• Journal of Environmental Impact Assessment
• /
• v.5 no.1
• /
• pp.69-77
• /
• 1996

The variations of ozone concentration and the sensitivity test for VOC emission intensities was investigated by means of a PBM(Photochemical Box Model). Compared to monitoring data, the typical variations of $NO_2$, CO, $O_3$ for days were successfully reproduced. Model results revealed that maximum ozone concentration got increased with the increase of VOC emission, that is, VOC played the important role in producing the photochemical smog.

• Journal of the Korean Institute of Landscape Architecture
• /
• v.27 no.5
• /
• pp.38-47
• /
• 2000

Carbon dioxide is a major greenhouse gas causing climate change. This study quantified annual direct and indirect uptake of carbon by urban greenspace, and annual carbon release from vegetation maintenance and fossil fuel consumption. The study area was whole Chuncheon and Kangleung, and also two districts of Kangnam and Junglang in Seoul, cities located in middle Korea. Carbon uptake by urban greenspace played an important role through offsetting carbon release by 6-7% annually in Chuncheon and Kangleung. For Kangnam and Junglang, where the population density was relatively higher, urban greenspace annually offset carbon release by 1-2%. Future possible tree plantings could double annual carbon uptake by existing trees in urban lands (except natural and agricultural lands) of a study city. Based on study results, planning and management guidelines for urban greenspace were suggested to save energy and to reduce atmospheric $CO_2$ concentrations. They included selection of optimum tree species, proper planting location from buildings, design of multilayered planting, amendment of existing regulations for greenspace enlargement, avoidance f intensive vegetation maintenance, and conservation of natural vegetation.

• Korean Journal of Remote Sensing
• /
• v.39 no.2
• /
• pp.129-142
• /
• 2023

This study analyzed the ratio of carbon monoxide (CO) and carbon dioxide (CO₂), CO and nitrogen dioxide (NO₂) for cities and regionsin Korea and China using column-averaged carbon dioxide dry-air mole fraction (XCO₂) of the Orbiting Carbon Observatory-2/3, CO and NO₂ vertical column density (named XCO, XNO₂ in thisstudy) of TROPOspheric monitoring instrument from April 2018 to April 2022, and presented the relationship between socioeconomic indicators (population, number of vehicles, Gross Regional Domestic Product) and ratio, and differences in characteristics between Korea and China. First, CO₂ and CO were analyzed after calculating ΔXCO₂ and ΔXCO removing the background value and trend line due to the difference in atmospheric residence time of three gaseous substances (CO₂, CO, and NO₂). Comparing the three values by regions, ΔXCO and ΔXCO₂ were relatively higher in China and XNO₂ were higher in Korea and the ratio of both values (ΔXCO/ΔXCO₂, ΔXCO/XNO₂) was higher in China than in Korea. ΔXCO/ΔXCO₂, ΔXCO/XNO₂ and socioeconomic indicators have a positive correlation suggesting that the concentration of air pollutants and greenhouse gases is higher as the city is large and the economic activity is active. Regarding the differences in the ratio characteristics of Korea and China, the relationship between ΔXCO and ΔXCO₂ showed a negative correlation in Korea and a positive correlation in China. When the relationship between ΔXCO and XNO₂ was examined for summer and winter, the change of ΔXCO by season was not significant in Korea, whereasthe change of ΔXCO and XNO₂ by season waslarge in China resulting in the relationship between two countries appeared differently. These results suggest that seasonal variability and national emission characteristics should be considered in the process of analyzing the ratio of greenhouse gases to air pollutants.

• Economic and Environmental Geology
• /
• v.51 no.1
• /
• pp.1-13
• /
• 2018

The radon concentration in soil varies with environmental factors such as atmospheric temperature and pressure, rainfall and soil temperature. The effects of these factors, therefore, should be differentiate in order to analyzed the anomalous radon variation caused by earthquake events. For these reasons, a comparative analysis between the radon variations with environmental factors and the anomalous variations caused by Gyeong-ju earthquake occurred in September 12, 2016 has been conducted. Radon concentration in soil and environmental factors were continuously measured at a monitoring ste located in 58Km away from earthquake epicenter from January 01, 2014 to May 31, 2017. The co-relationships between radon concentration and environmental factors were analyzed. The seasonal average radon concentration(n) and the standard variation(${\rho}$) was calculated, and the regions of ${\pm}1{\rho}$ and ${\pm}2{\rho}$ deviations from seasonal average concentration were investigated to find the anomalous radon variation related to Gyeong-ju earthquake. Earthquake effectiveness and q-factor were also calculated. The radon concentration indicated the seasonal variation pattern, showing high in summer and low in winter. It increases with increasing air temperature and soil temperature, and has the positive co-relationships of $R^2=0.9136$ and $R^2=0.8496$, respectively. The radon concentration decreases with increasing atmospheric pressure, and has the negative co-relationships of $R^2=0.7825$. Four regions of ${\pm}2{\rho}$ deviation from average seasonal concentration (A1: 7/3~7/5, A2: 7/18, A3: 8/4~8/5, A4: 10/17~10/20) were detected before and after Gyeong-ju earthquake. A1, A2, A3 were determined as the anomalous radon variation caused by the earthquake from co-relationship analyses with environmental factors, earthquake effectiveness and q-factor. During the period of anomalous radon variation, correlation coefficients between radon concentration and environmental factors were significantly lowered compared to other periods such as air temperature ($R^2=0.2314$), soil temperature ($R^2=0.1138$) and atmospheric pressure ($R^2=0.0475$). Annual average radon concentration was also highest at 2016, the year of Gyeong-ju earthquake.

• Journal of Korean Society for Atmospheric Environment
• /
• v.19 no.3
• /
• pp.307-314
• /
• 2003

The sonolytic decomposition of chlorofluorocarbon (CFC 113) and several alternative compounds, such as HCFC 225ca, HCFC 225cb, and HFC 134a, in.aqueous solutions was investigated. The CFC 113 with a high volatility and a low solubility in water was rapidly decomposed with increasing sonication time. The decomposition rates were influenced by the initial concentration of CFC 113, the reaction temperature, and the gas/liquid phase volume ratio but were independant of the pH of solution. The predominant pathway of the decomposition of CFC 113 by sonication was not the oxidation by OH radicals but the pyrolysis with high temperature and pressure inside of the cavitation bubble. The pyrolysis in the cavitation bubble resulted in an almost complete mineralization of CFC 113 with the high efficient formation of inorganic products (Cl$^{[-10]}$ , F$^{[-10]}$ , CO, $CO_2$). The addition of zinc powder on the decomposition of CFC 113 by sonication caused an acceleration of the decomposition. Also, HCFCs and HFC 134a were found to be readily decomposed by the pyrolysis induced from the sonication.

• Journal of Korean Society for Atmospheric Environment
• /
• v.21 no.1
• /
• pp.15-26
• /
• 2005

An experimental investigation of the gas-phase photooxidation of toluene-NO$_{x}$-air mixtures at sub-ppm concentrations has been carried out in a 6.9 m3, indoor smog chamber irradiated by blacklights. Measured parameters in the toluene-NO$_{x}$ experiments included $O_3$, NO, NO$_2$, NO$_{x}$, CO, SO$_2$ toluene, and air temperature. The initial toluene concentration ranged from 225 ppb to 991 ppb and the initial concentration ratio of toluene/NO$_{x}$ in ppbC/ppb was in the range of 5～20. It was found that the variation of gaseous species with irradiation time caused by the photooxidation of toluene-NO$_{x}$-air mixtures depended on the initial toluene concentration for similar concentration ratio of toluene/NO$_{x}$. The dependency of initial toluene concentration on the photooxidation of toluene-NO$_{x}$-air mixtures for toluene/NO$_{x}$=5～6 seemed to be opposite to that for toluene/NO$_{x}$=10～11. The arriving time at maximum ozone concentration depended on both initial toluene concentration and initial concentration ratio of toluene/NO$_{x}$. However, the maximum concentration of ozone formed by photooxidation depended only on the initial toluene concentration.luene concentration.

• Journal of Korean Society on Water Environment
• /
• v.32 no.5
• /
• pp.433-441
• /
• 2016

Many large dams have been constructed for water supply, irrigation, flood control and hydropower in Korea for the last century. Meanwhile, recent studies indicated that the artificial reservoirs impounded by these dams are major sources of carbon dioxide (CO₂) to the atmosphere and relevant to global budget of green house gases. However, limited information is available on the seasonal variations of CO₂ evasion from the reservoirs located in the temperate monsoon regions including Korea. The objectives of this study were to estimate daily Net Atmospheric Flux (NAF) of CO₂ in Daecheong Reservoir located in Geum River basin of Korea, and analyze the influencing parameters that characterize the variation of NAF. Daily pH and alkalinity (Alk) data collected in wet year (2012) and dry year (2013) were used for estimating the NAFs in the reservoir. The dissolved inorganic carbon (DIC) was computed using the pH and Alk measurements supposing an equilibrium state among the carbonate species. The results showed seasonal variations of NAF; negative NAFs from May to October when the primary production of the reservoir increased with water temperature increase, while positive NAF for the rest of the period. Overall the reservoir acted as sources of CO₂ to the atmosphere. The estimated NAFs were 2,590 and 771 mg CO₂ m^-2d^-1 in 2012 and 2013, respectively, indicating that the NAFs vary a large extent for different hydrological years. Statistical analysis indicated that the NAFs are negatively correlated to pH, water temperature, and Chl-a concentration of the reservoir.

• Journal of Environmental Science International
• /
• v.23 no.11
• /
• pp.1889-1907
• /
• 2014

The characteristics of meteorological conditions related to changes in atmospheric environment on Jeju Island were investigated during recent years (2010-2012). This analysis was performed using the hourly observed data of meteorological variables (air temperature, wind speed and direction) and air pollutants ($O_3$, $PM_{10}$, $SO_2$, $NO_2$, and CO). Out of 5 pollutants, $O_3$ and $PM_{10}$ concentrations have frequently exceeded national environmental standards in the study area during the study period, with relatively higher concentrations than the others. The concentrations of $O_3$ and $PM_{10}$ in 2010 and 2011 were somewhat higher than those in 2012, and their highest concentrations were mostly observed in spring followed by fall. Nighttime $O_3$ concentrations (with relatively high concentration levels) were almost similar to its daytime concentrations, due to less $O_3$ titration by very low NO concentrations in the target area and in part to $O_3$ increase resulting from atmospheric transport processes. The transport effect related to the concentration variations of $O_3$ and $PM_{10}$ was also clarified in correlation between these pollutants and meteorological variables, e.g. the high exceedance frequency of concentration criteria with strong wind speed and the high concentrations with the westerly/northwesterly winds (e.g., transport from the polluted regions of China). The overall results of this study suggest that the changes in atmospheric environment in the study area were likely to be caused by the transport effect (horizontal and vertical) due to the meteorological conditions rather than the contribution of local emission sources.

• Journal of Environmental Science International
• /
• v.12 no.2
• /
• pp.207-215
• /
• 2003

The purpose of this study is to estimate the air quality of subway stations having underground platforms in Busan Metropolitan City, from September to November 2000, over seven times. The places of the investigation include Yonsan-dong station, Somyon station, Busan station, Nampo-dong station, and Dusil station. Samplings were conducted at three points in each station, i.e. gates, ticket gates, and platforms. CO, NO, $NO_2$, and $O_3$ were the main components of air for this analysis. In order to more fully understand station environments, we also measured an air temperature at each point. The results showed that the $O_3$ average concentration of Yonsan-dong station was higher than others with 38~51 ppb. The average concentration of NO was high at the ticket gate and platform at Somyon station (119 ppb, 122 ppb) and Nampo-dong station (102 ppb, 100 ppb). These results show that the air pollution of stations with underground shopping malls were higher than others. At Somyon station having a junction station, NO and $NO_2$ concentration levels of platform-2 (noncrowded) were higher than platform-1 (crowded). This is most likely due to the accumulation of air pollutants and inadequate ventilation systems. To find the relationship of the indoor (platform) and outdoor (gate), we analyzed the I/O ratio. The averages of CO and $O_3$ were both higher than one: 1.16 and 1.82, respectively. In the correlations between each material and the others, NO vs $NO_2$ was the highest with R=0.63. In the correlations between indoor and outdoor, $O_3$ was the highest with R=0.64.

• Journal of Korean Society for Atmospheric Environment
• /
• v.12 no.3
• /
• pp.307-314
• /
• 1996

The rate of evolution of ethylent by tomato plants was rapidly increased by ozone fumigation. In the present study, the mechanism of ethylent evolution by ozone was investigated in experiments with aminoethoxyvinylglycine (AVG) and tiron, which inhibit the formation of ethylene and peroxidation of lipids, respectively. Pretreatment with AVG significantly inhibited the ozone-induced ethylent evolution, but the treatment of plants with tiron did not inhibit. These results indicate that the induction of the evolution of ethylene by ozone involves the pathway via aminocyclopropane-1-carboxylate (ACC), while not released as a result of the peroxidation of lipids. Ozone-induced ethylent evolution was greater in dar- than light-incubated, intact tomato plants. The difference between dark- and light-ethylene evolution was examined with diuron, an inhibitor of photosynthetic electron transport. The inhibitor treatment promoted ethylent evolution. These results suggest that ethylent retention and metabolism in plants were regulated by internal $CO_2$ levels which, in turn, were controlled in large part by photosynthesis. Thus, ethylene was retained in illuminated leaf tissue under low intenal $CO_2$ concentration which may develop in a sealed container without exogenously supplied $CO_2$.