• Title/Summary/Keyword: bend state

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Studies on Photosensitive Polymers (X). Studies on Photosensitivity and Spectral Sensitivity of Naphthoquinone-1,2-diazide-5-sulfonyl Esters (感光性 樹脂에 關한 硏究 (第10報). Naphthoquinone-1,2-diazide-5-sulfonyl Esters의 感光性과 分光感度)

  • Shim Jyong Sup;Kang Doo Whan
    • Journal of the Korean Chemical Society
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    • v.19 no.4
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    • pp.269-279
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    • 1975
  • Photosensitive properties of naphthoquinone-1,2-diazide-5-sulfonyl esters (PGND, BEND and PVAND) of polyglyceryl phthalate(PG), bisphenol A-epichlorohydrin condensate(BE) and polyvinyl alcohol(PVA) were investigated by the change of solubility before and after exposing to light. Various samples coated on glass or quartz plates were exposed to light under various conditions and steeped in aqueous alkali solution, and then the yield of residual film(W/W0) was determined. The yield of residual film, which was closely related to the sensitivity of the film, was affected by the degree of polymerization of the backbone resin, sensitizers and their concentration. In polymer homologs, the sensitivity was dependent on the degree of polymerization(the higher, the better). And also, it was most effective when 5 % of sensitizers to esters was used. The minimum exposed time was 0.6 min. for PGND-1, 1.0 min. for BEND-1, and 3.0 min. for PVAND-1. Most effective sensitizers for PGND, BEND and PVAND among those used here were benzanthrone, 5-nitroacenaphthene and picramide, respectively. The spectral sensitivities of PGND, BEND and PVAND were examined by comparing their spectrograms with UV-spectra in a solid state. Also, the sensitization and spectral sensitivity of the above polymers were studied. All the polymers containing the sensitizers showed optical sensitization. From the fact that in either case of sensitized or unsensitized sample, the ranges of absorption-maximum wave length were almost consistent with sensitivity maximum wave length, it was proved that the light absorbed by a sample served efficiently for photochemical reactions. Benzanthrone was found to be an excellent sensitizer for PGND.

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Theoretical Estimates for Elastic Properties of Biaxial Nematics

  • Allender, David W.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.195-198
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    • 2005
  • Using theoretical analysis based on Landau theory, it is shown that only five phenomenological parameters are necessary to describe the twelve bulk elastic constants of a biaxial nematic phase. Further, a simple method for determining the values of these five parameters experimentally is given. Comparison with the values of the well-known splay, twist, and bend elastic constants of the uniaial nematic is made.

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Hydrodynamic Characteristics of Vaned-Diffuser and Return-Channel for a Multistage Centrifugal Pump (원심다단펌프용 디퓨저-리턴채널의 유동특성)

  • Oh, Hyoung-Woo
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.6
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    • pp.54-60
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    • 2011
  • This paper presents the steady-state performance analysis of the first stage of a multistage centrifugal pump, composed of a shrouded-impeller, a vaned-diffuser and a return-channel, using the commercially available computational fluid dynamics (CFD) code, ANSYS CFX. The detailed flow fields in the vaned-diffuser with outlet in its side wall and the return-channel are investigated by the CFD code adopted in the present study. The effect of the vaned-diffuser with a downstream crossover bend and the corresponding return-channel on the overall hydrodynamic performance of the first stage pump has also been demonstrated over the normal operating conditions. The predicted hydrodynamics for the diffusing components herein could provide useful information to match the inlet blade angle of the next stage impeller for improving the multistage pump performances.

Stochastic elastic wave analysis of angled beams

  • Bai, Changqing;Ma, Hualin;Shim, Victor P.W.
    • Structural Engineering and Mechanics
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    • v.56 no.5
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    • pp.767-785
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    • 2015
  • The stochastic finite element method is employed to obtain a stochastic dynamic model of angled beams subjected to impact loads when uncertain material properties are described by random fields. Using the perturbation technique in conjunction with a precise time integration method, a random analysis approach is developed for efficient analysis of random elastic waves. Formulas for the mean, variance and covariance of displacement, strain and stress are introduced. Statistics of displacement and stress waves is analyzed and effects of bend angle and material stochasticity on wave propagation are studied. It is found that the elastic wave correlation in the angled section is the most significant. The mean, variance and covariance of the stress wave amplitude decrease with an increase in bend angle. The standard deviation of the beam material density plays an important role in longitudinal displacement wave covariance.

Shock wave instability in a bent channel with subsonic/supersonic exit

  • Kuzmin, Alexander
    • Advances in aircraft and spacecraft science
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    • v.6 no.1
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    • pp.19-30
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    • 2019
  • Two- and three-dimensional turbulent airflows in a 9-degrees-bent channel are studied numerically. The inner surfaces of upper and lower walls are parallel to each other upstream and downstream of the bend section. The free stream is supersonic, whereas the flow at the channel exit is either supersonic or subsonic depending on the given backpressure. Solutions of the Reynolds-averaged Navier-Stokes equations are obtained with a finite-volume solver ANSYS CFX. The solutions reveal instability of formed shock waves and a flow hysteresis in considerable bands of the free-stream Mach number at zero and negative angles of attack. The instability is caused by an interaction of shocks with the expansion flow formed over the convex bend of lower wall.

Bistable Property in a Splay Cell with a Chiral Additive

  • Lee, Seo-Hern;Kim, Tae-Jin;Lee, Jong-Lac;Jung, Mi-Jun;Park, Kyoung-Ho;Lee, Gi-Dong;Yoon, Tae-Hoon;Kim, Jae-Chang
    • Journal of Information Display
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    • v.4 no.3
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    • pp.22-25
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    • 2003
  • In this paper, we propose the bistability the bistability in a chiral-splay nematic liquid crystal cell, which is obtained by adding a chiral additive to a splay cell and introduce a novel switching method for the bistable chiral-splay nematic cell in order to transit the LC director between the non-twisted state with splay and the 180$^{\circ}$ twist state.

Mechanism of failure in the Semi-Circular Bend (SCB) specimen of gypsum-concrete with an edge notch

  • Fu, Jinwei;Sarfarazi, Vahab;Haeri, Hadi;Marji, Mohammad Fatehi;Guo, Mengdi
    • Structural Engineering and Mechanics
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    • v.81 no.1
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    • pp.81-91
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    • 2022
  • The effects of interaction between concrete-gypsum interface and edge crack on the failure behavior of the specimens in senicircular bend (SCB) test were studied in the laboratory and also simulated numerically using the discrete element method. Some quarter circular specimens of gypsum and concrete with 5 cm radii and hieghts were separately prepared. Then the semicircular testing specimens were made by attaching one gypsum and one concrete sample to one another using a special glue and one edge crack is produced (in the interface) by do not using the glue in that part of the interface. The tensile strengths of concrete and gypsum samples were separately measured as 2.2 MPa and 1.3 MPa, respectively. during all testing performances a constant loading rate of 0.005 mm/s were stablished. The proposed testing method showed that the mechanism of failure and fracture in the brittle materials were mostly governed by the dimensions and number of discontinuities. The fracture toughnesses of the SCB samples were related to the fracture patterns during the failure processes of these specimens. The tensile behaviour of edge notch was related to the number of induced tensile cracks which were increased by decreasing the joint length. The fracture toughness of samples was constant by increasing the joint length. The failure process and fracture pattern in the notched semi-circular bending specimens were similar for both methods used in this study (i.e., the laboratory tests and the simulation procedure using the particle flow code (PFC2D)).

Novel P(VDF-TrFE) Polymer Electrolytes: Their Use in High-Efficiency, All-Solid-State Electrochemical Capacitors Using ZnO Nanowires

  • Park, Young Jun;Bae, Joonho
    • Journal of Electrochemical Science and Technology
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    • v.9 no.2
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    • pp.126-132
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    • 2018
  • For the first time, an innovative approach using P(VDF-TrFE) as a polymer electrolyte for high efficiency, all-solid-state supercapacitors is presented. The polymer electrolyte was successfully achieved by dissolving P(VDF-TrFE) copolymers in dimethylformamide (DMF). Thermal analysis and infrared spectroscopy revealed excellent thermal stability up to $400^{\circ}C$ and copolymer's interaction with DMF. Electrochemical capacitors fabricated using P(VDF-TrFE) in DMF and ZnO NWs demonstrated high capacitive performance. Furthermore, the gel electrolyte-based supercapacitors demonstrated excellent mechanical durability up to a bend angle of $120^{\circ}$. Novel P(VDF-TrFE) electrolytes could be a promising approach for applications in flexible, fabric-based, and high-efficiency energy devices.

High Temperature Creep Behavior of Cr3C2 Composites (크롬-카바이드 복합체의 고온 크리프 거동)

  • 김지환;한동빈;김기태
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1219-1226
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    • 1995
  • Creep behaviors of Cr3C2 composites containing 90 wt% Cr3C2 and 10 wt% Ni were studied at high temperature. Compression tests at 100$0^{\circ}C$ and bending tests at 100$0^{\circ}C$ and 105$0^{\circ}C$ were done in argon environment. In all test conditions primary and steady-state creep behaviors were observed. Stress exponent and activatiion energy were determined from the experimental data. By microstructural analysis of Cr3C2 composites after creep test, the separate agglomerations of Ni phase were observed. Numerical analysis was also studied to analyze bending creep behaviors of Cr3C2 by assumming different tensile and compressive creep behavior in a bending sample. From the analysis, it was found that the stress state at the compressive region as applied stress increased. The observed creep rates were compared with the predicted creep rates by estimating power-law creep parameters from bending test data.

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