• 방사성폐기물학회지
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• 제18권3호
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• pp.407-414
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• 2020

Thermal decomposition of the uranyl phosphate mineral phase meta-ankoleite (KUO₂PO₄·3H₂O) has been considered in relation to high temperature thermal sintering for the immobilisation of a uranyl phosphate containing waste. Meta-ankoleite thermal decomposition was studied across the temperature range 25 - 1200℃ under an inert N₂ atmosphere at 1 atm. It is shown that the meta-ankoleite mineral phase undergoes a double de-hydration event at 56.90 and 125.85℃. Subsequently, synthetically produced pure meta-ankoleite remains stable until at least 1150℃ exhibiting no apparent phase changes. In contrast, when present in a mixed waste the meta-ankoleite phase is not identifiable after thermal treatment indicating incorporation within the bulk waste either as an amorphous phase and/or as uranium oxide. Visual inspection of the waste post thermal treatment showed evidence of self-sintering owing to the presence of glass former materials, namely, silica (SiO₂) and antimony(V) oxide (Sb₂O₅). Therefore, incorporation of the uranium phase into the waste as part of waste sentencing and immobilisation via high temperature sintering for the purpose of long-term disposal is deemed feasible.

• Nuclear Engineering and Technology
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• 제56권2호
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• pp.536-545
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• 2024

Radioactive iodine is a representative fission product to be quantified for the safety assessment of nuclear facilities. In integral severe accident analysis codes, the iodine behavior is usually described by a multi-physical model of iodine chemistry in aqueous phase under radiation field and mass transfer through gas-liquid interface. The focus of studies on iodine source term evaluations using the combination approach is usually put on the chemical aspect, but each contribution to the iodine amount released to the environment has not been decomposed so far. In this study, we attempted the decomposition by revising the two-film theory of molecular-iodine mass transfer. The model involves an effective overall mass transfer coefficient to consider the iodine chemistry. The decomposition was performed by regarding the coefficient as a product of two functions of pH and the overall mass transfer coefficient for molecular iodine. The procedure was applied to the EPICUR experiment and suppression chamber in BWR.

• 분석과학
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• 제10권3호
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• pp.179-186
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• 1997

본 연구는 식물체 중 게르마늄을 분석할 때 기존의 방법보다 분석효율이 높고 간편하여 분해시간이 짧게 걸리는 방법을 찾고자 실험을 수행하였다. 시료 분해시 분해액은 $HNO_3+HClO_4+H_2SO_4$의 혼합산을 10 : 4 : 1(v/v)의 비율로 혼합 사용하였을 때 분해 소요 일수는 4~5일이었고, 회수율은 98% 이상이었다. 분해 후 최종 일정 부피로 맞추어 주기 위한 용액은 0.1M acetic acid-sodium acetate가 좋았으며, 아르곤 연료를 사용한 탄소봉원자화기부착 원자흡광분광광도계의 검출 한계는 0.02ppm이었다. 이와 같은 결과들은 식물체 중 게르마늄 분석에 있어서 전술한 실험 목적에 부합되는 결과였다.

• 대한수학회보
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• 제52권1호
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• pp.85-103
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• 2015

We prove some sharp extremal distance results for functions in various spaces of analytic functions on bounded strictly pseudoconvex domains with smooth boundary. Also, we obtain atomic decompositions in multifunctional Bloch and weighted Bergman spaces of analytic functions on strictly pseudoconvex domains with smooth boundary, which extend known results in the classical case of a single function.

• 방사선산업학회지
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• 제5권3호
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• pp.253-258
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• 2011

Acetylsalicylic acid (ASA) has been issued recently in contaminated water environments because of potential impacts on ecosystem and public health. This study was aimed at investigating the possibility of ASA degradation using gamma ray irradiation. In addition, the use of sodium persulfate, hydrogen peroxide, ferrous sulfate were tested in order to examine a synergistic effect with gamma ray. The absorbed dose was ranged from 0.2 to 10 kGy and the concentration of oxidants were from 0.1 to 10 mM in this study. The concentration of ASA was gradually decreased corresponding to the increase of the absorbed dose. When soudium persulfate was simultaneously applied, most of the parent compound was completely degraded even at a low dose of 0.8 kGy. The removal efficiency of total organic carbon was 90% even at the highest dose of 10 kGy without sodium persulfate. However, the efficiency was dramatically enhanced up to 98% at the same dose by adding 10 mM of oxidants. It was suggested that hydroxyl radical ($OH{\cdot}$) and sulfate radical ($SO{_4}^-{\cdot}$) were formed in the system and made roles in degrading ASA at the same time.

• 한국세라믹학회지
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• 제39권2호
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• pp.204-209
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• 2002

본 연구에서는 AUC 공정에서 발생되는 액체폐기물에 미량 함유되어 있는 우라늄을 회수/재사용하기 위해 액상에서 침전법을 이용하여 용해도가 작은 우라늄화합물을 얻었으며, 이 화합물에 대한 chemical analysis, thermal analysis, x-ray diffraction analysis 및 FT-IR 분석을 통해 물성 특성을 해석하였다. 연구결과, 화학분석 및 FT-IR 분석으로부터 우라늄화합물은 $UO_4{\cdot}2NH_4F$ 형태를 가지고 있음을 알 수 있었으며, 평균 2∼3${\mu}m$ 입자 크기를 갖는 hexagonal 형태를 나타내었다. 열 분해시 분해 온도에 따라 중간물질로 $UO_4F,\;UO_4,\;UO_3,\;U_3O_8$ 등으로 변환되었으며, 상온에서 800$^{\circ}C$까지의 공기분위기에서 일정한 가열속도로 열분해시킬 경우, $UO_4{\cdot}2NH_4F{\rightarrow}UO_4F{\rightarrow}UO_4{\rightarrow}UO_3{\rightarrow}U_3O_8$의 반응 메커니즘을 나타내었다.

• 한국안전학회지
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• 제18권4호
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• pp.64-70
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• 2003

The thermal properties of chloroprene rubber (CR) with $^{60}Co\;{\gamma}$-ray irradiation has been investigated. The prepared CR was irradiated up to 1000kGy radiation dose by $^{60}Co\;{\gamma}$-ray and the radiation degradation of CR was investigated by thermogravimetric analysis and differential acanning calorimetry. Dynamic mechanical properties measurement and FT-IR observation are carried out as well. From these analyses results, the glass transition temperature($T_g$), decomposition onset temperature(DOT), oxidative induction time(OIT), the peak temperature of loss modulus and mechanical tan ${\delta}$ values were compared for the radiation degradation level of CR. The tendency between $T_g$ and peak temperature of loss modulus and mechanical tan ${\delta}$ agreed well with radiation doses. Decomposition temperature, OIT and DOT showed the same tendencies as increasing radiation doses. It was verified that these analyses are available to estimate the degradation level of CR.

• 방사성폐기물학회지
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• 제5권3호
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• pp.221-227
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• 2007

음이온교환수지인 IRN-78및 IRN-77과의 혼합 수지를 액체 상태로 직접 분해 처리하기 위하여 Fenton 시약을 이용하였다. 개선된 분해방법의 특징은 수지를 먼저 건조시키고 $FeSO_4$ 용액을 수지에 완전히 흡수시킨 후 일정량의 $H_2O_2$를 첨가하여 분해반응을 유도하는 방법을 적용하였다. 촉매로서 $CuSO_4,\;Cu(NO_3)_2$ 및 IRN-77 수지의 분해시 사용한 $FeSO_4$를 각각 사용하여 각 이온교환수지의 단독 및 혼합수지의 분해에 필요한 적절한 촉매와 그의 농도 및 $H_2O_2$의 소요량을 측정하였다. IRN-78 수지에 대해 $CuSO_4$ 촉매를 사용한 경우, 초기 분해반응을 유도하기 위해 $40^{\circ}C$까지 가열이 필요하였으며, 반응유도시간은 촉매의 적정온도에서 약 20분 이내 개시되는 것으로 나타났다. 동 수지에 $FeSO_4$를 사용한 경우에는 가열 없이 즉시 분해반응이 진행되었으며 분해율도 수% 높게 나타났다. 결론적으로 IRN-78 및 IRN-77과의 혼합수지의 분해를 위한 최적 촉매는 $FeSO_4$로 나타났으며 가열하지 않고 상온에서 반응유도시간 없이 각 수지를 단독으로 분해한 경우보다 적은 양의 $H_2O_2$로 완전히 액상으로 분해시킬 수 있는 좋은 결과를 얻었다. 또한 이들 각각의 수지 및 혼합수지에 대한 적절한 촉매 및 적정 농도와 완전분해에 필요한 $H_2O_2$의 양을 제시하였다.

• Bulletin of the Korean Chemical Society
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• 제31권6호
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• pp.1661-1664
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• 2010

The photocatalytic decomposition of toluene vapor by bare and $TiO_2$-coated carbon fibers was studied. Atomic layer deposition (ALD) was used to perform the $TiO_2$ coating. We show that, under our conditions, the photocatalytic activity of bare carbon fibers was comparable with that of $TiO_2$ films, which are known to be good photocatalysts. The origin of the high photocatalytic activity of bare carbon fibers is discussed.

• Kyungpook Mathematical Journal
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• 제32권3_spc호
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• pp.569-580
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• 1992