• 제목/요약/키워드: asymmetric step

검색결과 74건 처리시간 0.023초

Synthesis of Chiral Intermediates Catalyzed by New Chiral Polymeric (Salen) Cobalt Complexes Bearing Lewis Acidic Metal Halides

  • Lee, Kwang-Yeon;Kawthekar, Rahul B.;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • 제28권9호
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    • pp.1553-1561
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    • 2007
  • The new type of heterometallic chiral polymer salen complexes have been synthesized and it has been found that group 13 metal salts (AlCl3, GaCl3 and InCl3) combined to cobalt salen unit played the crucial role in the asymmetric kinetic resolution of racemic epoxides. Polymeric salen catalysts showed very high reactivity and enantioselectivity for the asymmetric ring opening of terminal epoxide with diverse nucleophiles. They provide the enantiopure useful chiral intermediates such as chiral terminal epoxides and α -aryloxy alcohols in one-step process. An efficient methodology for providing very high enantioselectivity can be achieved in the synthesis of valuable chiral building blocks via our catalytic system by combination of various asymmetric ring opening reactions.

기존시설물 내진성능평가를 위한 평가항목 분류체계와 평가방법 (Seismic Performance Level Criteria and Evaluation Methods)

  • 김남희
    • 한국지진공학회:학술대회논문집
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    • 한국지진공학회 2000년도 추계 학술발표회 논문집 Proceedings of EESK Conference-Fall 2000
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    • pp.251-260
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    • 2000
  • Seismic performance evaluation systems require rational classification of structure systems, proper evaluation criteria, and their scoring index for synthesis. Current seismic performance systems need expert judgments based on collection of available data, approximate analysis of important items, and various scoring system. This study presents a three-step seismic performance evaluation system for building structures in Korea. Each evaluation step determines the seismic performance and the method depends on the degree of refinement of analysis. The preliminary step evaluation involves the global attributes of structures such as vertical irregularity, asymmetric plan, redundancy, and age of structures. The second step requires an elastic analysis for estimation of forces acting on critical sections and checks the strength and ductility. The final step requires inelastic capacity of structures. Each stephas own evaluation scheme with proper weighing factor dependent on the importance and consequence. This study applies the fuzzy theory to a scoring method that synthesizes the individual quantity to a representative value.

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비대칭 Sloping 노치를 적용한 단상 BLDC 전동기의 코깅토크 저감 방법 (Cogging Torque Reduction Method of a Single-Phase BLDC Motor using Asymmetric Sloping Notch)

  • 박용운;소지영;우경일;김대경
    • 전기학회논문지
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    • 제66권11호
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    • pp.1568-1574
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    • 2017
  • This paper studied cogging torque reduction effect for sloping notch applied two notches on stator teeth. We have confirmed accuracy of FEM(Finite Element Method) through comparison previous model using asymmetric notch for experiment and 3D FEM results, and then cogging torque comparison of previous model and sloping notch model. Also the sloping notch model has been modified to step-sloping notch model to consider manufactur. The modification method of sloping notch changed the degree of slope of notch (a)(Notch(a) sloping Deg) and the degree of Slope of notch (b)(Notch(b) Sloping Deg). When Cogging torque is case of minimum, Notch (a) Sloping Deg is $-12[^{\circ}]$ and Notch(b) Sloping Deg $12[^{\circ}]$. In this case, cogging torque was about 23.9[mNm]. Cogging torque of previous model is about 40.8[mNm], so sloping notch model is less than previous model by 41.42[%]. Also, if sloping notch model is changed to step-sloping notch model, cogging torque of step-sloping notch model is about 24.82[mNm], Therefore the difference between the two cogging torque is about 3.85[%], so step-sloping notch model can be applied when considering manufacture.

The Effect of Pelvic Inclination on Gait Elements and Weight Bearing of Healthy Adults

  • Cho, Sung-Hyoun;Kim, Cheol-Yong
    • 국제물리치료학회지
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    • 제2권2호
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    • pp.294-300
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    • 2011
  • The purpose of this study was to investigate the influence of the static pelvic inclination and declination in the static standing position on weight bearing rate and gait elements. Fourteen healthy adults in their twenties were participated. Two groups of healthy adults were allocated in this study: above and below the average of pelvic tilt. The correlation between the pelvic inclination, weight bearing rate and gait elements were measured. There was a statistical correlation between the pelvic tilt and step. Also, there was a statistical difference when we compared anterior declination with swing period and posterior declination with step. There was an asymmetric correlation between pelvic tilt and step. However, there was no statistical difference between the groups above and below the average of pelvic tilt. This result indicates that dipper pelvic inclination doesn't affect the asymmetry of step.

계단 모양 전극을 가진 미세펌프 해석 (SIMULATION OF A MICROPUMP WITH STEP ELECTRODES)

  • 김병재;이승현;성형진
    • 한국전산유체공학회지
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    • 제15권4호
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    • pp.40-45
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    • 2010
  • The flow rate is higher in ACEO micro-pumps with step electrodes than in micro-pumps with planar asymmetric electrodes. In the present study, numerical simulations were made of a ACEO micro-pump with step electrodes to investigate the effects of electrode design parameters on the pumping flow rate. The electrical charge at the electrodes, the fluid flow, and potential were solved, taking into account the finite size of ions, that is, the steric effect. This effect is recognized to be capable of quantifying the electrical charge more accurately in the electrical double layer subject to high voltages. Geometrical parameters such as heights, widths, and gaps of three-dimensional electrodes were optimized to enhance the pumping flow rate. Moreover, the effect of amplitude and frequency of AC was studied.

광섬유 커플러 Add/Drop 필터의 연산자 분리 시영역 해석 및 설계 (Split-Step Time-Domain Analysis and Design of an Fiber-Optic Coupler Add/Drop Filter)

  • 강준환;김병성;정영철
    • 대한전자공학회논문지SD
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    • 제37권8호
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    • pp.57-66
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    • 2000
  • 비대칭 광섬유 커플러 ADF(add/drop filter)의 필터링 특성을 새로운 연산자 분리 시영역 모델을 이용해서 해석하였다. 연산자 분리 시영역 모델은 방향성 결합기와 브래그 격자를 포함하는 구조의 소자를 전산모사 할 때 미우 유용하다. 먼저 이 모델을 이용하여 대칭구조의 고아섬유 커플러 ADF의 특성을 해석하여 연산자 분리 알고리듬의 정확도를 확인 한 후에, 비대칭 구조 ADF의 특성을 해석하여 필터링 성능의 최적화에 필요한 파라미터 값들을 도출하였다.

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비대칭키 RSA의 𝜙(n) 해독을 위한 역 아기걸음- 2k-ary 성인걸음법 (Reverse Baby-step 2k-ary Adult-step Method for 𝜙((n) Decryption of Asymmetric-key RSA)

  • 이상운
    • 한국인터넷방송통신학회논문지
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    • 제14권6호
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    • pp.25-31
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    • 2014
  • 비대칭키 RSA의 공개키 e와 합성수 n=pq은 알고 있고 개인키 d를 모를 때, ${\phi}(n)=(p-1)(q-1)=n+1-(p+q)$을 구하여 $d=e^{-1}(mod{\phi}(n))$으로 개인키 d를 해독한다. 암호해독은 일반적으로 n/p=q 또는 $a^2{\equiv}b^2$(mod n), a=(p+q)/2,b=(q-p)/2를 구하는 소인수 분해법이 널리 적용되고 있다. 그러나 아직까지도 많은 RSA 수들이 해독되지 않고 있다. 본 논문은 ${\phi}(n)$을 직접 구하는 알고리즘을 제안하였다. 제안된 알고리즘은 이산대수의 아기걸음-거인걸음법과 모듈러 지수연산의 $2^k$-ary법을 적용하였다. 이 알고리즘은 역-아기걸음과 $2^k$-ary 성인걸음법을 적용하여 기본적인 성인걸음법 수행횟수를 $1/2^k$로 줄이고, $m={\lfloor}\sqrt{n}{\rfloor}$의 저장 메모리 용량도 l, $a^l$ > n로 감소시켜 ${\phi}(n)$을 l회 이내로 구하였다.

Step-up Switched Capacitor Multilevel Inverter with a Cascaded Structure in Asymmetric DC Source Configuration

  • Roy, Tapas;Bhattacharjee, Bidrohi;Sadhu, Pradip Kumar;Dasgupta, Abhijit;Mohapatra, Srikanta
    • Journal of Power Electronics
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    • 제18권4호
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    • pp.1051-1066
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    • 2018
  • This study presents a novel step-up switched capacitor multilevel inverter (SCMLI) structure. The proposed structure comprises 2 unequal DC voltage sources, 4 capacitors, and 14 unidirectional power switches. It can synthesize 21 output voltage levels. The important features of the proposed topology are its self-voltage boosting and inherent capacitor voltage balancing capabilities. Furthermore, a cascaded structure of the proposed SCMLI with an asymmetric DC voltage source configuration is presented. The proposed topology and its cascaded structure are compared with conventional and other recently developed topologies in terms of different aspects, such as the required components to produce a specific number of output voltage levels, the total standing voltage (TSV) and peak inverse voltage of the structure, and the maximum number of switches in the conducting path. Furthermore, a cost function is developed to verify the cost-effectiveness of the proposed topology with respect to other topologies. The TSV of the proposed topology is significantly lower than those of other topologies. Moreover, the developed topology is cost-effective compared with other topologies. A detailed operating principle, power loss analysis, and selection procedure for switched capacitors are presented for the proposed SCMLI structure. Extensive simulation and experimental studies of a 21-level inverter structure prove the effectiveness and merits of the proposed SCMLI.

Surface Crystalline Modification for Asymmetric Giant Mngnetoimpedance Profile in Annealed Co-based Amorphous Ribbons

  • Rheem, Y.W;Kim, C.G;Kim, C.O;Choi, Y
    • Journal of Magnetics
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    • 제6권3호
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    • pp.86-89
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    • 2001
  • Microstructure modifications are investigated for annealed Co-based amorphous ribbon in vacuum and open air. X-ray diffraction (XRD) spectra for annealed sample in vacuum indicate atomic arrangements with initial nucleation of hcp-Co crystallite at 38$0^{\circ}C$ annealing temperature. However, the XRD spectra in samples with long annealing times of $t_a\geq300$ min demonstrate sharp and good developed surface crystalline hcp-, fcc- Co and $Co_2$Si phases. The giant magnetoimpedance (GMI) profile at 0.1 MHz displaying one-peak behavior in vacuum annealed samples at T = 38$0^{\circ}C$ irrespective of annealing time $t_a$ from 20 to 480 mim. For the annealed samples in an open air, the GMI profile shows two-peaks for $t_a$ = 20 min annealed sample. However, one of peaks disappears and an asymmetric GMI profile exhibits a drastic step-like change near zero field for $t_a\geq300$min. Such asymmetric GMI characteristics is related to the surface microstructures of fcc-Co, hop-Co and $Co_2$Si crystalline phases.

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Magnetization Angle and Thickness Dependence of Perpendicular Exchange Anisotropy in [Pd/Co]n/FeMn Films

  • Choi, S.D.;Joo, H.W.;Yun, D.K.;Lee, M.S.;Lee, K.A.;Lee, H.S.;Kim, S.W.;Lee, S.S.;Hwang, D.G.
    • Journal of Magnetics
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    • 제11권2호
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    • pp.70-73
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    • 2006
  • The magnetization angle and thickness dependence of magnetic anisotropy in the exchange-biased [Pd/Co]${\times}$5/FeMn multilayers with an out-of-plane anisotropy were investigated to determine the origin of perpendicular exchange biasing. As the Co thickness increased to 1.5 nm in the [Pd(0.8 nm)/Co(t)]${\times}$5/FeMn(120 nm) films, the hysteresis loops were converted from square loops at a thin Co (<0.4 nm) to complicated round ones at a thick Co. The irregularly asymmetric step (IAS) at the left top of the loop appeared in the loop of the 0.6-nm Co film due to an inhomogeneity in the exchange anisotropy. As the Pd thickness increased to 1.6 nm, the step disappeared, and the perpendicular magnetic anisotropy was maximized in the Co thickness between 0.6 and 0.9 nm. The conversion of the magnetization loop along the magnetization angle coincided with the equation $H_{(eff)}=H_o\;cos{\theta}$. The IAS of the 0.8-nm Pd film disappeared after thermal annealing up to $200^{\circ}C$ under an external magnetic field.