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Antifungal Activities of Copper(II) with Biosensitive Macrocyclic Schiff Base Ligands Derived from 4-Aminoantipyrine Derivatives

  • Gopalakrishnan, S.;Joseph, J.
    • Mycobiology
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    • v.37 no.2
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    • pp.141-146
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    • 2009
  • Novel copper(II) complexes have been synthesized from the macrocyclic Schiff bases derived from Knoevenagel condensed ${\beta}$-ketoanilides (obtained by the condensation of acetoacetanilide and substituted benzaldehydes), 4-aminoantipyrine and ophenylene diamine. The structural features have been determined from their analytical and spectral data. All the Cu(II) complexes exhibit square planar geometry. Their high molar conductance values support their 1 : 2 electrolytic nature. The magnetic moment data provide evidence for the monomeric nature of the complexes. The X-band ESR spectra of the |$CuL^1$|$(OAc)_2$ in DMSO solution at 300 and 77 K were recorded and their salient features are reported. The in vitro biological screening effects of the investigated compounds were tested against the bacterial species Staphylococcus aureus, Escherichia coli, Klebsiella pneumoniae, Proteus vulgaris and Pseudomonas aeruginosa and fungal species Aspergillus niger, Rhizopus stolonifer, Aspergillus flavus, Rhizoctonia bataicola and Candida albicans by well diffusion method. A comparative study of inhibition values of the Schiff bases and their complexes indicate that complexes exhibit higher antimicrobial activity than the Schiff bases. Copper ions proved to be essential for the growth-inhibitor effect. The extent of inhibition appeared to be strongly dependent on the initial cell density and on the growth medium.

Protection of military bases and military facilities in the real estate assets held by the Ministry of National Defence study on the efficient management (군사시설보호법에 의한 국방부 보유 부동산 자산의 효율적인 관리방안에 관한 연구)

  • Shin, Kwang-Shig;Kim, Dong-Hyun
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.1
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    • pp.181-186
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    • 2012
  • This study military and local authorities to set up military reserves has often caused friction. Therefore, military bases and military facilities around the Act's real estate management practices that can be was to prepare. As a result, the first government to develop a plan to train real estate professionals are actively involved with the Advisory Board shall be utilized to configure. Utilizing the second army of real estate assets for future urban development should be. The third section, research on military protection should be continued. Finally, border management and development plans to propose the measures that should be carried out.

The Effect of Aircraft Parking Environment on Atmospheric Corrosion Severity (항공기 주기환경이 대기부식위험도에 미치는 영향)

  • Yun, Juhee;Lee, Dooyoul;Park, Sungryul;Kim, Min-Saeng;Choi, Dongsu
    • Corrosion Science and Technology
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    • v.20 no.2
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    • pp.94-104
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    • 2021
  • Atmospheric corrosion severity associated with aircraft parking environment was studied using metallic specimens, and temperature and humidity sensors installed at each aircraft operating base. Data were analyzed after a year of exposure. Silver was used to measure chloride deposition by integrating X-ray photoelectron spectroscopy depth profiles. Carbon steel was utilized to determine the corrosion rate by measuring the weight loss. The time of wetness was determined using temperature and humidity sensor data. Analysis of variance followed by Tukey's "honestly significant difference" test indicated that atmospheric environment inside the shelter varied significantly from that of unsheltered parking environment. The corrosion rate of unsheltered area also varies with the roof. Hierarchical clustering analysis of the measured data was used to classify air bases into groups with similar atmospheric corrosion. Bases where aircraft park at a shelter can be grouped together regardless of geographical location. Unsheltered bases located inland can also be grouped together with sheltered bases as long as the aircraft are parked under the roof. Environmental severity index was estimated using collected data and validated using the measured corrosion rate.

Algorithm for Determining Aircraft Washing Intervals Using Atmospheric Corrosion Monitoring of Airbase Data and an Artificial Neural Network (인공신경망과 대기부식환경 모니터링 데이터를 이용한 항공기 세척주기 결정 알고리즘)

  • Hyeok-Jun Kwon;Dooyoul Lee
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.377-386
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    • 2023
  • Aircraft washing is performed periodically for corrosion control. Currently, the aircraft washing interval is qualitatively set according to the geographical conditions of each base. We developed a washing interval determination algorithm based on atmospheric corrosion environment monitoring data at the Republic of Korea Air Force (ROKAF) bases and United States Air Force (USAF) bases to determine the optimal interval. The main factors of the washing interval decision algorithm were identified through hierarchical clustering, sensitivity analysis, and analysis of variance, and criteria were derived. To improve the classification accuracy, we developed a washing interval decision model based on an artificial neural network (ANN). The ANN model was calibrated and validated using the atmospheric corrosion environment monitoring data and washing intervals of the USAF bases. The new algorithm returned a three-level washing interval, depending on the corrosion rate of steel and the results of the ANN model. A new base-specific aircraft washing interval was proposed by inputting the atmospheric corrosion environment monitoring results of the ROKAF bases into the algorithm.

A Study on the Decoration of Stone Base at Sachuwang-sa Temple (사천왕사 초석의 장식에 관한 연구)

  • Kim, Sang-Tae
    • Korean Institute of Interior Design Journal
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    • v.16 no.1 s.60
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    • pp.3-10
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    • 2007
  • In the 7th century, Sachunwang-sa temple had two extra building-sites behind the Main hall. These two building-sites were found to be in peculiar form different from any another existing stone bases. The stone bases of northern put of these building-sites were decorated to molding as the protruding comers of eaves, which was pierced into a circular hole, and was carved into a form of Gomeck-ii(the stone bases lot supporting the wall). The northern building of sachunwang-sa temple was found to be used as the altar following munduru(文豆婁) method, through the observations of the archives of Samkukyusa(三國遺事) and the Abhiseka stura(skt. 灌頂經). The molding as the protruding cornets of eaves of stone bases was shaped as the roof of a building and the carving of Gomeck-ii gives a proof of the existence of the wall between columns in the altar. The hole of the stone bases protected the wooden cylinder of munduru from the exterior world. The author concludes, through this research, that the altar of Schunwang-sa temple was used lot the religious service during the war for worthship and protecting from the enemies. Also he concludes that these buildings must have been in wooden pagodas constructed upon a square plan, that is with both front and side width equal, haying a quite small scaled and low floored building with its first floor closed on all sides, being different item the usual form.

THE STUDY ON THE LEAKAGE OF BLEACHING AGENTS THROUGH CERVICAL AREA ACCORDING TO THE BASING METHOD (이장재 도포 방법에 따른 표백제의 치경부 누출에 대한 연구)

  • Kim, Sung-Chul;Yoon, Tae-Chull;Park, Dong-Soo
    • Restorative Dentistry and Endodontics
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    • v.20 no.1
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    • pp.250-260
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    • 1995
  • Bases have been used in order to prevent the leakage of bleachingagents through dentinal tubules in bleached teeth. But the proximal surfaces where the actual resorption takes place havenot been protected. The purpose of this study was to compare the conventional basing method with the basing of the labial and two proximal surfaces to the cementoenamel junction. The bases were placed after conventional root canal treatment. Group I: 2mm thickness bases were placed to the level of labial cementoenamel junction line. Group II : 2mm thickness bases were placed to the level of all c-e J lines including cervical area. Control : No bases were placed. After placement of sodium perborate and 30% hydrogen peroxide mixtureinto the teeth, the changes of pH were measured. The results were as follows. 1. Group II showed smaller leakage of bleaching agents and was statistically significant difference compared to Group I.(p<0.05) 2. Group I showed no statistically significant difference compared to the control group. (p>0.05) 3. There were no significant among the upper and lower teeth groups in each group and between the groups.(p>0.05). According to the above results, it was considered that basing of the labial and proximal surfaces to the cementoenamel junction can reduce the leakage of bleaching agents during bleaching procedure of pulplessteeth.

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A Study on Applications of Wavelet Bases for Efficient Image Compression (효과적인 영상 압축을 위한 웨이브렛 기저들의 응용에 관한 연구)

  • Jee, Innho
    • Journal of IKEEE
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    • v.21 no.1
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    • pp.39-45
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    • 2017
  • Image compression is now essential for applications such as transmission and storage in data bases. For video and digital image applications the use of long tap filters, while not providing any significant coding gain, may increase the hardware complexity. We use a wavelet transform in order to obtain a set of bi-orthogonal sub-classes of images; First, the design of short kernel symmetric analysis is presented in 1-dimensional case. Second, the original image is decomposed at different scales using a subband filter banks. Third, this paper is presented a technique for obtaining 2-dimensional bi-orthogonal filters using McClellan transform. It is shown that suggested wavelet bases is well used on wavelet transform for image compression. From performance comparison of bi-orthogonal filter, we actually use filters close to ortho-normal filters on application of wavelet bases to image analysis.

Comparing accuracy of denture bases fabricated by injection molding, CAD/CAM milling, and rapid prototyping method

  • Lee, Suji;Hong, Seoung-Jin;Paek, Janghyun;Pae, Ahran;Kwon, Kung-Rock;Noh, Kwantae
    • The Journal of Advanced Prosthodontics
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    • v.11 no.1
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    • pp.55-64
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    • 2019
  • PURPOSE. The accuracy of denture bases was compared among injection molding, milling, and rapid prototyping (RP) fabricating method. MATERIALS AND METHODS. The maxillary edentulous master cast was fabricated and round shaped four notches were formed. The cast was duplicated to ten casts and scanned. In the injection molding method, designed denture bases were milled from a wax block and fabricated using SR Ivocap injection system. Denture bases were milled from a pre-polymerized block in the milling method. In the RP method, denture bases were printed and post-cured. The intaglio surface of the base was scanned and surface matching software was used to measure inaccuracy. Measurements were performed between four notches and two points in the mid-palatal suture to evaluate inaccuracy. The palatine rugae resolution was evaluated. One-way analysis of variance was used for statistical analysis at ${\alpha}=.05$. RESULTS. No statistically significant differences in distances among four notches (P>.05). The accuracy of the injection molding method was lower than those of the other methods in two points of the mid-palatal suture significantly (P<.05). The degree of palatine rugae resolution was significantly higher in the injection molding method than that in other methods (P<.05). CONCLUSION. The overall accuracy of the denture base is higher in milling and RP method than the injection molding method. The degree of fine reproducibility is higher in the injection molding method than the milling or RP method.

Teachers' Knowledge Base and The Structure of Mathematical Knowledge for Effective Mathematics Teaching (효과적인 수학 교수를 위한 교사 지식 기반 영역과 수학적 지식 구조)

  • Kim, Young-Ok
    • Journal of the Korean School Mathematics Society
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    • v.11 no.4
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    • pp.595-608
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    • 2008
  • The purpose of this study is to address the teachers' knowledge bases for effective mathematics teaching and especially to provide the various definitions and the structures of mathematics knowledge which is the most important one of the knowledge bases. The conceptual understanding about teachers' knowledge bases for effective mathematics teaching and the structure of mathematics knowledge may be used in evaluating effective mathematics teaching and teachers as well as in developing a new conceptual framework for the structure of mathematical knowledge.

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Introduction of ISO 3010 -Bases for Design of Structures-Seismic Actions on Structure (국제 내진 기준(ISO 3010) 소개 및 평가)

  • 한상환
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2000.04a
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    • pp.417-426
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    • 2000
  • This paper introduces the ISO 3010 which is the design standard for seismic action of International Standard Organization. Specially this paper focuses on the philosophical background and the weakness of ISO 3010,. The ISO 3010\ulcorner(Bases for design of structures-Seismic action on structure) were made in 1998 by the efforts of ISO/TC98 which is one working group of ISO. TC98 deals with " Bases for design of structures" in the field of architectural and civil engineering. The revised Committee Draft ISO/CD 3010 was made in February 1999. Even if ISO 3010 has not been complete yet this study carry out critical review of this committee draft.tee draft.

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