsequent runoff from 15 watersheds. The NRCS-CN model (M1), one of its inspired modified model (M2), and the proposed model (M3) were analyzed employing different CN approaches. Using tabulated, calculated and least squares fitted CNs ($CN_T$, $CN_C$, $CN_{LSF}$, respectively), the models' performances were evaluated based on Root Mean Square Error (RMSE), Nash-Sutcliffe Efficiency (NSE), and Percent Bias (PBIAS). Applications of model M1, M2, and M3, respectively exhibited watershed cumulative mean [RMSE (23.60, 18.12, 16.04), NSE (0.54, 0.73, 0.79), and PBIAS (36.54, 20.25, 12.00)]. Similarly, using CNC (for M1 and M2 model) and $CN_{LSF}$ (for M3 model), the performance of three models respectively were assessed based on watershed cumulative mean [RMSE (17.17, 15.88, 13.82), NSE (0.76, 0.80, 0.85), and PBIAS (3.06, 4.47, 0.11)]. The proposed model (M3) that linked all of the NRCS-CN variants showed more statistically significant agreement between the observed and estimated data.

Characteristics of Speckle Errors of SeaWiFS Chlorophyll-α Concentration in the East Sea (동해 SeaWiFS 클로로필-α 농도의 스펙클 오차 특성)

  • Chae, Hwa-Jeong;Park, Kyung-Ae
    • Journal of the Korean earth science society
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    • v.30 no.2
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    • pp.234-246
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    • 2009
  • Characteristics of speckle errors of Sea-viewing Wide Field-of-view Sensor (SeaWiFS) chlorophyll-${\alpha}$ concentration were analyzed, and its causes were investigated by using SeaWiFS data in the East Sea from September 1997 to December 2007. The speckles with anomalously high concentrations were randomly distributed and showed remarkably high bias of greater than $10mg/m^3$, compared with their neighboring pixels. The speckles tended to appear frequently in winter, which might be related to cloud distribution. Ten-year averaged cloudiness of winter was much higher over the southeastern part, with frequent speckles, than the northwestern part of the East Sea. Statistical analysis results showed that the number of the speckles was increased as cloudiness increased. Normalized water-leaving radiance of the speckle pixel was considerably low at the short wavelengths (443, 490, and 510 nm), whereas the radiance at 555 nm band was normal. These low measurements produced extraordinarily high concentration from the chlorophyll-${\alpha}$ estimation formula. This study presented the speckle errors of SeaWiFS chlorophyll-${\alpha}$ concentration in the East Sea and suggested that more reliable chlorophyll-${\alpha}$ data based on appropriate ocean color remote sensing techniques should be used for the oceanic application researches.

Predicting and Extending the Shelf Life of Red Cabbage Sprouts (적양배추싹의 Shelf Life 예측 및 Aqueous ClO2, Fumaric Acid, UV-C 병합처리)

  • Chun, Ho Hyun;Park, Seung Jong;Jung, Seung Hun;Song, Kyung Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.9
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    • pp.1518-1523
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    • 2013
  • To estimate the shelf life of red cabbage sprouts (stored at 4 and $10^{\circ}C$), the numbers of total aerobic bacteria were determined during storage. Parameters for the Gompertz model were determined and the shelf life was predicted using a modified Gompertz equation. The estimated shelf lives of red cabbage sprouts packed with polyolefin film and polyamide/polyamide/polyethylene (PA/PA/PE) film at $4^{\circ}C$ were 49.4 and 52.3 h, respectively, whereas those of red cabbage sprouts packed with polyolefin film and PA/PA/PE film at $10^{\circ}C$ were 19.7 and 22.6, respectively. The shelf life prediction equation was appropriate, based on the statistical analysis of the accuracy factor, bias factor, and mean square error. On the other hand, for red cabbage sprouts treated with aqueous $ClO_2$/fumaric acid and UV-C then packed with polyolefin film or PA/PA/PE film, the shelf life was predicted to be longer than 168 h. These results suggest that the combined treatment of aqueous $ClO_2$/fumaric acid and UV-C can be useful for improving microbial safety and extending the shelf life of red cabbage sprouts during storage.