• Title/Summary/Keyword: base-metal

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Intermediate band solar cells with ZnTe:Cr thin films grown on p-Si substrate by pulsed laser deposition

  • Lee, Kyoung Su;Oh, Gyujin;Kim, Eun Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.247.1-247.1
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    • 2016
  • Low-cost, high efficiency solar cells are tremendous interests for the realization of a renewable and clean energy source. ZnTe based solar cells have a possibility of high efficiency with formation of an intermediated energy band structure by impurity doping. In this work, ZnO/ZnTe:Cr and ZnO/i-ZnTe structures were fabricated by pulsed laser deposition (PLD) technique. A pulsed (10 Hz) Nd:YAG laser operating at a wavelength of 266 nm was used to produce a plasma plume from an ablated a ZnTe target, whose density of laser energy was 10 J/cm2. The base pressure of the chamber was kept at approximately $4{\times}10-7Torr$. ZnTe:Cr and i-ZnTe thin films with thickness of 210 nm were grown on p-Si substrate, respectively, and then ZnO thin films with thickness of 150 nm were grown on ZnTe:Cr layer under oxygen partial pressure of 3 mTorr. Growth temperature of all the films was set to $250^{\circ}C$. For fabricating ZnO/i-ZnTe and ZnO/ZnTe:Cr solar cells, indium metal and Ti/Au grid patterns were deposited on back and front side of the solar cells by using thermal evaporator, respectively. From the fabricated ZnO/ZnTe:Cr and ZnO/i-ZnTe solar cell, dark currents were measured by using Keithley 2600. Solar cell parameters were obtained under Air Mass 1.5 Global solar simulator with an irradiation intensity of 100 mW/cm2, and then the photoelectric conversion efficiency values of ZnO/ZnTe:Cr and ZnO/i-ZnTe solar cells were measured at 1.5 % and 0.3 %, respectively.

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Synthesis and Characterization of SnO2 Thin Films Deposited by Plasma Enhanced Atomic Layer Deposition Using SnCl4 Precursor and Oxygen Plasma

  • Lee, Dong-Gwon;Kim, Da-Yeong;Gwon, Se-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.254-254
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    • 2016
  • Tin dioxide (SnO2) thin film is one of the most important n-type semiconducting materials having a high transparency and chemical stability. Due to their favorable properties, it has been widely used as a base materials in the transparent conducting substrates, gas sensors, and other various electronic applications. Up to now, SnO2 thin film has been extensively studied by a various deposition techniques such as RF magnetron sputtering, sol-gel process, a solution process, pulsed laser deposition (PLD), chemical vapor deposition (CVD), and atomic layer deposition (ALD) [1-6]. Among them, ALD or plasma-enhanced ALD (PEALD) has recently been focused in diverse applications due to its inherent capability for nanotechnologies. SnO2 thin films can be prepared by ALD or PEALD using halide precursors or using various metal-organic (MO) precursors. In the literature, there are many reports on the ALD and PEALD processes for depositing SnO2 thin films using MO precursors [7-8]. However, only ALD-SnO2 processes has been reported for halide precursors and PEALD-SnO2 process has not been reported yet. Herein, therefore, we report the first PEALD process of SnO2 thin films using SnCl4 and oxygen plasma. In this work, the growth kinetics of PEALD-SnO2 as well as their physical and chemical properties were systemically investigated. Moreover, some promising applications of this process will be shown at the end of presentation.

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ZnTe:O/CdS/ZnO intermediate band solar cells grown on ITO/glass substrate by pulsed laser deposition

  • Lee, Kyoung Su;Oh, Gyujin;Kim, Eun Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.197.2-197.2
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    • 2015
  • Low-cost, high efficiency solar cells are tremendous interests for the realization of a renewable and clean energy source. ZnTe based solar cells have a possibility of high efficiency with formation of an intermediated energy band structure by impurity doping. In this work, the ZnTe:O/CdS/ZnO structure was fabricated by pulsed laser deposition (PLD) technique. A pulsed (10 Hz) Nd:YAG laser operating at a wavelength of 266 nm was used to produce a plasma plume from an ablated a ZnTe target, whose density of laser energy was 4.5 J/cm2. The base pressure of the chamber was kept at a pressure of approximately $4{\times}10-7Torr$. ZnO thin film with thickness of 100 nm was grown on to ITO/glass, and then CdS and ZnTe:O thin film were grown on ZnO thin film. Thickness of CdS and ZnTe:O were 50 nm and 500 nm, respectively. During deposition of ZnTe:O films, O2 gas was introduced from 1 to 20 mTorr. For fabricating ZnTe:O/CdS/ZnO solar cells, Au metal was deposited on the ITO film and ZnTe:O by thermal evaporation method. From the fabricated ZnTe:O/CdS/ZnO solar cell, current-voltage characteristics was measured by using HP 4156-a semiconductor parameter analyzer. Finally, solar cell performance was measured using an Air Mass 1.5 Global (AM 1.5 G) solar simulator with an irradiation intensity of 100 mW cm-2.

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A Study on Characteristic of Fracture in Lap Joint Welded STS429L (STS429L 겹침 용접부의 파단 특성에 관한 연구)

  • Choi, Dong-Soon;Kim, Jae-Seong;Kim, Hyun-Jae;Lee, Bo-Young
    • Journal of Welding and Joining
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    • v.27 no.5
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    • pp.49-54
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    • 2009
  • Recently, a demand of ferritic STS is increasing rapidly in automobile exhaust system. Exhaust manifolds are the part nearest to the engine so that the material is exposed to high temperature exhaust gas. Excellent heat resistant properties, especially high temperature strength, thermal fatigue resistance and high corrosion resistance are necessary for these parts. STS429L contains 15 weight percent of Cr and low Mo, so has good price competitive. And it has excellent high temperature strength and corrosion resistance, so receives attentions as material that applying to exhaust manifold. In tensile test of lap joint welded STS 429L, most of specimens are failed in base metal, but occurs brittle fracture in weld metals at some specimens in the face of good welding conditions. In the process of tensile test, lap joint welded STS429L specimens are transformed locally. The brittle fracture occurs that local transforming area exists in weld metals. But, butt welding specimens made by same materials showed ductile fracture in tensile test and bending test. In this study, suppose the reason of brittle fracture is in the combined local transform and tensile stress, through analysis of bead geometry, evaluate geometrical factor of brittle fracture in lap joint welded STS429L.

AN EXPERIMENTAL STUDY ON THE MANDIBULAR CONDYLAR GROWTH FOLLOWING LATERAL DISPLACEMENT IN RABBIT (하악골 측방변위가 가토의 하악두에 미치는 영향에 관한 실험적 연구)

  • Shin, Dong-Young;Suh, Cheong-Hoon
    • The korean journal of orthodontics
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    • v.22 no.2 s.37
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    • pp.427-447
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    • 1992
  • The purpose of this study was to evaluate the effect of the lateral displacement on the mandibular condylar growth in the rabbit. The experimental animals were twenty White NewZealand rabbits of 4-week old. Ten of them was used as control group, and experimental animal was composed of remaining ten. Laterodeviation appliance was made of cast base metal and appliance was cemented with resin in permanent fashion. Experimental group were sacrificed at 1, 2, 4, 6, 8 weeks form beginning of the experiment. Both of temporomandibular joint were prepared for histologic study. The conclusions are: 1. In control group, there was slight increase of proliferative zone and hypertrophic zone at 2-week control animal and slight reduction at 4-week. 6-week and 8-week control animal were similiar to 1-week control animal. 2. In right mandibular condyle of experimental group, 2-week experimental animal showed marked increase of proliferative zone and hypertrophic zone at posterior surface of condylar head. In 8-week experimental animal marked increase at anterior surface of anticular surface is observed. 3. In left mandibular condyle of experimental group, proliferative zone and hypertrophic zone were reduced at 1-week experimental animal and slight increase at 2-week. Proliferative zone and hypertrophic zone were reduced at 4-week experimental animal and were slightly increased at 6 week. 4. After 8 weeks, right and left condyle were not different in experimental group. The condylar cartilage was stabilized 8 weeks after the experiment. No marked traumatic change was seen, but minute focal bleeding was seen at articular cavity in 1-week, 2-week and 4-week experimental animal. 6-week and 8-week experimental animal did not show bleeding tendency in articular cavity.

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Performance of carbon fiber added to anodes of conductive cement-graphite pastes used in electrochemical chloride extraction in concretes

  • Pellegrini-Cervantes, M.J.;Barrios-Durstewitz, C.P.;Nunez-Jaquez, R.E.;Baldenebro-Lopez, F.J.;Corral-Higuera, R.;Arredondo-Rea, S.P.;Rodriguez-Rodriguez, M.;Llanes-Cardenas, O.;Beltran-Chacon, R.
    • Carbon letters
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    • v.26
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    • pp.18-24
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    • 2018
  • Pollution of chloride ion-reinforced concrete can trigger active corrosion processes that reduce the useful life of structures. Multifunctional materials used as a counter-electrode by electrochemical techniques have been used to rehabilitate contaminated concrete. Cement-based pastes added to carbonaceous material, fibers or dust, have been used as an anode in the non-destructive Electrochemical Chloride Extraction (ECE) technique. We studied the performance of the addition of Carbon Fiber (CF) in a cement-graphite powder base paste used as an anode in ECE of concretes contaminated with chlorides from the preparation of the mixture. The experimental parameters were: 2.3% of free chlorides, 21 days of ECE application, a Carbon Fiber Volume Fraction (CFVF) of 0.1, 0.3, 0.6, 0.9%, a lithium borate alkaline electrolyte, a current density of $4.0A/m^2$ and a cement/graphite ratio of 1.0 for the paste. The efficiency of the ECE in the traditional technique using metal mesh as an anode was 77.6% and for CFVF of 0.9% it was 90.4%, with a tendency to increase to higher percentages of the CFVF in the conductive cement-graphite paste, keeping the pH stable and achieving a homogeneous ECE in the mass of the concrete contaminated with chlorides.

The origination and Changes of Street Style on the Development of Rock Music (락(Rock) 음악의 발전에 따른 스트리트 스타일의 발생과 변천)

  • 정미진;정흥숙;김선화
    • Journal of the Korean Society of Costume
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    • v.52 no.5
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    • pp.173-186
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    • 2002
  • Street Style, occurred in British and America, has been expressed the character of the new generation by repeating developments and changes. Nowadays, pop music reflects the phase of society. and simultaneously it has influence on from culture to society. Rock Music was rooted in Country 8l western of America. Upon Country & Western, Afro-Americans Rhythm & Blues was added, and that was the birth of Rockabilly. Rockabilly developed to Rock'n 'roll and it started to change to various forms of Rock since 1950s. As the commercial impact and the breakthrough of teenagers emotion, the rock culture comprised the base of the youth culture. However. it formed the anti-establishment culture against the established value, accepting working class subculture. The teenager culture was affected by the Rock culture, also found relief in the opulence provided by the established generation, imitating it as it was. Simultaneously, it had a contrary aspect as anti-establishment form under the banner of revolt against languor in richness. The youth culture created street style that was escaped from high fashion, every time Rock music had changes. Since Street style was based on resistance of established culture and it fully refused vogue, it was indifferent from high fashion. The results of this study were as following. First, every time Rock music had changes, the new youth culture was concomitant with, the youth culture created street style. Secondly, rockahibilly style was characterized as diamond shaped design, embroidery, extra wide shirt collar, vivid contrast color . Rockers style was represented as metal studs, beads, denim, leather jacket, boots. Fusion of hippies style and Psychedelic, long hair, beads. worn denim were elements of headbangers style. Punks style was characterized as ripped T-shirt. rooster hair, over decorated jacket, short skirt. net or plastic T-shirt. Lastly, the firm relation between popular art and fashion was proved by examining the history of Rock Music and Street Style.

Characteristics of Fiber Laser Welding on STS304L for GTT MARK III Membrane (GTT MARK III 스테인리스강 STS304L의 파이버 레이저 용접특성)

  • Kim, Jong-Do;Lee, Chang-Je;Song, Moo-Keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.8
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    • pp.1069-1075
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    • 2012
  • Laser is high density heat source, so it can make high speed welding with minimum heat input possible. Especially the high power fiber laser is recently commercialized and has high beam quality and the smallest system size compared with conventional laser due to it's unique oscillating mechanism. Because of these advantages it's thought that the most suitable heat source for LNG cargo tank welding precess which has to be conducted inside of ships. In this study fiber laser was used for welding of stainless steel for LNG carrier to applicate laser welding technique for shipbuilding industry. 1.2mmt STS304L of austenite stainless steel which apply to cargo tank was used for fiber laser welding. Butt and lap welding was conducted changing laser power, welding speed, then penetration characteristic was analyzed and optimal parameters for each materials. Consequently, we found that same or better mechanical properties were obtained in weld compared to base metal.

A study on the effect to yongrak phenomenon of submerged arc welding depending on the plasma cutting surface characteristics (플라즈마 절단면 특성이 서브머지드 아크용접 용락 현상에 미치는 영향에 관한 연구)

  • Kim, Jeongtae;Jeong, Hyomin;Ji, Myoungkuk;Chung, Hanshik
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.6
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    • pp.589-595
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    • 2013
  • This paper was to study the effect to Yongrak phenomenon of I groove submerged arc welding depending on the plasma cutting surface characteristics, and how to reduce the causes and characteristics Yongrak phenomenon. Shipbuilding and marine structures is designed to use the thick plates and welded by high current to obtain deep penetration. Yongrak phenomenon has been occurred frequently depending on the quality of cutting surface and it makes degrade of the welding quality and modification of the welding. As a result, it was confirmed that I Groove plasma cutting characteristics get bevel form of 2 to 4 degrees to one side direction from the vertical position with Yongrak phenomenon. This is the main reason of Yongrak phenomenon in butt joint welding and 4 degree reverse bevel on the upper surface of base metal by submerged arc welding brought the effect of significant reduction of Yongrak phenomenon.

A Study on the Evaluation of the Fracture Toughness for the Narrow Gap Welding Part of Nuclear Piping (원전배관 협개선 용접재 파괴인성 평가에 관한 연구)

  • Huh, Yong;Park, Soo;Sin, In-Hwan;Seok, Chang-Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.1
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    • pp.67-72
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    • 2010
  • The fracture toughness for the LBB analysis of piping is generally determined by the J-integral according to ASTM E1820. However, since this evaluates a base metal, the fracture toughness for narrow gap welding can be differently than the real value. This study evaluated the plastic  factor of the narrow gap welding part of a nuclear piping with SA508 Cl.1a and SA312 TP316. Also, it performed the fracture toughness test for the narrow gap welding part and applied the new plastic $\eta$ factor equation by Huh, et al. and then compared the results with those according with the ASTM standard.