• Journal of the Korean Chemical Society
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• v.34 no.6
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• pp.658-662
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• 1990

A method for regioselective mono-carbonylation of halobenzyl halide is described. Alkyl halophenylacetate is easily prepared by carbonylating a benzylic halide of halobenzyl halide in the presence of catalytic amount of cobalt carbonyl, a base, and an alcohol under atmospheric pressure of carbon monoxide. The base plays a decisive role in the selectivity of product and NEt$_3$ is the best one among bases used.

• Journal of Advanced Marine Engineering and Technology
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• v.22 no.4
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• pp.451-459
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• 1998

THe influence of internal acoustic exitation through a square prism on the turbulent wake flow characteristics was investigated. The intermediate wake region where is about ten times the respective length of the body was experimentally investigated using a conditional phase average technique. At first the static base pressures of square prism and the shedding frequencies have been measured at various internal acoustic exciation frequencies. The experiment were performed under the four cases of internal acoustic excitation frequencies 0Hz 30Hz($St_e$=0.09) 65Hz($St_e$=0.20) 120Hz($St_e$=0.38) And velocity vector fields were presented and discussed. The influence of acoustic exvitation frequencies on the structure of intermediate turbulent wake region is evident. As the internal acoustic frequency increased shedding frequency gradually increased and aerodynamic force decreased. Also it was found that the vortex shedding occurs dratically well and shedding frequency reached nearly the same value as the internal acoustic frequency. but above Strouhal number 0.3 the influence disappeared.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.968-971
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• 2017

In this study, manufacturing the Single Base propellant using a Nitroguanidine(NGD A%, NGD-B%, 2A=B). The Factors affecting the combustion rate are Moisture and Volatiles, Residual Solvents, Dimension. These Factors were analyzed and compared. Also, NGD-A% propellants and NGD-B% propellants were compared with firing test Test. As a result, NGD-A% was confirmed to have a higher speed at a similar pressure than NGD-B% propellants.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.459-463
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• 2006

For the purpose of developing liner board for water-resistant corrugated board in the cold chain system, several types of base paper for corrugated board were purchased from the market and 6 different boards were produced in the paperboard mill by applying the chemicals on the base paper. Then, water-moisture resistant performance and physical properties of the boards were evaluated and compared each other. The liner board which is dried at high temperature with pressure by the Condebelt showed a superior performance in strength over conventional liner boards. Strength of the board increased by surface chemical treatment up to 60% of compressive strength and 30% of bursting strength. Starch insolubilization with Ammonium-Zirconium -Carbonate and surface coating with a surface size and a moisture resistant chemical on CK paper showed the best result. Therefore, this method was recommended to produce the outer liner board for water -resistant corrugated board.

• Journal of Korean Society of Steel Construction
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• v.17 no.6 s.79
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• pp.717-726
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• 2005

This study investigates the bearing pressure distribution and design of an H-section steel column baseplate under concentric loading. In general, the size and thickness of the baseplate are determined with the assumption that the bearing pressure of the column baseplate is distributed uniformly. When the column is loaded lightly, however, the baseplate becomes smaller andthinner and the bearing pressure of the baseplate is distributed non-uniformly. In this study, the distribution of the bearing pressure is investigated using the experimental method and the analytical method. Seven specimens of the H-section steel column baseplate were fabricated and tested. The analysis of the specimens was performed using the finite element analysis program, ANSYS. It is not appropriate to use the Limit State Design,which assumes that the bearing pressure of the baseplate is distributed uniformly,because the bearing pressure is distributed non-uniformly and is concentrated under the column sectio.

• Transactions of Materials Processing
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• v.28 no.1
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• pp.43-48
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• 2019

Aluminum nitride (AlN) is used by the semiconductor industry, and is a compound that is required when manufacturing high thermal conductivity. The AlN films with c-axis orientation and thermal conductivity characteristic were deposited by using the Pulsed Laser Deposition (PLD). The AlN thin films were characterized by changing the deposition conditions. In particular, we have researched the AlN thin film deposited under optimal conditions for growth atmosphere. The epitaxial AlN films were grown on sapphire ($c-Al_2O_3$) single crystals by PLD with AlN target. The AlN films were deposited at a fixed temperature of $650^{\circ}C$, while conditions of nitrogen ($N_2$) pressure were varied between 0.1 mTorr and 10 mTorr. The quality of the AlN films was found to depend strongly on the $N_2$ partial pressure that was exerted during deposition. The X-ray diffraction studies revealed that the integrated intensity of the AlN (002) peak increases as a function the corresponding Full width at half maximum (FWHM) values decreases with lowering of the nitrogen partial pressure. We found that highly c-axis orientated AlN films can be deposited at a substrate temperature of $650^{\circ}C$ and a base pressure of $2{\times}10^{-7}Torr$ in the $N_2$ partial pressure of 0.1 mTorr. Also, it is noted that as the $N_2$ partial pressure decreased, the thermal conductivity increased.

• The Korean Journal of Nuclear Medicine Technology
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• v.13 no.3
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• pp.147-151
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• 2009

Purpose: 2-[$^{18}F$]Fluoro-2-deoxy-D-glucose ([$^{18}F$]FDG) particularly plays as a important role in Positron Emission Tomography (PET) imaging in nuclear medicine. Domestic [$^{18}F$]FDG auto synthesizers are installed in Seoul National University Bundang Hospital (SNUBH) at June 2008, these modules were known that it's synthetic yields were guaranteed in average $45{\pm}5%$ so far. To improve yields and convenience of domestic [$^{18}F$]FDG auto synthesizer, numerous trials in reaction time, base concentration, pressure and temperature were performed to increase [$^{18}F$]FDG yields. Materials and Methods: Several synthetic factors (temperature, time and pressure) and shortcoming were corrected based on many evaporation test. Syringe dispensing of tetra-butylammonium bicarbonate (TBAB) was replaced with micro pipette to prepare tetrabutyl ammonium fluoride salt ([$^{18}F$]TBAF). Troublesome refill of liquid nitrogen every 2 hours which was used to protect vacuum system was changed to charcoal cartridge, base guard filter. To monitor the volume of delivered $[^{18}O]OH_2$ from cyclotron by surveillance camera, we set up the volumetric vial on the cover of the module. In addition to, the recovery vial was added in [$^{18}F$]FDG production system to recover [$^{18}F$]FDG loss due to the leak of valve ($V_{13,14}$) in [$^{18}F$]FDG purification process. Results: When we used micro pipette for adding TBAB ($30\;{\mu}L$ in 12% $H_2O$ in acetonitrile), this quantitative dispensation has enabled to improve $5.5{\pm}1.7%$ residual fluorine-18 activity in fluorine separation cartridge compared to syringe adding. Besides, the synthetic yields of [$^{18}F$]FDG has increased $58{\pm}2.6%$ (n=19), $58{\pm}2.9%$ (n=14), $60%{\pm}2.5%$ (n=17) for 3 months. The life cycle of charcoal cartridge and base vacuum was 3 months prior to filling liquid nitrogen every 2 hours and additional side separator can prevent pump corrosion by organic solvent. After setting of volumetric indicator vial, the operator can easily monitor the total volume of irradiated $[^{18}O]OH_2$ from cyclotron. The recovery vial can be used for the stabilizer when an irregular [$^{18}F$]FDG loss was generated by the leak of valves ($V_{13,14}$). Conclusions: We has optimized appropriate synthetic conditions (temperature, time, pressure) in domestic [$^{18}F$]FDG auto synthesizer. In addition to, the remodeling with several accessories improve yields of domestic [$^{18}F$]FDG auto synthesizer with reliable reproducibility.

• Nuclear Engineering and Technology
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• v.27 no.5
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• pp.645-660
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• 1995

The loss of Residual Heat Removal System (RHRS) event during reduced inventory operation for the Korean Standard Nuclear Power Plants (KSNPPS) is simulated by RELAP5/MOD3 and RELAP5/MOD3.1 Tn cases are considered : Base case for an intact Reactor Coolant System (RCS) with no tent and a vent case for an open system. Comparative simulations of base case are peformed by RELAP5/MOD3 and RELAP5/MOD3. 1 computer codes. The results of too simulations are generally in good qualitative and quantitative agreement. However, since the results of RELAP5/MOD3 simulation reveals the deficiency of RELAP5/MOD3 wall heat model, the RELAP5/AOD3.1 computer code is used for the simulation of the vent case. The analysis result of base case show that two steam generators are insufficient to remove decay heat at one day after shutdown, where the RCS is closed. The RCS pressure increased continuously and reached the RCS temporary boundaries design pressure of 0.24 MPa around 4,000 seconds. In the vent case with a flow capacity equivalent to three times the capacity of Pressurizer Safety Valve (PSV), it is shown that the RCS Pressure does not reach 0.24 MPa and core uncovery does not occur until 10,000 seconds. The detailed discussions on the results of this study suggest the feasibility of RELAP5/AOD3.1 as an analysis tool for the simulation of the loss of RHRS event at reduced inventory operation. The results of this study also provide insight for the determination of proper vent capacity.

• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.706-712
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• 2014

Explosives are reactive material that contain a great amount of high potential energy. They produce detonation if released suddenly, accompanied by the production of strong light, high heat, great noise and high pressure. Damage at surrounding detonation point is affected by high pressure and blast wave for explosives detonation. Consequently, analysis of pressure and blast wave is very important. This study focuses on the analysis of maximum overpressure and blast wave of explosives for safety assurance. First of all, four cases of the amount of HMX were selected. Secondly, maximum pressure and blast wave were calculated through detonation simulation along with a set of TNT and HMX quantities. The peripheral effect of detonation point was analyzed by calculating overpressure and absolute velocity and considering detonation occurred in the center of geometry by HMX. Also, maximum overpressure and blast wave of HMX were compared to equivalent amount of TNT, which was taken as a base case and verified through theoretical HMX graph. This study contributes to the base case for overpressure and blast wave of complex gunpowder containing HMX.

• Computational Structural Engineering
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• v.9 no.4
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• pp.189-198
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• 1996

The fracture behaviour of concrete gravity dam mainly due to uplift pressure acting at the crack face was studied. Triangular type and parabolic type distribution of the uplift pressure including uniform type were first considered in case of calculating stress intensity factor(SIF) by the surface integral method. Second, the directions of crack propagation according to the uplift pressure distribution were pursued by FRANC(FRacture ANalysis Code). Third, critical crack lengths according to the uplift pressure distribution under the overflow depth were calculated. The SIF values obtained from the surface integral method were compared with those by FRANC and relatively good agrements could be obtained between both of them. And it could be seen that the direction of crack propagation in case of triangular pressure distribution was a little benter to the dam base than the one by the uniform type. Maximum critical crack lengths under the overflow depth were obtained at about 2/5-1/2 of the dam height.