• 제목/요약/키워드: atomic processes

검색결과 450건 처리시간 0.027초

원자층 증착법을 통하여 유리 기판에 증착한 Ti-ZnO 박막의 전기적 광학적 특성 (Electrical and Optical Properties of Ti-ZnO Films Grown on Glass Substrate by Atomic Layer Deposition)

  • 이우재;김태현;권세훈
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2018년도 춘계학술대회 논문집
    • /
    • pp.57-57
    • /
    • 2018
  • Zinc-oxide (ZnO), II-VI semiconductor with a wide and direct band gap (Eg: 3.2~3.4 eV), is one of the most potential candidates to substitute for ITO due to its excellent chemical, thermal stability, specific electrical and optoelectronic property. However, the electrical resistivity of un-doped ZnO is not low enough for the practical applications. Therefore, a number of doped ZnO films have been extensively studied for improving the electrical conductivities. In this study, Ti-doped ZnO films were successfully prepared by atomic layer deposition (ALD) techniques. ALD technique was adopted to careful control of Ti doping concentration in ZnO films and to show its feasible application for 3D nanostructured TCO layers. Here, the structural, optical and electrical properties of the Ti-doped ZnO depending on the Ti doping concentration were systematically presented. Also, we presented 3D nanostructured Ti-doped ZnO layer by combining ALD and nanotemplate processes.

  • PDF

INTERPRETATION OF ELECTROCHEMICAL NOISE PARAMETERS AS INDICATORS OF INITIATION AND PROPAGATION OF SCC OF AN ALLOY 600 SG TUBE AT HIGH TEMPERATURES

  • Kim, Sung-Woo;Kim, Hong-Pyo
    • Nuclear Engineering and Technology
    • /
    • 제41권10호
    • /
    • pp.1315-1322
    • /
    • 2009
  • The present article is concerned with the application of an electrochemical noise (EN) monitoring technique to analyze the initiation and propagation of Pb-assisted stress corrosion cracking (SCC) of an Alloy 600 material in a simulated environment of a steam generator (SG) sludge pile at high temperatures. A typical increase of electrochemical current noise (ECN) and electrochemical potential noise (EPN) was frequently recorded from the EN measurement in a caustic solution with such impurities as PbO and CuO, indicating that there are localized corrosion events occurring. With the aid of microscopic and spectral analyses, the EN data involving information on such stochastic processes as uniform corrosion and the initiation and propagation of SCC, were analyzed based on a stochastic theory.

A Thermal hydraulic Investigation on ADSR Liquid Lead Target

  • Kim, Ju Y.;Byung G. Huh;Chang H, Chung;Tae Y. song;Park, Won S.
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1998년도 춘계학술발표회논문집(1)
    • /
    • pp.666-671
    • /
    • 1998
  • Computational fluid dynamics(CFD) code FLUENT[11 was used to simulate the thermal hydraulic processes occuring in conceptual design of the accelerator-driven subcritical reactor(ADSR) liquid lead target. The purpose of the analysis is to investigate the thermal hydraulic characteristics of liquid lead as ADSR target material with various target geometries and injection locations of proton beam. In the calculation analysis, the local temperature of the liquid lead target rises to the boiling temperature very rapidly When the proton beam is injected from the bottom of the target system, the duration time to reach the boiling temperature is longer and the temperature distribution is flatter than other cases.

  • PDF

환원확산법에 의한 TiFe 수소 흡장합금의 제조에 관한 기초적 연구 (Fundamental Study on the Production of TiFe Hydrogen Alloy by the Reduction-Diffusion Process)

  • 권호영;일본명;일본명
    • 한국안전학회지
    • /
    • 제8권2호
    • /
    • pp.3-9
    • /
    • 1993
  • For comparison, we used Ca and Mg as reducers to produce TiFe hydrogen stroage alloy from Fe and TiO$_2$by the Reduction-Diffusion process. The results obtained were as follow. \circled1 Ca was found to be effective both for reduction and diffusion processes. Moreover, Ca oxide was easily removed in an NH$_4$Cl solution after the reaction. \circled2 In the case of using Ca as a reducer, the Reduction-Diffusion process is considered to take place in the foiling three steps. First, TiO$_2$is reduced to Ti by Ca over 100$0^{\circ}C$. Second, the atomic Ti drifts in the Ca melt and meets Fe particles. Finally, the atomic Ti diffuses in to the Fe particles. \circled3 In the case of using Mg as a reducer, We found that the reduction reaction of TiO$_2$went well. But the reduced Ti scarcely diffused into Fe particles. This was probably because no Mg melt was formed due to the high vapor pressure of Mg.

  • PDF

광물표면의 화학적 특성과 금속이온 수착의 고찰: A Review (Chemical Properties of Mineral Surfaces and Metal Ion Sorption: A Review)

  • 윤소정
    • 자원환경지질
    • /
    • 제45권2호
    • /
    • pp.205-215
    • /
    • 2012
  • 금속이온은 토양이나 퇴적물 내의 광물에 수착되어 고착화될 수 있다. 여기서는 광물 표면의 화학적 특성과 금속이온의 수착에 관련된 이론 및 수착 연구를 위한 X-선 흡수 미세구조(extended X-ray absorption fine structure, EXAFS) 분석방법에 대해 알아보고 금속이온의 광물표면 수착에 관한 원자 단위 연구 결과를 정리하였다. 광물표면의 특성과 금속이온의 수착에 관한 원자 단위 이론의 이해는 원자 단위 분광법의 분석을 수행하는데 있어서 기초가 된다. 여기에 정리된 원자 단위 수착상 연구 결과는 외부권 착물, 내부권 착물, 표면침전뿐 아니라 공침전, 삼성분 착물, 수착반응 시간의 효과, 탈착가능성을 포함한다.

자기펄스 가압성형법에 의한 알루미나 나노분말의 치밀화 및 특성 평가 (Densification of Al2O3 Nanopowder by Magnetic Pulsed Compaction and Their Properties)

  • 강래철;이민구;김홍회;이창규;홍순직
    • 한국분말재료학회지
    • /
    • 제15권1호
    • /
    • pp.37-45
    • /
    • 2008
  • This article presents the challenges toward the successful consolidation of $Al_2O_3$ nanopowder using magnetic pulsed compaction (MPC). In this research the ultrafine-structured $Al_2O_3$ bulks have been fabricated by the combined application of magnetic pulsed compaction (MPC) and subsequent sintering, and their properties were investigated. The obtained density of $Al_2O_3$ bulk prepared by the combined processes was increased with increasing MPC pressure from 0.5 to 1.25 GPa. Relatively higher hardness and fracture toughness in the MPCed specimen at 1.25 GPa were attributed to the retention of the nanostructure in the consolidated bulk without cracks. The higher fracture toughness could be attributed to the crack deflection by homogeneous distribution and the retention of nanostructure, regardless of the presence of porosities. In addition, the as consolidated $Al_2O_3$ bulk using magnetic pulsed compaction showed enhanced breakdown voltage.

9Cr-3W 강의 크리프 특성에 미치는 Mo 첨가의 영향 (Effect of Mo addition on the Creep Properties of 9Cr-3W Steel)

  • 김용래;장진성;김태규
    • 한국주조공학회지
    • /
    • 제33권1호
    • /
    • pp.1-7
    • /
    • 2013
  • The effect of the Mo addition on the high temperature creep properties of the 9Cr-3W steel was also evaluated. Two experimental steels, (9Cr-3W and 9Cr-3W-0.5Mo), were prepared using a vacuum induction melting process, followed by hot rolling and heat treatment processes. Three types of precipitates, ($M_{23}C_6$, Nb-rich MX and V-rich MX) were observed in a typical tempered martensitic matrix. Significant effects of the Mo addition on the tensile properties were not observed. However, the creep properties at $650^{\circ}C$ under applied stresses of 140 and 150 MPa were considerably enhanced by the Mo addition. The microstructural observation after the creep test indicated that the addition of Mo could function to retain the recovery of the martensitic matrix, thus resulting in the enhanced creep properties of the 9Cr-3W-0.5Mo steel. Furthermore coarsening of the $M_{23}C_6$ carbides and formation of Laves phases were observed in both samples after the creep tests.

Calculation of The Core Damage & FP Release Behavior for The PHEBUS FPT0 Similar to Cold Leg Break Accident Using MELCOR

  • Park, Jong-Hwa;Cho, Song-Won;Kim, Hee-Dong
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1996년도 춘계학술발표회논문집(2)
    • /
    • pp.637-642
    • /
    • 1996
  • This paper presents the analysis results for the core degradation processes and the fission product release of the PHEBUS FPT0 experiment using MELCOR1.8.3. The objective of this study is to assess models associated with the core damage and fission product behavior in MELCOR. The calculation results were much improved through sensitivity studies. Thermal/hydraulic behavior in the core and the circuit was well predicted under the intact core geometry. In non-eutectic model case. the UO$_2$ dissolution model in the MELCOR always showed such a tendency that the resulting dissolved UO$_2$ mass was small at the highly oxidized condition due to the model logic. Total H$_2$ generation mass was underpredicted because the stiffner was not modeled and the liner in the shroud was not allowed to be oxidized in MELCOR. Some difficulties were found in modeling the activation product were solved by manipulating the RN input associated with the initial fission product inventory. These problem were occurred because there are no control rod model in MELCOR. Generally the fission product release ratio showed a similar trend compared with the measured data except the activation product. which have no model to simulate in MELCOR.

  • PDF

A STUDY ON INDUSTRIAL GAMMA RAY CT WITH A SINGLE SOURCE-DETECTOR PAIR

  • Kim Jong-Bum;Jung Sung-Hee;Kim Jin-Sup
    • Nuclear Engineering and Technology
    • /
    • 제38권4호
    • /
    • pp.383-390
    • /
    • 2006
  • Having its roots in medical applications, industrial gamma ray CT has opened up new roads far investigating and modeling industrial processes. Using a line of research related to industrial gamma ray CT, the authors set up a system of single source and detector gamma transmission tomography for wood timber and a packed bed phantom. The hardware of the CT system consists of two servo motors, a data logger, a computer, a radiation source and a radiation detector. One motor simultaneously moves the source and the detector for a parallel beam scanning, whereas the other motor rotates the scan table at a preset projection angle. The image is reconstructed from the measured projections by the filtered back projection method. The phantom was designed to simulate a cross section of a packed bed with a void. The radiation source was 20mCi of Cs-137 and the detector was a 1 inch $\times$ 1 inch NaI (TI) scintillator shielded by a lead collimator. The experimental gamma ray CT image has sufficient resolution to reveal air holes and the density distribution inside the phantom. The system could possibly be applied to a packed bed column or a pipe flow in a petrochemical plant.

EFFECTS OF MECHANICAL PROPERTY VARIABILITY IN LEAD RUBBER BEARINGS ON THE RESPONSE OF SEISMIC ISOLATION SYSTEM FOR DIFFERENT GROUND MOTIONS

  • Choun, Young-sun;Park, Junhee;Choi, In-Kil
    • Nuclear Engineering and Technology
    • /
    • 제46권5호
    • /
    • pp.605-618
    • /
    • 2014
  • The effects of variability of the mechanical properties of lead rubber bearings on the response of a seismic isolation system are investigated. Material variability in manufacturing, aging, and operation temperature is assumed, and two variation models of an isolation system are considered. To evaluate the effect of ground motion characteristics on the response, 27 earthquake record sets with different peak A/V ratios were selected, and three components of ground motions were used for a seismic response analysis. The response in an isolation system and a superstructure increases significantly for ground motions with low A/V ratios. The variation in the mechanical properties of isolators results in a significant influence on the shear strains of the isolators and the acceleration response of the superstructure. The variation provisions in the ASCE-4 are reasonable, but more strict variation limits should be given to isolation systems subjected to ground motions having low A/V ratios. For application of seismic isolation systems to safety-related nuclear structures, the variation in the material and mechanical properties of the isolation system should be properly controlled during the manufacturing and aging processes. In addition, special consideration should be given to minimize the accidental torsion caused by the dissimilarity in the stiffness variations of the isolators.