• 제목/요약/키워드: ash analysis

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An Analysis on the Properties of Cement Mortar using Sewage Sludge Incineration Ash (하수슬러지 소각재를 이용한 시멘트 모르타르의 특성분석)

  • Ryu, Heon-Ki;Park, Jeong-Min
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.55-62
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    • 2010
  • This is an experimental research in order to judge the applicability of sewage sludge incineration ash having applied the mixing proportion needed to manufacture bricks and to do plaster work with addition of hwangtoh and slaked lime as a part of the methods for utilizing the wastes produced from sewage sludge incineration ash. Based on the results from experiment and analysis, it is judged that, in case of mixing proportion of 1:2 for the purpose of plastering and masonry work, the cement mortar produced by using a 10% addition ratio of sewage sludge incineration ash with mixture of hwangtoh covering all range of addition ratio, and also the cement mortar produced by using a 20% of sewage sludge incineration ash together with 0% and 10% addition ratio of hwangtoh, was possible to be applied to the practical use. In case of mixing proportion of 1:7 for manufacture of bricks and blocks, if such brick and block products are produced with 10% and 20% addition ratio of sewage sludge incineration ash having added aggregate fines or stone dust that has been actually used in brick and block manufacturing, it is judged that these bricks and blocks could be practically used in the job sites, although strength development is a little bit lower.

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Analytical Estimation of the Performance of Marine Concrete with Mineral Admixture (광물질 혼화재를 혼합한 해양 콘크리트의 해석적 성능 평가)

  • Lee, Bang-Yeon;Kwon, Seung-Jun;Kang, Su-Tae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.4
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    • pp.301-306
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    • 2015
  • For the purpose of developing high performance marine concrete with improved crack resistance and durability, this analytical study aimed to estimate strength, hydration heat characteristics, and chloride attack resistance of concrete with mineral admixture. Ground granulated furnace slag and fly ash were considered for mineral admixture. The replacement of ground granulated furnace slag and fly ash considered in the analysis was in the range of 0~70% and 0~40 %, respectively. The analysis results indicated that both ground granulated furnace slag and fly ash decreased compressive strength, and the effect of adding ground granulated furnace slag on mitigation of hydration heat was limited whereas fly ash had an noticeable influence on it. It was also found that the replacement with ground granulated furnace slag enhanced the chloride attack resistance but fly ash deteriorated the resistance. From the analytical studies, It could be expected that a ternary blended cement composition with proper amount of ground granulated furnace slag and fly ash might be effective to control crack resistance as well as chloride attack resistance of marine concrete.

Investigation on the Leaching Potential of Water-Soluble Metals from Bottom Ashes in Coal-fired Power Plants (화력발전소 바닥재의 수용성 금속이온 용출가능성 조사)

  • Seo, Hyosik;Koh, Dong-Chan;Choi, Hanna
    • Journal of Soil and Groundwater Environment
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    • v.27 no.1
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    • pp.39-49
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    • 2022
  • Bottom ash generated from thermal power plants is mainly disposed in landfills, from which metals may be leached by infiltrating water. To evaluate the effect of metals in leachate on soil and groundwater, we characterized bottom ash generated from burning cokes, bituminous coal, the mixture of bituminous coal and wood pellets, and charcoal powder. The bottom ash of charcoal powder had a relatively large particle size, and its wood texture was well-preserved from SEM observation. The bottom ash of charcoal powder and wood pellets had relatively high K concentration from total element analysis. The eluates of the bottom ash samples had appreciable concentrations of Ca, Al, Fe, SO4, and NO3, but they were not a significant throughout the batch test. Therefore, it is considered that there is low possibility of soil and groundwater contamination due to leaching of metal ions and anions from these bottom ash in landfills. To estimate the trend of various trace elements, long-term monitoring and additional analysis need to be performed while considering the site conditions, because they readily adsorb on soil and aquifer substances.

Effects of subsequent curing on chloride resistance and microstructure of steam-cured mortar

  • Hu, Yuquan;Hu, Shaowei;Yang, Bokai;Wang, Siyao
    • Advances in concrete construction
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    • v.9 no.5
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    • pp.449-457
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    • 2020
  • The influence of subsequent curing on the performance of fly ash contained mortar under steam curing was studied. Mortar samples incorporated with different content (0%, 20%, 50% and 70%) of Class F fly ash under five typical subsequent curing conditions, including standard curing (ZS), water curing(ZW) under 25℃, oven-dry curing (ZD) under 60℃, frozen curing (ZF) under -10℃, and nature curing (ZN) exposed to outdoor environment were implemented. The unsteady chloride diffusion coefficient was measured by rapid chloride migration test (RCM) to analyze the influence of subsequent curing condition on the resistance to chloride penetration of fly ash contained mortar under steam curing. The compressive strength was measured to analyze the mechanical properties. Furthermore, the open porosity, mercury intrusion porosimetry (MIP), x-ray diffraction (XRD) and thermogravimetric analysis (TGA) were examined to investigate the pore characteristics and phase composition of mortar. The results indicate that the resistance to chloride ingress and compressive strength of steam-cured mortar decline with the increase of fly ash incorporated, regardless of the subsequent curing condition. Compared to ZS, ZD and ZF lead to poor resistance to chloride penetration, while ZW and ZN show better performance. Interestingly, under different fly ash contents, the declining order of compressive strength remains ZS>ZW>ZN>ZD>ZF. When the fly ash content is blow 50%, the open porosity grows with increase of fly ash, regardless of the curing conditions are diverse. However, if the replacement amount of fly ash exceeds a certain high proportion (70%), the value of open porosity tends to decrease. Moreover, the main phase composition of the mortar hydration products is similar under different curing conditions, but the declining order of the C-S-H gels and ettringite content is ZS>ZD>ZF. The addition of fly ash could increase the amount of harmless pores at early age.

Effect of Aluminum Potassium Sulfate Addition on the Color Change in Caesalpinia Sappan Dyeing by Rice Straw Ash Solution (볏짚 잿물 매염에 의한 소목 염색에서 명반 첨가가 색상변화에 미치는 영향)

  • Seo Hee-Sung;Jeon Dong-Won;Kim Jeon-Jun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.11
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    • pp.1465-1474
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    • 2005
  • The primary purpose of this study is to investigate the differences in the characteristics of the mordants, synthetic aluminum mordants and ash solutions as natural mordants, used in Caesalpinia sappan dyeing. By introducing aluminum potassium sulfate in the ash solutions, the behavior of the aluminum in the ash solutions were observed. In the rice straw ash solutions, adjusted to the levels of pH6 and pH10, the aluminum potassium sulfate was introduced to achieve various concentration levels. From the analysis of the ash solution of pull, $K^+$ and $Na^+$ ion concentrations were found to be extremely high, while $Al^+$ ion concentration was 0. The color development in the Caesalpinia sappan dyeing by ash solution mordanting was found to be mainly governed not by the mordanting actions of the metallic ions but by those of alkali components. In the case of cotton, the application of pH10 ash solution promoted reddish color development compared to the case of non-mordanting, regardless of the aluminum potassium sulfate addition. In the case of silk, the application of pH10 ash solution increased a* value and decreased b* value compared to the case of non-mordanting.

The Influences of Cement Mortar Replaced by Paper Sludge Ash and Blast Furnace Slag (제지 슬러지 애쉬 고로슬래그 미분말로 혼합치환한 시멘트가 모르타르에 미치는 영향)

  • 소병현;이주나;박찬수
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.3-9
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    • 2002
  • Paper sludge ash was assured as material of a sort of pozzolan. For the reason of fluidity decrease caused by the strong absorption of paper stooge ash and the decrease of compressive strength in case of using over30% replacement by the weight of cement, paper sludge ash is not suitable for blending material. Therefore, it is necessary to find proper replacement ratios between paper sludge and blast furnace slag to insure compressive compensation and appropriate slump. Accordingly, as varied the blending ratios of paper sludge and blast furnace slag, testing mortar was made. This study was aimed to investigate the possibility of using blending replacement of paper sludge ash and blast furnace slag throughout compressive test, flow test, SEM(Scanning Eletron Microscope), MIP(Mercury Intrusion Porosity test), and TG-DTA(Thermal analysis).

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Engineering Properties of Volcanic Ash-Cement Soil Mixtures and Zeolite-Cement Soil Mixtures (화산재-시멘트 혼합토 및 제올라이트-시멘트 혼합토의 공학적 특성)

  • Lee, Chung-Won;Chang, Dong-Su;Park, Sung-Yong;Yeon, Kyu-Seok;Kim, Yong-Seong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.2
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    • pp.65-75
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    • 2013
  • In this study, the engineering characteristics of volcanic ash-cement soil mixtures and zeolite-cement soil mixtures are investigated by using unconfined compression test, freezing-thawing test, SEM and XRD analysis. The samples were mixed with volcanic ash from Mt. Baekdusan or porous zeolite, and cement as the ratios of 3.5:1, 4.0:1, 4.5:1, 5.0:1 with and without metakaolin. It is confirmed that compressive strength degraded with increasing of the amount of volcanic ash or zeolite, and increased with addition of metakaolin as a binder. Moreover, test results suggested that the mixtures provided sufficient freezing-thawing resistance. In addition, ettringite as a product of cement hydration was detected by SEM and XRD, and that possibly contributes to the strength of the mixtures.

Characteristics of Sewage sludge, Its Incineration Ash, and Sintering Pellet

  • Lee, Ki-Hwan;Lee, Tae-Ho;Cho, Heon-Young;Han, Ki-Suk
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.4
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    • pp.215-220
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    • 2000
  • This study on the incineration ash and sintering pellet from sewage sludge was carried out to evaluate the possibility of recycling in sewage sludge disposal. The samples used in this experiment were raw sewage sludge, its incineration ash, and sintering pellet. The characteristics of the three sample types were identified using X-ray diffraction(XRD), X-ray fluorescence(XRF), atomic absorption spectroscopy(AAS), and inductively coupled plasma spectroscopy(ICP). The chemical compositions of all three sample types were similar in their clay component, however, the sewage sludge had a high content of organic materials. From an analysis of the mineral content of the three sample types, the conversion of their compositions was found to be relative to temperature. Accordingly, incineration ash and sintering pellet both have potential for use as a functional construction material.

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Experiment Study on the Improvement of the Early-Age Strength of Fly Ash Concrete Using CSA (CSA를 사용한 플라이애시 콘크리트의 초기강도 개선을 위한 실험연구)

  • Park, Ji-Sun;Jeon, Chan-Soo
    • Korean Journal of Materials Research
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    • v.23 no.12
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    • pp.687-694
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    • 2013
  • This study was performed with an aim to improve the early-age strength of concrete containing fly ash, which is known to increase the long-age strength of concrete, reduce drying shrinkage, and enhance water tightness. The composition was partially substituted with calcium sulfoaluminate (CSA), from which ettringite is actively produced, in the early stages of hydration to verify its effect on improving the early-age strength and to determine the optimal mixing ratio. For this purpose, up to 30 % of the cement weight was substituted with fly ash, and the amount of CSA substitution was 8% of the fly ash weight. The mixtures were then fabricated into concrete specimens for compressive strength measurement and analysis of the correlation between the hydration products and the compressive strength.

Slagging treatment of MSW incineration ash by plasma system (플라즈마를 이용한 도시 쓰레기 소각재 용융처리 기술)

  • 박현서;지규일;장준섭;전석구;배희주;김형진;이시창;주성준;신범수
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.10a
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    • pp.65-68
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    • 1999
  • A plasma melting system to vitrify ny ash from MSW(Municipal Solid Waste) incinerator has been operated in SHI(Samsung Heavy Industries) since 1996. Waste feeding rate was 200kg/hr. with maximum working power of 500㎾. Because of high melting temperature of fly ash, bottom ash was used as an additive to decrease melting temperature. Data analysis for discharged slag shows volume reduction up to 30% and no leaching of heavy metals such as Pb, Cd, Cr which were an obstacle for landfill and recycle. Atmospheric pollution gas like nitrogen oxides, carbon monoxide, and PCDD/PCDF were restrained below the regulatory limit.

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