• Transactions of Materials Processing
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• v.3 no.3
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• pp.271-281
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• 1994

Titanium-6242 $({\alpha}+{\beta})$ alloy has been used for aircraft engine components such as disks and blades, because it has an excellent strength/weight ratio at high temperatures. When this material is forged to manufacture disks, process parameters should be carefully designed to control strain and temperature distributions within the process windows by which desirable mechanical properties can be produced. In the present investigation, it was intended to design the process parameters for a conventional hot forging of this material by using a rigid-thermoviscoplastic finite element analysis technique. It was assumed that the process was performed by a screw press which is capable of maintaining a constant ram speed during loading. From the analysis results, it was found out that the initial temperature of the workpiece and the die shape were important parameters to control the forging process. In result, these parameters were properly designed for hot forging of a disk with specific dimensions.

• Oral Biology Research
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• v.42 no.4
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• pp.187-197
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• 2018

Chemical agents such as minocycline (MC) and citric acid (CA) were suggested in the treatment of contaminated implant surface. In this study, MC-HCl treatment was performed to enhance surface characteristics of titanium alloy surface. The purpose of this study was to assess the characteristics and the biocompatibility of Ti-6Al-4V surface treated by MC. Alpha-beta titanium alloy (Ti-6Al-4V) samples were prepared and they were divided into 6 groups according to chemical concentration and treatment time. These groups include 1) group I, non-treated smooth titanium alloy; 2) group II, MC 1.5 mg/mL for 1 hour; 3) group III, MC 1.5 mg/mL for 24 hours; 4) group IV, MC 15 mg/mL for 10 minutes; 5) group V, MC 100 mg/mL for 5 minutes; 6) group VI, pH1 CA for 3 minutes. The analysis of the surface characteristics of MC-treated titanium alloy was executed using scanning electron microscopy, roughness test, and X-ray photoelectron spectroscopy (XPS). Cell adhesion and MTT assay was done using MC3T3 cell. Titanium surfaces treated with MC indicated a more smoothened surface microstructure. For group II and III, the new peaks of rutile TiO2 were found. Group II and V have more basic group of Ti-OH form in XPS. In MTT assay, all MC-treated groups showed significantly higher cell viability compared to control. The surface roughness, crystal structure, surface hydrophilicity, cell viability of smooth titanium surface was improved by MC treatment. Compared with the control experiment and CA-treated group, smooth titanium surface treated with MC showed improved surface characteristics and cell biocompatibility.

• Bulletin of the Korean Chemical Society
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• v.25 no.11
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• pp.1653-1656
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• 2004

${\alpha},{\beta}$-Unsaturated aldehydes such as acrolein and crotonaldehyde were reacted with diols in the presence of conc. sulfuric acid to give products of which concomitant addition to C-C double bond and acetalization took place. Boron trifluoride etherate and titanium tetrachloride gave only acetalization products.

• Journal of Periodontal and Implant Science
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• v.36 no.4
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• pp.849-861
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• 2006

타이타늄은 기계적 특성이 우수하고 생체적합성이 뛰어나 의료용 장비의 주 재료로 사용되고 있으며 타이타늄 보다 기계적 특성이 더 우수한 타이타늄 합금들(주로 Ti-6Al-4V와 Ti-6Al-7Nb 합금)도 개발되어 치과와 의료용 임플란트로 사용되고 있다. 그러나 타이타늄 합금 성분들 중 알루미늄 (aluminum)과 바나디움(vanadium)은 인체에 노출되면 세포손상과 신경계에 문제를 일으킬 수 있다. 따라서 인체에 독성이 없으면서 기계적 성질과 생체적합성이 우수한 타이타늄 합금의 개발이 필요하다. 최근 인체에 독성이 없는 성분들이 함유된 새로운 ${\beta}$ - 형태의 타이타늄 합금들이 개발되고 있는데, ${\beta}$ - 타이타늄 합금은 그 기계적 성질이 기존의 ${\alpha}+{\beta}$ 타이타늄 합금에 비해 우수하다고 알려져 있다. 최근 새로운 ${\beta}$ - 타이타늄 합금이 전남대학교 부설 타이타늄 연구소에서 개발되었다. 이 연구는 새로 개발된 ${\beta}$ - 타이타늄 합금의 생채 적합성을 세포 증식도, 알카리 인산 분해 효소 활성과 유전자 증폭을 통해 알아보고자 하였다. 그 결과는 다음과 같다; 1. Titanium-6aluminum-4vanadium (Ti-6Al-4V) 합금 표면애서의 세포 증식율은 Titanium-Titanium8Tantalum-3Niobium (Ti-8Ta-3Nb) 합금과 순수 타이타늄 표면에 비해 유의하게 낮았다(p<0.00l). Ti-8Ta-3Nb 합금 표면에서의 증식도는 순수 타이타늄 표면과 유사하였다. 2. Ti-8Ta-3Nb 합금과 순수 타이타늄에서 배양된 세포이 알카리 인산 분해 효소의 활성도는 Ti-6Al-4V 합금에서의 것보다 유의하게 높았다 (p<0.001). 3. 유전자 증폭 분석 결과, Ti-8Ta-3Nb 합금과 순수 타이타늄에서 collagen type I과 bone sialoprotein mRNA 가 유사한 수준으로 발현되었다. 이상의 결과는 생체 적합성 측면에서 Ti-8Ta-3Nb 합금과 순수 타이타늄의 차이가 없음을 보여주며 따라서 Ti-8Ta-3Nb 합금이 의학 및 치의학 영역에서 새로운 임프란트 재료로 사용될 수 있음을 의미한다.

• Proceedings of the KWS Conference
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• 2002.10a
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• pp.632-638
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• 2002

Electron beam (EB) and Gas tungsten arc (TIG) welds were performed on 12.7 mm thick Ti-6Al-4V plate (ASTM Titanium Grade 5). Charpy-V toughness and hardness, as well as, microstructure of the welds and penetration from the macrostructure were studied. It appears that by EB welding rather smaller $\beta$-grains than with TIG welding can be obtained. Next to the fusion line the $\beta$-grain size in the HAZ was 50 ${\mu}{\textrm}{m}$l while in the weld metal it was 150 ${\mu}{\textrm}{m}$. Charpy-V toughness of the EB weld metal was equal or even better to that of base metal, which shows that the $\alpha$-martensite per se is not particularly brittle if only the grain size is fine enough. This is similar to behavior of low carbon martensite in steel. The grain size was studied with light optical and scanning electron (SEM) microscopes. Thus for products, for products which can be manufactured automatically with very narrow fit, the EB welding of Ti-6Al-4V appears to yield satisfactory toughness without any complex post weld heat treatment. ill this study as in earlier studies the TIG welds gave lower toughness than that of the base material due to the higher heat input and slower cooling as compared to EB welding.

• Journal of Technologic Dentistry
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• v.28 no.1
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• pp.61-66
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• 2006

Titanium alloys have been used for dental materials due to it's very good biocompatibility. Ti-6Al-4V alloy instead of pure titanium is being widely used as biomaterials has some characteristics such as high fatigue strength, tensile strength and corrosion resistance. But it has been reported recently that the vanadium element expresses cytotoxicity and carcinogenicity and the aluminium element is related with dementia of Alzheimer type and neurotoxicity. The Ti-Nb alloys has designed and examined corrosion resistance. Ti-3wt.%Nb($\alpha$type), Ti-20wt.%Nb(${\alpha}+{\beta}$type) and Ti-40wt.%Nb($\beta$type) alloys were melted by vacuum arc furnace. The corrosion resistance of Ti alloys was evaluated by potentiodynamic polarization test in the solution of 0.9% NaCl and 5% HCl. The results can be summarized as follows: 1) For the corrosion test in the solution of 0.9% NaCl and 5% HCl, the corrosion behaviour of Ti-Nb alloys was similar to ASTM grade 2 CP Ti. 2) The corrosion resistance of Ti-20Nb alloy was better than that of CP-Ti, Ti-3Nb, Ti-40Nb alloy in 0.9% NaCl and 5% HCl, solutions.

• The korean journal of orthodontics
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• v.23 no.2 s.41
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• pp.283-294
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• 1993

The friction of orthodontic appliances is recogonized to be detrimental to tooth movement. The purpose of this study was to determine the magnitude of frictional force changes between bracket$(018'\times025'\;solt)$ and orthodontic wires(stainless steel, cobalt-chromium, and $\beta-titanium$, $017'\times0.25'$ rectangular) with time. The wire was secured in the bracket slot with a elastomeric ligature. Frictional forces were measured by universal testing machine. The following conclusions were obtained. 1. The frictional forces under dry condition were greater than those in saliva. 2. The frictional forces produced by cobalt-chromium wire were less than those generated by stainless steel and $\beta-titanium$ wire. 3. The frictional forces increased progressively with time, and the amount of increase on first two weeks was greater than on last two weeks. 4. The change of frictional force under dry condition was greater than in artificial saliva.

• The korean journal of orthodontics
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• v.18 no.1 s.25
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• pp.155-163
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• 1988

The purpose of this study was to evaluate and compare frictional forces generated between orthodontic brackets and arch wires. Independent variables were chosen for study: arch wire size and shape, arch wire material, bracket width, and second-order angulation between bracket and arch wire. Kinetic frictional forces of stainless steel (0.014', 0.016', 0.018', 0.016' ${\times}$ 0.022', 0.018' ${\times}$ 0.022'), $\beta-titanium$ (0.016' ${\times}}$ 0.022') arch wires were measured on wide and junior edgewise twin brackets (0.018' ${\times}$ 0.022' slot). Instron was used to pull arch wires while $0^{\circ},\;3^{\circ},\;6^{\circ},\;or\;9^{\circ}$ angulation between and wire and bracket was given. The results were as follows: 1. The frictional force of $\beta-titanium$ wire was larger than that of stainless steel wire. 2. The frictional force was generally increased as the size of wire is increased. 3. The frictional force of rectangular wire was larger than that of round wire. 4. As second order angulation was increased, the frictional force was also increased. 5. The frictional force was larger on a wide bracket than on a junior bracket.

• Journal of Korea Foundry Society
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• v.22 no.3
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• pp.114-120
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• 2002

A new titanium based alloy, Ti-10Ta-10Nb, has designed to examine the improved mechanical properties and biocompatibility. A specimen of titanium alloy was melted in a consumable vacuum arc furnace and homogenized at $1050^{\circ}C$ for 24 h. The effect of hot rolling on microstructure was estimated after rolling at $400^{\circ}C$ and $800^{\circ}C$ respectively. Surface of melted alloy by consumable vacuum arc melting was consisted of rough surface and it was changed to sound surface by coating of $ZrO_2$ slurry on copper mold surface. The hardness of Ti-10Ta-10Nb alloy increased with the amount of${\alpha}+{\beta}$ phase. Ti-10Ta-10Nb alloy showed $Widmanst{\"{a}}ten$ structure by hot rolling at $800^{\circ}C$ and in the rolling ${\beta}-region$ was negligible effects on microstructure refining.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.482-490
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• 1992

2,5-dimethoxy-2,5-dihydrofurfuryl alcohol was electrosynthesized from furfuryl alcohol in methanol solution by using three kinds of metal oxide anode. The electrods were prepared by the following process : Thin layer of semiconducting material such as tin(IV)oxide and antimony(III)oxide was made on the titanium base metal in an electric furnace. The titanium metal block with the layer was coated with ${\alpha}-PbO_2$, ${\beta}-PbO_2$, and $MnO_2$ in each electrolytes by anodic deposition, respectively. The lead dioxide electrodes showed better anti-corrosive property than the manganase dioxide electrode. The yield of the product was 92% which is almost the same as the one with conventional platinum electrodes.