• Title/Summary/Keyword: ash analysis

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Overview on The Measurement Methods of Unburned Carbon Contents in Coal Fly-Ash (석탄 비산회(Fly-Ash)의 미연탄소 함량 측정방법에 대한 고찰)

  • Hong, EunPyo;Kim, Jung Hyeun
    • Particle and aerosol research
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    • v.10 no.4
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    • pp.131-136
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    • 2014
  • The importance of waste treatments is increasing because of the lack of resources and environmental problems resulted from economic growth policy. Especially, the pollutant dust which is one of the wastes should be treated considerately because it could cause secondary damages on the human health as well as environmental systems. Recently, massive amount of coal fly-ash is being produced in thermoelectric power plants. In this study, we compared two general methods used in estimating the amount of unburned carbon in fly-ashes to categorize the coal fly-ashes into several groups following their carbon contents. One is the "loss on ignition(KS L 5405) method" which estimates the change of mass after combustion, and it is generally used. Another one is measuring $CO_2$ gas content by burning solid carbon in the fly-ash, and it is called "$CO_2$ analysis method."

A Study on the Engineering Characteristics of Power Plant Coal Ash (화력발전소 부산물인 석탄회의 공학적 특성에 관한 연구)

  • Kuk, Kilkeun;Kim, Hyeyang;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.5
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    • pp.25-34
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    • 2010
  • In this study characteristics for reclaimed ash was studied to enlarge the usage of reclaimed ash which is reaching to 72 million ton producted from whole thermal power plants in South Korea. Fly ash and bottom ash are reclaimed separately at some of thermal power plants. However, typically bottom ash and fly ash are mixed when they are buried at most of the thermal power plant, as a result the engineering characteristics of ponded ash are not investigated properly. In order to investigate the engineering characteristics of the ponded ash, laboratory tests were performed with ponded ash and fly ash from youngheung and samcheonpo thermal power plants. Specific gravity, unit weight, and grain size analysis test were fulfilled to evaluate the physical characteristics and triaxial permeability test, direct shear test, unconfined compressive strength test, compaction test were performed to evaluate the mechanical characteristics. And also engineering characteristics of coal ash from anthracite and Bituminous thermal power plants were compared and studied respectively. As a result of the study, it was confirmed that using coal ash from Bituminous thermal power plants can be effective in the place where lightweight materials are required and using coal ash from anthracite thermal power plants can be effective as backfill material which require higher permeability. Finally, it was confirmed that fly ash from youngheung thermal power plants which has the lowest permeability among the tested material is suitable for a field requiring impermeable material.

Exploiting the Potentials of Rice Husk Ash as Supplement in Cement for Construction in Nigeria

  • Akindahunsi, Akindehinde Ayotunde;Alade, Oluwotosin
    • International Journal of Concrete Structures and Materials
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    • v.4 no.1
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    • pp.3-8
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    • 2010
  • This paper present the results of investigation on the use of rice husk ash as a partial substitute for cement in construction. One hundred and eighty specimens of concrete cubes were cast. 0, 5, 10, 15, and 20% partial replacement of cement with rice husk ash were carried at 1:2:4 mixes by weight with 0.60, 0.65, 0.70 water/cement ratio. The results indicated that compressive strengths of cubes at 0.6, water/cement were higher than 0.65 and 0.70. Also 5% partial replacement cement with rice husk ash at $28^{th}$ day average compressive strength value of $25.4\;N/mm^2$ compared well with 0% partial replacement of cement with rice husk ash of $26.28\;N/mm^2$. This shows that at 5% partial replacement of cement with rice husk ash can be used for structural concrete and at 15% replacement or more it can be used for non - structural construction works or light weight concrete construction. The cost analysis shows substantial amount of savings for the country.

CHARACTERISTICS AND STRENGTH EVALUATION OF THE MIXED MATERIAL OF FLY ASH FROM MUNICIPAL SOLID WASTE INCINERATOR AND THE RECYCLED POLYPROPYLENE

  • Park, Sang-Min;Kim, Hwan-Gi
    • Environmental Engineering Research
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    • v.11 no.5
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    • pp.257-265
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    • 2006
  • The purpose of research is to mix the fly ash from municipal solid waste incinerator in the recycled Polypropylene and to recycle. The specimen was produced by mixing 20 wt.% of MSWI fly ash at maximum in the recycled Polypropylene and the particle size analyzer, DSC, TGA, SEM and UTM instruments were used to analyze the physical chemical properties of the specimen. As a result of measurement, the average particle size of MSWI fly ash was $18.08\;{\mu}m$. In TGA analysis, the temperature of specimen S-5 at 50% of weight decrease was risen by $7^{\circ}C$ higher than specimen S-1. In UTM measurement, specimen S-2 showed the maximum strength for tensile strength and specimen S-3 showed the maximum strength for flexural strength. But, impact strength was decreased according to the increasing proportion of MSWI fly ash. In conclusion, when the proper amount of MSWI fly ash was added to the recycled Polypropylene, thermal endurance, tensile strength and flexural strength could be increased, but impact strength was decreased.

The Time-Dependent Behavior Characteristic of Bottom Ash by Maximum Particle Size and Application of Creep Models (Bottom Ash의 최대입경에 따른 시간-의존적 거동 특성 및 크리프 모델 적용성 검토)

  • Kim, Tae-Wan;Son, Young-Hwan;Bong, Tae-Ho;Noh, Soo-Kack;Park, Jae-Sung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.5
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    • pp.9-16
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    • 2013
  • This study finds the characteristics of long-term settlement of Bottom Ash and to review the application of Singh-Mitchell creep equation and Burgers Model to the creep behavior of Bottom Ash. In the undrained state, it was confirmed that creep behavior appeared in the range to 30-80 % of the maximum deviator stress by applying condition in other three stresses through triaxial compression test after isotropically consolidation. By using sieve analysis, it was compared to each sample that was passed through 9.5 mm, 2 mm, 0.25 mm sieves. Also, using Singh-Mitchell creep equation and Burgers Model, it was compared between the theoretical behavior and the observed behavior for each sample. In the result, it is found that creep behavior of Bottom Ash is similar to the theoretical behavior of Singh-Mitchell creep equation and Burgers Model in early stage and it is possible to predict creep behavior of Bottom Ash by these models.

Analysis of Ash and Trace Metals in Korean Native Bee Honey

  • Kim, Seok-Chang;Lee, Jong-Tae;Park, Chae-Kyu;Shim, Sang-Kwon;Han, Sang-Bae;Kwak, Yi-Seong;Whang, Mi-Sun;Won, Jun-Yeon
    • Journal of Applied Biological Chemistry
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    • v.49 no.4
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    • pp.154-156
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    • 2006
  • Trace metals in honey have an influence on the taste of honey along with pollens. Western bee honeys, which are mostly collected from acacia, have less than 0.1% of ash. Savor of Korean native-bee honey is thought to be due to the difference of the contents of trace metals. Korean native-bee honeys collected from Jirisan District, which is the greatest producing area of native-bee honey in Korea, showed high contents of ash. Korean native-bee honeys from the districts other than Jirisan District also showed similar results($0.44{\sim}0.83%$ of ash) to those from Jirisan District. Potassium was found to be the principal factor of high content of ash with over 85% of trace metals in ash.

Charactetistics of Cement-Fly Ash Paste Containing High Early Strength Admixtures (조강제를 함유한 플라이애쉬 시멘트 페이스트의 특징)

  • 이진용;조현수;이선우;이광명
    • Journal of the Korea Concrete Institute
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    • v.12 no.6
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    • pp.51-56
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    • 2000
  • Fly ash used as a cement replacement material increases the long term strength and also improves the durability of concrete and mortar. However, the use of fly ash is a little in spite of great benefit. In order to increase the consumption of fly ash, it has to be used as a cement replacement materials in the production of mortar and concrete, and the reduction of early strength development due to the use of fly ash also has to be diminished. In this study, many chemical compounds which accelerate the early strength was investigated. The $Na_2$$SO_4$, $K_2$$SO_4$, Triethanolamine were selected and applied to the production of mortar. It was found that they enhance the early strength development of mortar(1, 3day) and decrease the amount of $Ca(OH)_2$, and also increase the production of ettringite. According to the results of mercury instruction test, the pores ranged from 0.01 $\mu\textrm{m}$ to 5$\mu\textrm{m}$ were decreased and it was also found in the analysis of X ray and SEM that fly ash increases the amount of ettringite at early ages.

Supergene Alteration of Basaltic Ash in Udo Tuff Cone, Jeju Island (제주도 우도 현무암질 화산재의 표성 변질작용)

  • Jeong, Gi-Young
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.2
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    • pp.141-150
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    • 2010
  • Basaltic ash of Udo tuff cone, Jeju Island, was almost fresh across strata, but significantly altered toward surface by supergene process. The supergene alteration of the Udo tuff was examined by using X-ray diffraction, scanning and transmission electron microscopy, and electron microprobe analysis for elucidating the alteration process of basaltic ash in terrestrial environments. Fresh ash particles were composed of glass matrix, plagioclase, olivine, and pyroxene. The glass matrix was selectively replaced inward by colloform alteration rinds of Fe-Ti-rich amorphous silicate nanogranules and smectite, often leaving glass core at the center of larger ash particles. Some of the dissolved species released from the altered ash particle precipitated as fine honycomb aggregates of smectite on the pore walls, contributing to the cementation and lithification of volcanic ash.

Carbon nanotubes formation on clay and fly ash from catalytic thermal decomposition of recycled polypropylene

  • Nur A. Atikah Kamaruddin;Norzilah A. Halif;Siti A. Hussin;Mohd. N. Mazlee
    • Advances in materials Research
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    • v.13 no.3
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    • pp.173-181
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    • 2024
  • Fly ash, plastic waste, and clay are mineral materials and residues commonly found in Malaysia. In this study, these materials were fully utilized as raw materials for synthesizing carbon nanotubes (CNTs). Recycled polypropylene, previously used as a food container, served as a carbon source. Fly ash and clay were explored as potential substrates for CNTs growth. The recycled polypropylene was thermally decomposed at 900 ℃ in an inert environment for 90 minutes. Carbon atoms released during this process were deposited on fly ash and clay substrates, which had been immersed in a ferrocene solution to provide a metal catalyst for CNTs growth. The deposited products were characterized using a Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD). Morphological analysis revealed that both fly ash and clay were coated with fiber-like structures, confirmed to be CNTs based on a diffraction peak around 26° from the XRD pattern. In conclusion, clay and fly ash demonstrate the potential to be utilized as substrates for CNTs formation.

Determination of Mercury in Fly Ash by Using Flow Injection Cold Vapor Isotope Dilution Inductively Coupled Plasma Mass Spectrometry

  • Suh, Jung-Ki;Min, Hyung-Sik;Kamruzzaman, Mohammad;Lee, Sang-Hak
    • Mass Spectrometry Letters
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    • v.3 no.2
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    • pp.58-61
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    • 2012
  • A method based on flow injection-isotope dilution-cold vapor-inductively coupled plasma mass spectrometry (FI-IDCV-ICP/MS) has been applied to determine trace level of mercury in fly ash. $^{200}Hg$ isotopic spike was added to 0.25 g of BCR176R fly ash and then decomposed by microwave digestion procedure with acid mixture A (8 mL $HNO_3$ + 2 mL HCl + 2 mL HF) and acid mixture B (8 mL $HNO_3$ + 2 mL $HClO_4$ + 2 mL HF) for applying IDMS. Mercury cold vapor was generated by using reductant solution of 0.2% (w/w) $NaBH_4$ and 0.05% (w/w) NaOH. The measurements of n($^{200}Hg$)/n($^{202}Hg$) isotope ratio was made using a quadrupole ICP/MS system. The accuracy in this method was verified by the analysis of certified reference material (CRM) of fly ash (BCR 176R). The indicative value of Hg in BCR 176R fly ash was $1.60{\pm}0.23$ mg/kg (k = 2). The determined values of Hg in BCR 176R fly ash by the method of FI-CV-ID-ICP/MS described in this paper were $1.60{\pm}0.24$ mg/kg (k = 3.18) and the analysis results were in well agreement with the indicative value within the range of uncertainty.