• 제목/요약/키워드: atmospheric temperature

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첨가제(添加劑) 알칼리 법(法)에 의한 일본 잎갈 나무의 펄프화(化) 특성(特性)에 관(關)한 연구(硏究) (Studies on the Pulping Characteristics of Larchwood (Larix leptolepis Gordon) by Alkaline Process with Additives)

  • 임기표;신동소
    • Journal of the Korean Wood Science and Technology
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    • 제7권2호
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    • pp.3-30
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    • 1979
  • 우리나라에서는 일본잎갈나무가 대량(大量) 조림(造林)되어 축적(蓄積)과 생장량(生長量)으로 보아 주요(主要)한 조림(造林) 수종(樹種)이나 각종(各種) 추출물(抽出物)과 활성(活性) phenol 성분(成分)이 많고 심재율(心材率)이 높아 펄프화(化)에서 수율저하(收率低下)와 표백곤란(漂白困難)이 초래(招來)되어 펄프원료(原料)로서의 이용(利用)이 기피(忌避)되고 있다. 따라서 일본잎갈나무의 화학(化學)펄프 원료화(原料化)의 제고(提高)로서 펄프수율(收率) 향상(向上)과 표백성(漂白性) 개선(改善)을 위하여 셀룰로오스보호제를 첨가(添加)한 소다펄프화(化) 특성(特性)을 구명(究明)하였다. 증해(蒸解)는 최고온도(最高溫度) 170$^{\circ}C$까지 90분간(分間) 가열(加熱)하고 90분간(分間) 유지(維持)하는 일정조건(一定條件)으로 황화도(黃化度) 25%, 활성(活性)알칼리 18%의 크라프트법(法)으로 일본잎갈나무의 수령별(樹齡別) 펄프화(化) 특성(特性)을 구명(究明)하고, 18%활성(活性) 알칼리의 소다증해(蒸解)에 첨가제로 2.5% $MgSO_4$, 2.5% $ZnSO_4$, 2.5% $Al_2(SO_4)_3$, 2.5% KI, 2.5% hydroquinone, 2.5% ethylene diamine 또는 0.1~1.0% anthraquinone를 가(加)하여 15년생(年生) 일본잎갈나무의 변재(邊材)와 심재별(心材別) 소다펄프화(化) 특성(特性)을 구명(究明)한 후(後), 0.5% anthraquinone과 18% 활성(活性)알칼리로 증해(蒸解)된 펄프를 3%, 6%, 9% NaOH를 투입(投入)한 30%의 고농도(高農度)펄프를 상압(常壓) 산소표백(酸素漂白)하고, 이산화염소(二酸化鹽素)의 DED로 계속표백(繼續漂白)한 결과(結果) 다음과 같은 결론(結論)을 얻었다. 1. 일본잎갈나무의 수령별(樹齡別) 크라프트펄프는 수령간(樹齡間)에 펄프의 정선수율(精選收率)은 차(差)가 없으나, 수령(樹齡)이 증가함에 따라 펄프의 총수율(總收率)은 감소(減少)하고 비인열도(比引裂度)는 증가하였으며, 목재(木材)의 심재율(心材率), 용적밀도(容積密度) 수(數), 섬유장(纖維長) 및 온수추출물(溫水抽出物)도 증가하는 경향(傾向)을 나타냈다. 2. 일본잎갈나무의 변재(邊材)와 심재별(心材別) 소다증해(蒸解)에 셀룰로오스 보호제로 첨가(添加)된 7종(種)의 첨가제들은 변재(邊材)와 심재(心材)펄프화(化)에 대한 영향(影響)이 대체로 소다법(法)보다 증가되었으나 크라프트법(法)에 미치지 못하고, 크라프트펄프법(法)에 가까운 첨가제는 펄프수율(收率)에서 KI $MgSO_4$, anthraquinone이며, 특(特)히 다른 첨가제의 25분(分) 1이 첨가(添加)된 anthraquinone은 펄프의 정선수율(精選收率)과 KappaNo. 및 비파열도(比破裂度)에서 다른 첨가제보다 효과적이었다. 3. anthraquinone첨가량(添加量)에 따른 변재(邊材)와 심재별(心材別) 소다펄프의 품질(品質)은 변재(邊材)와 심재(心材) 모두 첨가량(添加量)이 많을수록 탈(脫)리그닌도(度)와 펄프수율(收率)이 높으나 활성(活性)알칼리가 낮으면 정선수율(精選收率)도 낮았으며 활성(活性)알칼리 17%의 소다 증해액(蒸解液)에 0.5% anthraquinone을 첨가(添加)한 조건(條件)에서는 크라프트펄프보다 비교적(比較的) 양호(良好)한 펄프가 얻어졌다. 4. 일반화(一般化)된 CEDED표백중(漂白中) 염소화(鹽素化)와 알칼리 추출단계(抽出段階) 대신(代身)에 30%의 고농도(高濃度)펄프에 상압(常壓) 산소표백(酸素漂白)한 ODED표백(漂白)은 산소단계(酸素段階)에서 변재(邊材)와 심재(心材)펄프 모두 NaOH투입량(投入量)이 증가될수록 백색도(白色度)와 비인열도(比引裂度)가 향상(向上)되나 펄프수율(收率)과 Kapa No.는 감소(減少)되었으며, NaOH 투입량(投入量)이 높을수록 펄프품질(品質)은 CEDED 표백(漂白)과 유사(類似)하나 펄프수율(收率)이 떨어졌다. 5. 따라서 본(本) 실험(實驗)에서는 펄프수율(收率) 향상(向上)을 위해서는 원료(原料)에서 심재율(心材率)이 낮은 수령(樹齡)의 경우가 펄프재(材)로 적당(適當)하고, 0.5% anthraquinone을 첨가(添加)한 활성(活性)알카리 18%의 소다증해(蒸解)하는 것이 적당(適當)하며 폐수중(廢水中)의 염소화합물(鹽素化合物)을 감소(減少)시키기 위하여서는 펄프농도(濃度) 30%이상(以上)의 고농도(高濃度)에서 상압(常壓) 산소(酸素)로 표백후(漂白後) 이산화(二酸化) 염소(鹽素)로 DED 표백(漂白)하면 일본잎갈나무의 크라프트법(法)보다 비교적(比較的) 우수(優秀)한 펄프를 얻을 수 있다.

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논벼 장.단간품종의 증발산제계수와 건물량과의 관계에 대한 연구(I) (Studies on Relations between Various Coeffcients of Evapo-Transpiration and Quantities of Dry Matters for Tall-and Short Statured Varieties of Paddy Rice)

  • 류한열;김철기
    • 한국농공학회지
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    • 제16권2호
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    • pp.3361-3394
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    • 1974
  • The purpose of this thesis is to disclose some characteristics of water consumption in relation to the quantities of dry matters through the growing period for two statured varieties of paddy rice which are a tall statured variety and a short one, including the water consumption during seedling period, and to find out the various coefficients of evapotranspiration that are applicable for the water use of an expected yield of the two varieties. PAL-TAL, a tall statured variety, and TONG-lL, a short statured variety were chosen for this investigation. Experiments were performed in two consecutive periods, a seedling period and a paddy field period, In the investigation of seedling period, rectangular galvanized iron evapotranspirometers (91cm${\times}$85cm${\times}$65cm) were set up in a way of two levels (PAL-TAL and TONG-lL varieties) with two replications. A standard fertilization method was applied to all plots. In the experiment of paddy field period, evapotanspiration and evaporation were measured separately. For PAL-TAL variety, the evapotranspiration measurements of 43 plots of rectangular galvanized iron evapotranspirometer (91cm${\times}$85cm${\times}$65cm) and the evaporation measurements of 25 plots of rectangular galvanized iron evaporimeter (91cm${\times}$85cm${\times}$15cm) have been taken for seven years (1966 through 1972), and for TONG-IL variety, the evapotranspiration measurements of 19 plots and the evaporation measurements of 12 plots have been collected for two years (1971 through 1972) with five different fertilization levels. The results obtained from this investigation are summarized as follows: 1. Seedling period 1) The pan evaporation and evapotranspiration during seedling period were proved to have a highly significant correlation to solar radiation, sun shine hours and relative humidity. But they had no significant correlation to average temperature, wind velocity and atmospheric pressure, and were appeared to be negatively correlative to average temperature and wind velocity, and positively correlative to the atmospheric pressure, in a certain period. There was the highest significant correlation between the evapotranspiration and the pan evaporation, beyond all other meteorological factors considered. 2) The evapotranpiration and its coefficient for PAL-TAL variety were 194.5mm and 0.94∼1.21(1.05 in average) respectively, while those for TONG-lL variety were 182.8mm and 0.90∼1.10(0.99 in average) respectively. This indicates that the evapotranspiration for TONG-IL variety was 6.2% less than that for PAL-TAL variety during a seedling period. 3) The evapotranspiration ratio (the ratio of the evapotranspiration to the weight of dry matters) during the seedling period was 599 in average for PAL-TAL variety and 643 for TONG-IL variety. Therefore the ratio for TONG-IL was larger by 44 than that for PAL-TAL variety. 4) The K-values of Blaney and Criddle formula for PAL-TAL variety were 0.78∼1.06 (0.92 in average) and for TONG-lL variety 0.75∼0.97 (0.86 in average). 5) The evapotranspiration coefficient and the K-value of B1aney and Criddle formular for both PAL-TAL and TONG-lL varieties showed a tendency to be increasing, but the evapotranspiration ratio decreasing, with the increase in the weight of dry matters. 2. Paddy field period 1) Correlation between the pan evaporation and the meteorological factors and that between the evapotranspiration and the meteorological factors during paddy field period were almost same as that in case of the seedling period (Ref. to table IV-4 and table IV-5). 2) The plant height, in the same level of the weight of dry matters, for PAL-TAL variety was much larger than that for TONG-IL variety, and also the number of tillers per hill for PAL-TAL variety showed a trend to be larger than that for TONG-IL variety from about 40 days after transplanting. 3) Although there was a tendency that peak of leaf-area-index for TONG-IL variety was a little retarded than that for PAL-TAL variety, it appeared about 60∼80 days after transplanting. The peaks of the evapotranspiration coefficient and the weight of dry matters at each growth stage were overlapped at about the same time and especially in the later stage of growth, the leaf-area-index, the evapotranspiration coefficient and the weight of dry matters for TONG-IL variety showed a tendency to be larger then those for PAL-TAL variety. 4) The evaporation coefficient at each growth stage for TONG-IL and PAL-TALvarieties was decreased and increased with the increase and decrease in the leaf-area-index, and the evaporation coefficient of TONG-IL variety had a little larger value than that of PAL-TAL variety. 5) Meteorological factors (especially pan evaporation) had a considerable influence to the evapotranspiration, the evaporation and the transpiration. Under the same meteorological conditions, the evapotranspiration (ET) showed a increasing logarithmic function of the weight of dry matters (x), while the evaporation (EV) a decreasing logarithmic function of the weight of dry matters; 800kg/10a x 2000kg/10a, ET=al+bl logl0x (bl>0) EV=a2+b2 log10x (a2>0 b2<0) At the base of the weight of total dry matters, the evapotranspiration and the evaporation for TONG-IL variety were larger as much as 0.3∼2.5% and 7.5∼8.3% respectively than those of PAL-TAL variety, while the transpiration for PAL-TAL variety was larger as much as 1.9∼2.4% than that for TONG-IL variety on the contrary. At the base of the weight of rough rices the evapotranspiration and the transpiration for TONG-IL variety were less as much as 3.5% and 8.l∼16.9% respectively than those for PAL-TAL variety and the evaporation for TONG-IL was much larger by 11.6∼14.8% than that for PAL-TAL variety. 6) The evapotranspiration coefficient, the evaporation coefficient and the transpiration coefficient and the transpiration coefficient were affected by the weight of dry matters much more than by the meteorological conditions. The evapotranspiratioa coefficient (ETC) and the evaporation coefficient (EVC) can be related to the weight of dry matters (x) by the following equations: 800kg/10a x 2000kg/10a, ETC=a3+b3 logl0x (b3>0) EVC=a4+b4 log10x (a4>0, b4>0) At the base of the weights of dry matters, 800kg/10a∼2000kg/10a, the evapotranspiration coefficients for TONG-IL variety were 0.968∼1.474 and those for PAL-TAL variety, 0.939∼1.470, the evaporation coefficients for TONG-IL variety were 0.504∼0.331 and those for PAL-TAL variety, 0.469∼0.308, and the transpiration coefficients for TONG-IL variety were 0.464∼1.143 and those for PAL-TAL variety, 0.470∼1.162. 7) The evapotranspiration ratio, the evaporation ratio (the ratio of the evaporation to the weight of dry matters) and the transpiration ratio were highly affected by the meteorological conditions. And under the same meteorological condition, both the evapotranspiration ratio (ETR) and the evaporation ratio (EVR) showed to be a decreasing logarithmic function of the weight of dry matters (x) as follows: 800kg/10a x 2000kg/10a, ETR=a5+b5 logl0x (a5>0, b5<0) EVR=a6+b6 log10x (a6>0 b6<0) In comparison between TONG-IL and PAL-TAL varieties, at the base of the pan evaporation of 343mm and the weight of dry matters of 800∼2000kg/10a, the evapotranspiration ratios for TONG-IL variety were 413∼247, while those for PAL-TAL variety, 404∼250, the evaporation ratios for TONG-IL variety were 197∼38 while those for PAL-TAL variety, 182∼34, and the transpiration ratios for TONG-IL variety were 216∼209 while those for PAL-TAL variety, 222∼216 (Ref. to table IV-23, table IV-25 and table IV-26) 8) The accumulative values of evapotranspiration intensity and transpiration intensity for both PAL-TAL and TONG-IL varieties were almost constant in every climatic year without the affection of the weight of dry matters. Furthermore the evapotranspiration intensity appeared to have more stable at each growth stage. The peaks of the evapotranspiration intensity and transpiration intensity, for both TONG-IL and PAL-TAL varieties, appeared about 60∼70 days after transplanting, and the peak value of the former was 128.8${\pm}$0.7, for TONG-IL variety while that for PAL-TAL variety, 122.8${\pm}$0.3, and the peak value of the latter was 152.2${\pm}$1.0 for TONG-IL variety while that for PAL-TAL variety, 152.7${\pm}$1.9 (Ref.to table IV-27 and table IV-28) 9) The K-value in Blaney & Criddle formula was changed considerably by the meteorological condition (pan evaporation) and related to be a increasing logarithmic function of the weight of dry matters (x) for both PAL-TAL and TONG-L varieties as follows; 800kg/10a x 2000kg/10a, K=a7+b7 logl0x (b7>0) The K-value for TONG-IL variety was a little larger than that for PAL-TAL variety. 10) The peak values of the evapotranspiration coefficient and k-value at each growth stage for both TONG-IL and PAL-TAL varieties showed up about 60∼70 days after transplanting. The peak values of the former at the base of the weights of total dry matters, 800∼2000kg/10a, were 1.14∼1.82 for TONG-IL variety and 1.12∼1.80, for PAL-TAL variety, and at the base of the weights of rough rices, 400∼1000 kg/10a, were 1.11∼1.79 for TONG-IL variety and 1.17∼1.85 for PAL-TAL variety. The peak values of the latter, at the base of the weights of total dry matters, 800∼2000kg/10a, were 0.83∼1.39 for TONG-IL variety and 0.86∼1.36 for PAL-TAL variety and at the base of the weights of rough rices, 400∼1000kg/10a, 0.85∼1.38 for TONG-IL variety and 0.87∼1.40 for PAL-TAL variety (Ref. to table IV-18 and table IV-32) 11) The reasonable and practicable methods that are applicable for calculating the evapotranspiration of paddy rice in our country are to be followed the following priority a) Using the evapotranspiration coefficients based on an expected yield (Ref. to table IV-13 and table IV-18 or Fig. IV-13). b) Making use of the combination method of seasonal evapotranspiration coefficient and evapotranspiration intensity (Ref. to table IV-13 and table IV-27) c) Adopting the combination method of evapotranspiration ratio and evapotranspiration intensity, under the conditions of paddy field having a higher level of expected yield (Ref. to table IV-23 and table IV-27). d) Applying the k-values calculated by Blaney-Criddle formula. only within the limits of the drought year having the pan evaporation of about 450mm during paddy field period as the design year (Ref. to table IV-32 or Fig. IV-22).

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