• Title/Summary/Keyword: atmospheric condition

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Characteristics of Low Dielectric Constant SiOF Thin Films with Post Plasma Treatment Time (플라즈마 후처리 시간에 따른 저유전율 SiOF 박막의 특성)

  • Lee, Seok Hyeong;Park, Jong Wan
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.267-267
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    • 1998
  • The fluorine doped silicon oxide (SiOF) intermetal dielectric (IMD) films have been of interest due to their lower dielectric constant and compatibility with existing process tools. However instability issues related to bond and increasing dielectric constant to water absorption when the SiOF films was exposured to atmospheric ambient. Therefore, the purpose of this research is to study the effect of post oxygen plasma treatment on the resistance of moisture absorption and reliability of SiOF film. Improvement of moisture absorption resistance of SiOF film is due to the forming of thin SiO₂layer at the SiOF film surface. It is thought that the main effect of the improvement of moisture absorption resistance was densification of the top layer and reduction in the number of Si-F bonds that tend to associate with OH bonds. However, the dielectric constant was increased when plasma treatment time is above 5 min. In this study, therefore, it is thought that the proper plasma treatment time is 3 min when plasma treatment condition is 700 W of microwave power, 3 mTorr of process pressure and 300℃ of substrate temperature.

Technical Feasibility of Ethanol as a Fuel for Farm Diesel Engines (농용(農用) 디이젤 엔진 연료(燃料)로서의 에타놀 이용(利用)에 관(關)한 연구(硏究))

  • Ryu, Kwan Hee;Bae, Yeong Hwan;Yoo, Soo Nam
    • Journal of Biosystems Engineering
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    • v.6 no.2
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    • pp.1-8
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    • 1982
  • The objective of this study was to find out the technical feasibility of ethanol-diesel fuel blends as a diesel engine fuel. Fuel properties essential to the proper operation of a diesel engine were determined for blends containing several concentrations of ethanol in No. 2 diesel fuel. A single-cylinder diesel engine for a power tiller was used for the engine tests, in which load, speed and fuel consumption rate were measured. The fuels used in tests were No. 2 diesel fuel and a blend containing 10-percent ethanol and 90-percent No. 2 diesel fuel. The results of the study are summarized as follows. 1. It was not possible to blend ethanol and No. 2 diesel fuel as a homogeneous solution even though anhydrous ethanol was used. The problem of blending ethanol in No. 2 diesel fuel could be solved by adding butanol about 5% of the amount of ethanol in the blends. 2. Because ethanol had a much lower boiling point ($78.3^{\circ}C$ under atmospheric pressure) than a diesel fuel, it was necessary to store ethanol-diesel fuel blends airtight in order to prevent them from evaporation losses of ethanol. 3. The addition of ethanol to No. 2 diesel fuel lowered the fuel viscosity and the cetane rating, but a blend of 10% ethanol and 90% diesel fuel had a viscosity and a cetane rating well above the KS minimum values for No. 2 diesel fuel. 4. At the rated speed, the specific fuel consumption of No.2 diesel fuel was lower than that of the 10% ethanol blend for the almost entire range of load. However, under the overload condition the specific fuel consumption was lower for the 10% ethanol blend. 5. Under the variable-speed full-load tests, both fuels produced approximately the same torque and power. At the speeds of 1600rpm or below, the specific fuel consumption of No. 2 diesel fuel was lower than that of the 10% ethanol blend. At the speeds of 1600rpm or above, however, the specific fuel consumption was lower for the 10% ethanol blend. 6. At the ambient temperature above $15^{\circ}C$, the use of the 10% ethanol blend in the engine created a vapor lock in the fuel injection pump and stalled the engine. The vapor locking problem was overcome by chilling the surroundings of the fuel injection pump and the cylinder head with water.

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Weathering Characteristics of Rocks near Churyong Tunnel Site, Kyongbuk, using Geophysical and Geochemical Methods (경북 추령터널 부근 암석의 풍화특성에 관한 지구물리화학적 연구)

  • 서만철;김민규;최석원
    • The Journal of Engineering Geology
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    • v.4 no.3
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    • pp.269-281
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    • 1994
  • Microscopic study and X-ray diffraction analysis were carried out to find out rock type, tock forming minerals; and weathering characteristics of rocks at the constructing site of the churyong Tunnel, Kyongju-Gun, Kyongbuk. Seismic velocity and compressional strength were measured to evaluate mechanical properties of rock. The rock of the study area is Jurassic tuff consisting of clay minerals, crystals of quartz and feldspar, fragments of volcanic rocks and shale. Fresh tuff has compressional strength of about $443kg/\textrm{cm}^2$ and seismic velocity of about 3680m/sec in average. It is classified as soft rock. Rock fragment within tuff is andesite and it has compressional strength of about $2500kg/\textrm{cm}^2$ and seismic velocity of about 4340m/sec in average. It is classified as hard rock. A good linear relationship is found between compressional streangth and seismic velocity in both laboratory sample and in-situ rocks. Laboratory samples has seismic velocities faster about 1.5km/sec than those in-situ rocks. It is interpreted that joints, fractures, and water content in the in-situ rocks result in decreas of seismic velocity. As Tuff has more than 50% of clay minerals in matrix and shale fragments, it absorbs water easily in atmospheric condition. Therefore, though the rock in the study area is medium hard rock before weathering, it is weathered very easily in the case of exposure to natural environment, comparing with other rock.

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Study on the improvement of prediction model for the railway environmental noise using ISO 9613-2 (ISO 9613-2를 이용한 철도 환경소음 예측 모델 개선에 관한 연구)

  • Jang, Seungho;Koh, Hyo-In;Hong, Jiyoung
    • Journal of Environmental Impact Assessment
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    • v.26 no.1
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    • pp.11-26
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    • 2017
  • Approximate empirical equations obtained by measuring overall noise levels at different distances have been used to evaluate environmental influence of the railway noise though the accurate prediction of noise levels is important. In this paper, a noise prediction model considering the frequency characteristics of noise sources and propagation was suggested to improve the accuracy of noise prediction. The railway noise source was assorted into track, wheel, traction and aerodynamic components and they were characterized with the source strength and speed coefficient at each octave-band frequency. Correction terms for the acoustic roughness and the track/bridge condition were introduced. The sound attenuation from a source to a receiver was calculated taking account of the geometrical divergence, atmospheric absorption, ground effect, diffraction at obstacles and directivity of source by applying ISO 9613-2. For obtaining the source strength and speed coefficients, the results of rolling noise model, numerical analysis and measurements of pass-by noise were analyzed. We compared the predicted and measured noise levels in various vehicles and tracks, and verified the accuracy of the present model. It is found that the present model gives less error than the conventional one, so that it can be applied to make the accurate prediction of railway noise effect and establish its countermeasures efficiently.

Mineral Carbonation of High Carbon Dioxide Composition Gases Using Wollastonite-distilled Water Suspension (규회석-증류수 현탁액을 이용한 고농도 CO2 가스의 탄산염 광물화)

  • Song, Haejung;Han, Sang-Jun;Wee, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.5
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    • pp.342-351
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    • 2014
  • The present paper investigates the performance of direct wet mineral carbonation technology to fix carbon dioxide ($CO_2$) from relatively high $CO_2$ concentration feeding gas using wollastonite ($CaSiO_3$)-water (and 0.46 M acetic acid) suspension solution. To minimize the energy consumed on the process, the carbonation in this work is carried out at atmospheric pressure and slightly higher room temperature. As a result, carbon fixation is confirmed on the surface of $CaSiO_3$ after carbonation with wollastonite-water suspension solution and its amount is increased according to the $CO_2$ composition in the feeding gas. The leaching and carbonation ratio of wollastonite-water suspension system obtained from the carbonation with 50% of $CO_2$ composition feeding gas is 13.2% and 10.4%, respectively. On the other hand, the performance of wollastonite-acetic acid in the same condition is 63% for leaching and 1.39% for carbonation.

A Study on Engine Health Monitoring using Linear Gas Path Analysis for Turboprop Engine (선형 GPA 기법을 이용한 터보프롭 엔진의 성능진단에 관한 연구)

  • 공창덕;신현기;기자영
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.4
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    • pp.93-103
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    • 1999
  • The steady-state performance analysis program for turboprop engine which was used for a small, middle industrial aircraft and a basic trainer aircraft was developed and linear Gas Path Analysis method was applied to Engine Health Monitoring for Turboprop engine. This program was compared with TURBOMARCH program which is well known with performance and power according to flight Mach No. at the standard atmospheric condition to prove a steady-state performance analysis program. From the result, inlet, exit temperature and pressure of each component had error within 3% and especially power according to flight Mach No. had error within 2.4% so that this program could be assured. To make sure if linear Gas Path Analysis is reasonable four cases were selected. The first is the case that fouling is occurred in compressor only. The second is the case that fouling is occurred in compressor and erosion is occurred in turbine. The third is the case that erosion is occurred in both compressor and turbine and power turbine at the same time. Finally, the case that fouling and erosion are occurred in compressor, compressor turbine and power turbine was selected. Different parameters were selected impartially among the independent parameters so that the effect of measurement parameter selection was observed. From the result, the more measurement parameters the smaller RMS error and even though the number of measurement parameters was the same, the RMS error was obtained differently according to which measurement parameters were selected. The case using eight instrument parameters of case IV-4 had small error comparably and was economic and it was important to select optimal number of measurement and optimal measurement parameters.

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Construction of Surface Boundary Conditions for the Regional Climate Model in Asia Used for the Prevention of Disasters Caused by Climate Changes (기상방재 대책수립을 위한 아시아지역 기상모형에 필요한 지표경계조건의 구축)

  • Choi, Hyun-Il
    • Journal of the Korean Society of Hazard Mitigation
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    • v.7 no.5
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    • pp.73-78
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    • 2007
  • It has been increasing that significant loss of life and property due to global wanning and extreme weather, and the climate and temperature changes in Korea Peninsula are now greater than the global averages. Climate information from regional climate models(RCM) at a finer resolution than that of global climate models(GCM) is required to predictclimate and weather variability, changes, and impacts. The new surface boundary conditions(SBCs) development is motivated by the limitations and inconsistencies of existing SBCs that have influence on model predictability. A critical prerequisite in constructing SBCs is that the raw data should be accurate with physical consistency across all relevant parameters and must be appropriately filled for missing data if any. The aim of this study is to construct appropriate SBCs for the RCM in Asia domain which will be used for the prevention of disasters due to climate changes. As all SBCs have constructed onto the 30km grid-mesh of the RCM suitable for Asia applications, they can be also used for other distributed models for climate and hydrologic studies.

Chemical Characteristics of Water Soluble Components in Fine Particulate Matter at a Gwangju area (광주지역 PM2.5 입자 수용성 성분의 화학적 특성조사)

  • Park, Seung Shik;Cho, Sung Yong;Kim, Seung Jai
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.20-26
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    • 2010
  • Water soluble organic and inorganic species are important components in atmospheric aerosol particles and may act as cloud condensation nuclei to indirectly affect the climate. To characterize organic and elemental carbon(OC and EC), water-soluble organic carbon(WSOC) and inorganic ionic species contents, daily $PM_{2.5}$ measurements were made during the wintertime at an urban site of Gwangju. Average concentrations of WSOC, $NO_3^-$, $SO_4^{2-}$ and $NH_4^+$, which are major components in the water-soluble fraction in PM2.5, are 2.11, 5.73, 3.51 and $3.31{\mu}g/m^3$, respectively, representing 12.0(2.9~23.9%), 21.0(12.9~37.6%), 11.6(2.5~25.9%) and 11.7%(3.8~18.6%) of the $PM_{2.5}$, respectively. Abundance of water soluble organic compounds ranged from 5.4 to 35.9% of total water soluble organic and inorganic components with a mean of 17.6%. Even though the sampling was performed during the winter, the average contributions of secondary OC and WSOC, as deduced from primary OC/EC(or WSOC/EC) ratio, were relatively high, accounting for 17.9%(0~44.4%) of the total OC and 11.2%(0.0~51.4%) of the total WSOC, respectively. During the sampling period, low $SO_4^{2-}/(SO_4^{2-}+SO_2$) ratio of 0.14(0.03~0.32) and relative humidity condition in the winter time suggest an possibility of impact of long-range transport and/or aqueous transformation processes such as metal catalyzed oxidation of sulfur, in-cloud processes, etc.

EFFECT OF CURING CONDITIONS ON THE MONOMER ELUTION OF ORTHODONTIC ACRYLIC RESIN (교정용 아크릴릭 레진의 중합조건에 따른 모노머 용리)

  • Noh, Hong-Seok;Kim, Jae-Moon;Kim, Shin;Jeong, Tae-Sung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.35 no.3
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    • pp.477-486
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    • 2008
  • Acrylic resin is widely used in dental practice. However, the residual monomer in acrylic resin could act as a negative biocompatability on human body. The aim of this study was to evaluate the amount of the monomer elution from polymerized orthodontic acrylic resin. Orthodontic acrylic resin was used in the study. The curing condition of the resin was controlled by temperature, pressure, aquatic and atmospheric environment. The duration and amount of monomer elution and timedependent plot was recorded by high performance liquid chromatography. The result showed that the only monomer eluted from the resin was methyl methacrylic acid. And the amount of the monomer elution has diminished considerably by time progress especially within 24 hours. Furthermore, elution of the residual monomer was significantly lower in group of pressure, moisture and elevated temperature than control (p<.05). According to this study, it was thought that the elution of residual monomer might be influenced by curing environment.

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Synthesis of Styrenated Phenol Alkoxylate from Styrenated Phenol with Ethylene Carbonate over KOH/La2O3 Catalyst (KOH/La2O3 촉매상에서 Styrenated Phenol과 Ethylene Carbonate의 반응으로부터 Styrenated Phenol Alkoxylate의 합성)

  • Lee, Seungmin;Son, Seokhwan;Jung, Sunghun;Kwak, Wonbong;Shin, Eun Ju;Ahn, Hogeun;Chung, Minchul
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.62-66
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    • 2018
  • Styrenated phenol alkoxylates (SP-A) were prepared from styrenated phenol (SP) and ethylene oxide (EO) under a homogeneous base catalyst. However, to use EO that is difficult to handle, a high-pressure reaction device capable of controlling the reaction process should be used. Additionally, when a homogeneous base catalyst is used, a neutralization process is required to remove residual bases after the reaction, and it is also difficult to separate the catalyst and the product. Therefore, in this study, we report the results of SP-A prepared from the reaction of SP and EC using only heterogeneous base catalysts. The heterogeneous base catalyst was obtained by supporting KOH on $La_2O_3$ and calcintion. Using EC instead of EO, it was possible to produce SP-A under the atmospheric rather than high-pressure reaction condition. Average molecular weights of synthesized SP-A varied greatly depending on reaction conditions. The average molecular weight of SP-A prepared using the $KOH/La_2O_3$ catalyst could be controlled arbitrarily by controlling the reaction temperature and added catalyst and EC amounts.