• Title/Summary/Keyword: basic materials

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Highly Photocatalytic Performance of flexible 3 Dimensional (3D) ZnO nanocomposite

  • Lee, Hyun Uk;Seo, Jung Hye;Son, Byoungchul;Kim, Hyeran;Yun, Hyung Joong;Jeon, Cheolho;Lee, Jouhahn
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.270.1-270.1
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    • 2013
  • Zinc oxide (ZnO) is one of the most powerful materials for purifying organic pollutants using photocatalytic activity. In this study, we have introduced a novel method to design highly photoreactive flexible 3 dimensional (3D) ZnO nanocomposite [F-ZnO-m (m: reaction time, min)] by electrospinning and simple-step ZnO growth processing (one-step ZnO seed coating/growth processing). Significantly, the F-ZnO-m could be a new platform (or candidate) as a photocatalytic technology for both morphology control and largearea production. The highest photocatalytic degradation rate ([k]) was observed for F-ZnO-m at 2.552 h-1, which was 8.1 times higher than that of ZnO nanoparticles (NPs; [k] = 0.316 h-1). The enhanced photocatalytic activity of F-ZnO-m may be attributed to factors such as large surface area. The F-ZnO-m is highly recyclable and retained 98.6% of the initial decolorization rate after fifteen cycles. Interestingly, the F-ZnO-m samples show very strong antibacterial properties against both Gram-negative Escherichia coli (E. coli) and Gram-positive Staphylococcus aureus (S. aureus) after exposure to UV-light for 30 min. The antibacterial properties of F-ZnO-m samples are more effective than those of ZnO NPs. More than 96.6% of the E. coli is sterilized after ten cycles. These results indicate that F-ZnO-m samples might have utility in several promising applications such as highly efficient water/air treatment and inactivation of pathogenic microorganisms.

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Novel Photocatalytic and Antibacterial Activities of Three-Dimensional (3D) Polycrystalline Anatase TiO2 Structures

  • Lee, Hyun Uk;Yun, Hyung Joong;Son, Byoungchul;Seo, Jung Hye;Kim, Hyeran;Choi, Saehae;Jeon, Cheolho;Kim, Hae Jin;Lee, Jouhahn
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.635-635
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    • 2013
  • We report three-dimensional polycrystalline anatase TiO2 structures (3D a-TiO2) for environmental and bio-medical applications. The 3D a-TiO2 was synthesized without thermal treatment by the growth of rod-like polycrystals on Degussa P25 (P25) via low temperature (< $85^{\circ}C$) modified alkali hydrothermal processing. X-ray diffraction and high-resolution transmission electron microscopic results showed that the rod-like polycrystals of 3D a-TiO2 possessed the highly anatase nanostructures. The photocatalytic activity of 3D a-TiO2 was found to be 2.2 times higher than that of P25. The recyclability of the 3D a-TiO2 was found to be high: the decolorization rate was 94.8% of the initial value after fifteen cycles. In addition, 3D a-TiO2 exhibited excellent antibacterial activities for the sterilization of gram-negative Escherichia coli (E. coli) and gram-positive Staphylococcus aureus (S. aureus). Even at the 10th recycled use, more than 98.4% of E. coli and S. aureus can be killed. These results indicated that 3D a-TiO2 might have utility in several promising applications such as photocatalytic water/air purification and bactericidal agents.

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Preparation of LiFe PO4 Using Chitosan and its Cathodic Properties for Rechargeable Li-ion Batteries

  • Hong, Kyong-Soo;Yu, Seong-Mi;Ha, Myoung-Gyu;Ahn, Chang-Won;Hong, Tae-Eun;Jin, Jong-Sung;Kim, Hyun-Gyu;Jeong, Euh-Duck;Kim, Yang-Soo;Kim, Hae-Jin;Doh, Chil-Hoon;Yang, Ho-Soon;Jung, Hee
    • Bulletin of the Korean Chemical Society
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    • v.30 no.8
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    • pp.1719-1723
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    • 2009
  • The LiFeP$O_4$ powder was synthesized by using the solid state reaction method with Fe($C_2O_4){\cdot}2H_2O,\;(NH_4)_2HPO_4,\;Li_2CO_3$, and chitosan as a carbon precursor material for a cathode of a lithium-ion battery. The chitosan added LiFePO4 powder was calcined at 350 ${^{\circ}C}$ for 5 hours and then 800 ${^{\circ}C}$ for 12 hours for the calcination. Then we calcined again at 800 ${^{\circ}C}$ for 12 hours. We characterized the synthesized compounds via the crystallinity, the valence states of iron ions, and their shapes using TGA, XRD, SEM, TEM, and XPS. We found that the synthesized powders were carbon-coated using TEM images and the iron ion is substituted from 3+ to 2+ through XPS measurements. We observed voltage characteristics and initial charge-discharge characteristics according to the C rate in LiFeP$O_4$ batteries. The obtained initial specific capacity of the chitosan added LiFeP$O_4$ powder is 110 mAh/g, which is much larger than that of LiFeP$O_4$ only powder.

A LCA Case Study on Basic Materials of PC (PC 구성물질에 관한 LCA 사례연구)

  • Lee, Sung-Ho
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.28 no.3
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    • pp.10-17
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    • 2005
  • In this paper, the life cycle assessment(LCA) methodology is applied to Personal Computer's basic materials in order to analyze the impact to the environment. LCA data collection is carried out taking into account on main materials of PC's parts and component. And the impact assessment is the environmental burden on three factor into air emission(CO2, SOx, NOx), five factor into water emission(BOD, COD, SS, N, P), and three factor on transported substance(cl, NH4, SO4). According to the result, the environmental burden of PC's basic materials was proved to be used total energy 6,285Mj and emitted CO2 259.8kg, SOx 3,571g, NOx 330g, COD 1,328g, P 246g, N 2,434g. And this paper was presented the problems of its disposition-incinerating, landfill, and recycling.