• Title/Summary/Keyword: attachment of particle

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Investigation of chemical modification on tosyl-activated polystyrene microsphere magnetic particle surface by infrared microscopy (토실 활성화된 폴리스티렌 마이크로구체 자성 입자 표면의 화학적 변형에 대한 적외선 연구)

  • Byun, Chang Kyu
    • Analytical Science and Technology
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    • v.29 no.5
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    • pp.225-233
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    • 2016
  • The chemical engrafting of polymers on particle surface, plays an important role on selective partitioning of micro/nano-particles in the separated layers of liquid media, such as aqueous two phase systems (ATPSs). Three polymers, dextran, poly (ethylene glycol) and albumin were chosen and chemically conjugated to the polystyrene (PS) magnetic microparticle surface. The attachment of long-chained polymer chains which may switch the partition behavior, can be simply performed by SN2 substitution of various polymers having primary amine functional groups, with p-toluenesulfonyl (tosyl)-activated polystyrene magnetic micro-particles. The surface modification of microparticle was probed by infrared microscopy. The distinctive peak represents N-H stretching vibration mode for microparticles after the reaction and it is common for all three polymers examined. The locations of main peaks are similar for all micro-particles but different and distinguishable in fingerprint region.

A Study on the Characteristics of the Treatment with Bed Expansion and the Biomass Attachment in the Start-up of the AFBR (혐기성 유동층 반응기에서 층팽창에 따른 처리특성 및 미생물 부착특성)

  • 안재동;정종식;장인용
    • Journal of Environmental Health Sciences
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    • v.21 no.2
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    • pp.20-26
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    • 1995
  • The objective of this study is to estimate the effect of the bed expansion and the characteristics of attached biomass in the start-up in the anaerobic fluidized bed reactor(AFBR). The fluidized bed reactor was operated with bacteria supported on the bed of granular activated carbon(GAC). The reactor was operated at 35$\circ$C, 5 kg $COD/m^3\cdot day$ at bed expansion varying from 0 to 100% with soluble glucose wastewater(5,000 mg/l). When the effluent reached a steady state at 100% of bed expansion, maximum COD removal efficiency of 87.3% and 0.031 $m^3CH_4/kg COD_{removed}$ were obtained. At higher bed expansion, COD removal efficiency, methane production rate and biogas production rate increased. Especially, at 50% of bed expansion, the efficiency of the treatment increasedg rapidly in the AFBR. The biomass colonized in the pits and crevices of the GAC particle and no complete biofilm was established in the bioreactor during the experiment.

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A study on the Reduction of Scattering of Polyurea Coating for Waterproofing and Anti-Corrosion by Installing Air Jet Nozzle (에어분사구 설치에 따른 폴리우레아 도막 방수·방식재의 비산 발생 저감에 관한 연구)

  • Kim, Sun-Do;Park, Wan-Goo;Park, Jin-Sang;Cho, Il-Kyu;Kim, Byoung-Il;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.236-237
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    • 2017
  • This study discusses the development of waterproofing layer jet-spray nozzle that forms a three-dimensional air cell. This nozzle has an air flow generation mechanism in the air groove of the attachment cell part located at the end of the injection nozzle. Since the air grooves also function as an air curtain, the airborne particles generated when the waterproof material is sprayed is effectively blocked. In the past, spraying of the waterproof material through the high pressure was possible, but this technology allows stable injection due to the static agitation method, and various problems caused by particle generation has been (damages to neighboring areas, economic loss, etc.) minimized.

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The Characteristics of Suspended Particulate Matters in Downtown Seoul During Winter Period (겨울철 서울도심의 대기중 부유분진의 특성)

  • Kim, Shin-Do;Kim, Jong-Ho;Lee, Jeong-Joo
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.2
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    • pp.105-111
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    • 1992
  • The characteristics of suspended particulate matters(dust) in Seoul had been studied. The effects of various environmental factors, such as passengers, motor vehicles, wind velocity, wind direction, temperature and humidity were examined during the study period. It was shown that the dust emission occurred through the heating was the major source, and the contribution of passengers and motor vehicles was relatively negligible during the night. It was also revealed that the number concentration between $0.5{\mu}m$ and $2.0{\mu}m$ was increased due to the attachment among the dusts and mists by the increased humidity during the night. Considering the fact that the particles larger than $2{\mu}m$ take the most part of weight concentration, it was suggested that the PM-10 method which considered respirable particle as a weighting factor should be adapted in the evaluation air quality.

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Sample Preparation for EBSD Analysis: Tips for Metals with Delicate Surfaces (표면처리가 어려운 금속재료의 EBSD 분석을 위한 시편 준비)

  • Kang, Joo-Hee;Kim, Su-Hyeon
    • Korean Journal of Metals and Materials
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    • v.48 no.8
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    • pp.730-740
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    • 2010
  • Aluminum, magnesium, titanium and high Mn steel are difficult to use in electron backscatter diffraction (EBSD) sample preparation due to the formation of an oxidation layer under conventional polishing. Alcohol-based polishing with colloidal silica suspension was introduced for these delicate samples. A hard particle-embedded sample was analyzed successfully using mechanical polishing. Ion-milling was effective in removing oxidized, deformed and transformed layers after mechanical polishing and was able to reduce artifacts significantly. The microstructure of a cross-section of a thin copper film was evaluated by attachment of a dummy to the film for mechanical polishing.

Evaluation of Flotation Efficiency and Particle Separation Characteristics of Carbon Dioxide Bubbles using Collision Efficiency Model (단일포집자충돌(SCC) 모델을 이용한 이산화탄소기포의 입자분리특성과 부상효율 평가)

  • Lee, Jun-Young;Kim, Seong-Jin;Yoo, Young-Hoon;Chung, Paul-Gene;Kwon, Young-Ho;Park, Yang-Kyun;Kwak, Dong-Heui
    • Journal of Korean Society on Water Environment
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    • v.28 no.1
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    • pp.129-136
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    • 2012
  • In this century, scientists realized that carbon dioxide gas in the atmosphere cause a greenhouse effect which affects the planet's temperature. Therefore lots of attempts have carried out to decrease the discharge of carbon dioxide gas in the field. The dissolved carbon dioxide flotation (DCF) process was developed as an alternative of DAF process to decrease the discharge and reuse of carbon dioxide as well as to save energy consumption. To investigate the particle separation characteristics and the flotation efficiency of carbon dioxide, SCC model was employed in the DCF process which has been applied extensively for the evaluation and simulation in the DAF process. The simulation results by the SCC model revealed the predicted curve of flotation efficiency became decreased gradually over the optimal pressure range of saturator about 1.6 atm in accordance with the experiment results of the DCF pilot plant and the size distribution and the bubble volume concentration of $CO_{2}$ bubbles depending on the operation pressure of saturator. The findings through the simulation results led to the conclusion that there was no significant difference between $CO_{2}$ bubbles and air bubbles, affecting on the practical flotation efficiency, in terms of the initial collision and attachment efficiency.

Detachment of nanoparticles in granular media filtration

  • Kim, Ijung;Zhu, Tongren;Jeon, Chan-Hoo;Lawler, Desmond F.
    • Membrane and Water Treatment
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    • v.11 no.1
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    • pp.1-10
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    • 2020
  • An understanding of particle-particle interactions in filtration requires studying the detachment as well as the attachment of nanoparticles. Nanoparticles captured in a granular media filter can be released by changing the physicochemical factors. In this study, the detachment of captured silver nanoparticles (AgNPs) in granular media filtration was examined under different ionic strengths, ion type, and the presence or absence of natural organic matter (NOM). Filtration velocity and ionic strength were chosen as the physical and chemical factors to cause the detachment. Increasing filtration velocity caused a negligible amount of AgNP detachment. On the other hand, lowering ionic strength showed different release amounts depending on the background ions, implying a population of loosely captured particles inside the filter bed. Overall detachment was affected by ionic strength and ion type, and to a lesser degree by NOM coating which resulted in slightly more detachment (in otherwise identical conditions) than in the absence of that coating, possibly by steric effects. The secondary energy minimum with Na ions was deeper and wider than with Ca ions, probably due to the lack of complexation with citrate and charge neutralization that would be caused by Ca ions. This result implies that the change in chemical force by reducing ionic strength of Na ions could significantly enhance the detachment compared to that caused by a change in physical force, due to a weak electrostatic deposition between nanoparticles and filter media. A modification of the 1-D filtration model to incorporate a detachment term showed good agreement with experimental data; estimating the detachment coefficients for that model suggested that the detachment rate could be similar regardless of the amount of previously captured AgNPs.

Theoretical Studies of the Electrical Discharge Characteristics of Sulfur Hexafluoride

  • Radmilovic-Radjenovic, Marija;Radjenovic, Branislav
    • Journal of Electrical Engineering and Technology
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    • v.12 no.1
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    • pp.288-294
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    • 2017
  • This paper contains results of the theoretical studies of the electrical breakdown properties in sulfur hexafluoride. Since the strong interaction of high-energy electrons with the polyatomic sulfur hexafluoride molecule causes their rapid deceleration to the lower energy of electron capture and dissociative attachment, the breakdown is only possible at relatively high field strengths. From the breakdown voltage curves, the effective yields that characterize secondary electron productions have been estimated. Values of the effective yields are found to be more consistent if they are derived from the experimentally determined values of the ionization coefficient and the breakdown voltages. In addition, simulations were performed using an one-dimensional Particle-in-cell/Monte Carlo collision code. The obtained simulation results agree well with the available experimental data with an error margin of less than 10% over a wide range of pressures and the gap sizes. The differences between measurements and calculations can be attributed to the differences between simulation and experimental conditions. Simulation results are also compared with the theoretical predictions obtained by using expression that describes linear dependence of the breakdown voltage in sulfur hexafluoride on the pressure and the gap size product.

Fabrication and Manipulation of Gold 1D Chain Assemblies Using Magnetically Controllable Gold Nanoparticles

  • Kim, Lily Nari;Kim, Eun-Geun;Kim, Junhoi;Choi, Sung-Eun;Park, Wook;Kwon, Sunghoon
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3735-3739
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    • 2012
  • We have developed magnetically controllable gold nanoparticles by synthesizing superparamagnetic $Fe_3O_4$ core/gold shell nanoparticles. The core/shell particles have the capability of forming gold 1D chains in the presence of an external magnetic field. Here we demonstrate dynamic and reversible self-assembly of the gold 1D chain structures in an aqueous solution without any templates or physical or chemical attachment. The spatial configuration of gold chains can be arbitrarily manipulated by controlling the direction of a magnetic field. This technique can provide arbitrary manipulation of gold 1D chains for fabrication purpose. To demonstrate this capability, we present a technique for immobilization of the gold particle chains on a glass substrate.

Control of Turbid Water Transport with Filamentous Mat (섬모상 매트에 의한 탁수이동차단에 관한 실험적 연구)

  • Yu, Jianghua;Yi, Qitao;Kim, Youngchul
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.44-51
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    • 2010
  • A lab-scale apparatus for turbid water transport control was tested and examined. The channel had a dimension of $100cm{\times}30cm{\times}15cm$ (length${\times}$hight${\times}$width). And the turbidity water was prepared using two types of particles, bentonite and loess. The channel equipped with filamentous mat was operated under various shock load conditions. In the control channel, instantly, turbid water mixed with the clean water inside the channel and turbidity prevails the entire channel. While in the mat-equipped channel, it increases only at the bottom. Overall, the filamentous mat gave capture efficiency of 70~90% compared with the control group. The capture efficiency of turbid particles decreased with increased input turbidity flux. The result of experimental run on how turbid particles are separated in the mat channel shows that settling, filtration and attachment are the main processes. Meanwhile, turbidity was diffused from the channel bottom due to turbidity gradient before and after mat zone. The particle size before mat zone was lightly coarser than that after mat zone.