• Title/Summary/Keyword: ash analysis

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Economic Analysis of Dry Bottom Ash Handling System in a Pulverized Coal Thermal Power Plant in Korea (Ⅱ) -Case Study for Retrofitting the Existing Facility (國內 微分炭 化力發電所에서 바닥재 再活用을 위한 乾式 바닥재 處理시스템 導入의 經濟性 分析 (Ⅱ) -旣存設備 改善事業에 대하여)

  • Oh, Se-Won
    • Resources Recycling
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    • v.14 no.2
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    • pp.56-61
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    • 2005
  • Economic feasibility for retrofitting the wet bottom ash handling system to the dry system in a existing 500MW${\times}$2 units pulverized coal thermal power plant in Korea was studied. Replacing to the dry system requires the initial capital costs of 13,415,127,000\, and saves the operating costs of 935,345,000\ per year. Economic analyses based on these results showed that the initial capital cost would not be recovered within the service life of the facilities at the interest rate of 10%, and the internal rate of return of 5.6% were obtained. Thus, the retrofitting to the dry system was not economically favorable in the current condition. However, the retrofitting would be profitable when the ash disposal cost and ash selling price were increased over 15,000\/MT or 17,000\/MT, respectively.

Characteristics of Hg, Pb, As, Se Emitted from Medium Size Waste Incinerators (중형폐기물 소각시설의 수은, 납, 비소, 셀렌 배출특성)

  • Lee Han-Kook
    • Journal of Environmental Health Sciences
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    • v.32 no.1 s.88
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    • pp.8-18
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    • 2006
  • The aim of this study is to evaluate the emission characteristics of mercury, lead, arsenic, and selenium from medium size municipal solid waste incinerators(MSWIs) in Korea. The concentrations of mercury, lead, arsenic, and selenium emitted from medium size MSWI stack were $2.67\;{\mu}g/Sm^3,\;0.38\;mg/Sm^3,\;1.33\;{\mu}g/Sm^3,\;0.28\;{\mu}g/Sm^3$, respectively. The concentration levels of mercury, lead, arsenic in flue gas from medium size MSW incinerator stacks selected were nearly detected under the Korea criteria level. Removal efficiencies of mercury, lead, arsenic, and selenium in waste heat boiler(WHE) and cooling tower(CT) were $90.36\%,\;69.76\%,\;43.04\%,\;40.64\%$, respectively. In general, the removal efficiencies of mercury and lead in WHE were higher than those of arsenic and selenium in WHE. Emission gas temperature reduction from waste heat boiler(WHB) and cooling tower(CT) can control mercury and lead of medium size MSWIs. To evaluate the relationship between mercury, lead, arsenic, selenium of fly ash and those of flue gas, it was carried out to correlation analysis of each metal concentration in the fly ash and in the flue gas from medium size MSWIs. From the correlation analysis, the coefficients of mercury, lead, arsenic, and selenium were 0.61, -0.38, 0.87, 0.28, respectively. The results of correlation analysis revealed that it should be highly positive to the correlation coefficients of mercury and arsenic in the fly ash and those of the flue gas emitted from medium size MSWIs. As it were, the concentrations of mercury and arsenic of flue gas from medium size MSWIs are high unless mercury and arsenic in fly ash are properly controlled in dust collection step in medium size MSWIs. It was also concluded that mercury, lead, arsenic, and selenium from MSWIs stacks could be controlled by waste heat boiler(WHE) and dust collecting step in medium size MSWIs.

Prediction of UCS and STS of Kaolin clay stabilized with supplementary cementitious material using ANN and MLR

  • Kumar, Arvind;Rupali, S.
    • Advances in Computational Design
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    • v.5 no.2
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    • pp.195-207
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    • 2020
  • The present study focuses on the application of artificial neural network (ANN) and Multiple linear Regression (MLR) analysis for developing a model to predict the unconfined compressive strength (UCS) and split tensile strength (STS) of the fiber reinforced clay stabilized with grass ash, fly ash and lime. Unconfined compressive strength and Split tensile strength are the nonlinear functions and becomes difficult for developing a predicting model. Artificial neural networks are the efficient tools for predicting models possessing non linearity and are used in the present study along with regression analysis for predicting both UCS and STS. The data required for the model was obtained by systematic experiments performed on only Kaolin clay, clay mixed with varying percentages of fly ash, grass ash, polypropylene fibers and lime as between 10-20%, 1-4%, 0-1.5% and 0-8% respectively. Further, the optimum values of the various stabilizing materials were determined from the experiments. The effect of stabilization is observed by performing compaction tests, split tensile tests and unconfined compression tests. ANN models are trained using the inputs and targets obtained from the experiments. Performance of ANN and Regression analysis is checked with statistical error of correlation coefficient (R) and both the methods predict the UCS and STS values quite well; but it is observed that ANN can predict both the values of UCS as well as STS simultaneously whereas MLR predicts the values separately. It is also observed that only STS values can be predicted efficiently by MLR.

Analysis of the clinker formed in circulating fluidized bed boiler (유동층 보일러에 생성된 크링커에 대한 분석)

  • Kim, Kyeong-Sook;Park, Hyun-Joo;Lee, Tae-Won;Jeong, Nyeon-Ho
    • Analytical Science and Technology
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    • v.13 no.1
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    • pp.5-11
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    • 2000
  • During the commissioning period in Tonghae thermal power plant which is the largest circulating fluidized bed boiler in the nation, a considerable amount of clinker was formed at FBAC and seal pot. Various attempts, for example, concentration analysis, surface phenomena, thermal characterization, and crystal structure of ash, bed sand, limestone, clinker, and mixture of each gradients have been studied to identify the causes of clinker formed in circulating fluidized bed boiler. As the results, the characterization of black particles in which separated from the clinker is more similar to that of bed sand, on the other hand, white particles are more similar to ash. In addition, the sintering temperature of sand is over $1,200^{\circ}C$ and this temperature was decreased as limestone is added to bed material. The cause of clinker was proved that ash was sticked to molten or sintered sand or limestone in the area of high temperature in the circulating system.

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Analysis of Evaluation Possibility of Fly Ash Fineness Using Hydrometer (Hydrometer에 의한 플라이애시의 분말도 평가 가능성 분석)

  • Song, Heung-Ho;Han, Cheon-Go
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.119-125
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    • 2017
  • Due to the processing cost, there were some reports on distribution of unrefined fly ash. Hence, in this research, the possibility of fly ash quality evaluation by measuring the density of various qualities of coal ash suspensions with hydrometer. According to the experimental results, the appropriate test conditions were determined with 1,000cc capacity mass cylinder for 1,000cc of water with 100g of fly ash. From the evaluating performance of various coal ashes, based on a good correlation between fineness and quality of the coal ashes, it was possible to evaluate the quality of coal ash by measuring different density of suspension with hydrometer. In this research conditions, the suggestable measuring time of density variation was three minute for fly ash quality related with fineness.

Condensation and coagulation of metallic species with fly ash particles in a waste incinerator (폐기물 소각시 생성되는 유해 중금속물질과 연소실내 비산재와의 응축, 응집 현상에 대한 연구)

  • Yu, Ju-Hyeon;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.2
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    • pp.264-274
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    • 1997
  • A numerical analysis on condensation and coagulation of the metallic species with fly ash particles pre-existing in an incinerator was performed. Waste was simplified as a mixture of methane, chlorine, and small amounts of Pb and Sn. Vapor-phase amounts of Pb- and Sn -compounds were first calculated assuming a thermodynamic equilibrium state. Then theories on vapor-to-particle conversion, vapor condensation onto the fly ash particles, and particle-particle interaction were examined and incorporated into equations of aerosol dynamics and vapor continuity. It was assumed that the particles followed a log-normal size distribution and thus a moment model was developed in order to predict the particle concentration and the particle size distribution simultaneously. Distributions of metallic vapor concentration (or vapor pressure) were also obtained. Temperature drop rate of combustion gas, fly ash concentration and its size were selected as parameters influencing the discharged amount of metallic species. In general, the coagulation between the newly formed metal particles and the fly ash particles was much greater than that between the metal particles themselves or between the fly ash particles themselves. It was also found that the amount of metallic species discharged into the atmosphere was increased due to coagulation. While most of PbO vapors produced from the combustion were eliminated due to combined effect of condensation and coagulation, the highly volatile species, PbCl$_{2}$ and SnCl$_{4}$ vapors tended to discharge into the atmosphere without experiencing either the condensation or the coagulation. For Sn vapors the tendency was between that of PbO vapors and that of PbCl$_{2}$ or SnCl$_{4}$. To restrain the discharged amount of hazardous metallic species, the coagulation should be restrained, the number concentration and the size of pre-existing fly ash particles should be increased, and the temperature drop rate of combustion gas should be kept low.

Trends of Recycling Technologies in Utilization of Coal Combustion Byproducts for Manufacturing Geopolymers through Patent and Literature Analysis (특허와 논문으로 본 석탄 연소부산물의 지오폴리머 원료화 기술 동향)

  • Lee, Sujeong;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.23 no.2
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    • pp.81-89
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    • 2014
  • Approximately 8.5 million tons of fly ash and 740,000 tons of briquette ash were produced in 2010. Inefficient recycling of coal ash has been a heavy economic and environmental burden and economical coal ash utilization technologies are required to turn coal ash into valuable resources. In this study the patents and literature were analyzed to understand the present situation of coal ash recycling technologies and to promote utilization of coal ash for producing a non-sintering green cement, geopolymer. The survey was based on the open patents of USA, European Union, Japan and Korea, and the papers in SCI - indexed journals published between 1979 and 2013. Technical key words were used for data collection and noise filtering. Trends of recycling technologies in utilization of coal ash for producing geopolymers were discussed in terms of time periods, countries, companies and various forms of technologies.

Efficacy of supplementary cementitious material and hybrid fiber to develop the ultra high performance hybrid fiber reinforced concrete

  • Sharma, Raju;Bansal, Prem Pal
    • Advances in concrete construction
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    • v.8 no.1
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    • pp.21-31
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    • 2019
  • The rich recipe of ultra high performance concrete (UHPC) offers the higher mechanical, durability and dense microstructure property. The variable like cement/sand ratio, amount of supplementary cementitious material, water/binder ratio, amount of fiber etc. alters the UHPC hardened properties to any extent. Therefore, to understand the effects of these variables on the performance of UHPC, inevitably a stage-wise development is required. In the present experimental study, the effect of sand/cement ratio, the addition of finer material (fly ash and quartz powder) and, hybrid fiber on the fresh, compressive and microstructural property of UHPC is evaluated. The experiment is conducted in three phases; the first phase evaluates the flow value and strength attainment of ingredients, the second phase evaluates the efficiency of finer materials (fly ash and quartz powder) to develop the UHPC and the third phase evaluate the effect of hybrid fiber on the flow value and strength of ultra high performance hybrid fiber reinforced concrete (UHP-HFRC). It has been seen that the addition of fly ash improves the flow value and compressive strength of UHPC as compared to quartz powder. Further, the usage of hybrid fiber in fly ash contained matrix decreases the flow value and improves the strength of the UHP-HFRC matrix. The dense interface between matrix and fiber and, a higher amount of calcium silicate hydrate (CSH) in fly ash contained UHP-HFRC is revealed by SEM and XRD respectively. The dense interface (bond between the fiber and the UHPC matrix) and the higher CSH formation are the reason for the improvement in the compressive strength of fly ash based UHP-HFRC. The differential thermal analysis (DTA/TGA) shows the similar type of mass loss pattern, however, the amount of mass loss differs in fly ash and quartz powder contained UHP-HFRC.

Quality Analysis of Fly Ash Through Correlation between Density by Hydrometer and Test Report (Hydrometer법을 이용한 밀도 측정값과 시험 성적서간 상관분석을 통한 플라이애시의 품질특성 분석)

  • Song, Heung-Ho;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.4
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    • pp.305-312
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    • 2017
  • To evaluate the reliability of fly ash quality supplied to ready-mixed concrete plant using mass cylinder and hydrometer, in this research, the correlationship between the fly ash properties provided from certification and density measurement with suspension was evaluated. As a result, the reliability of the certification, except fineness and loss on ignition, all properties had a discord. Additionally, in the case of density, fineness, and L.O.I, the relation with the density measured using hydrometer showed high correlation, especially fineness was strongly related with the density measured using hydrometer. Furthermore, according to the comparative analysis with previous research, the fly ash used in this research was similar measurement with raw powder without any refining process, it is considered that the constant error of blaine test or using raw ash sample as a fly ash. In current standard regarding fly ash, the fineness range of class 2 can be changed from $3,000-4,500cm^2/g$ to $3,500-4,500cm^2/g$ for improved quality of fly ash in fineness aspect.

Study on Characteristics of Fine Bottom Ash Based Geopolymer Mortar (미분쇄 바텀애시 기반 지오폴리머 모르타르 특성에 관한 연구)

  • Lim, Gwi-Hwan;Lee, Jeong-Bae;Jeong, Hyun-Kyu;Kim, Seong-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.418-424
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    • 2016
  • This study is an experimental study on the recycling of bottom ash in coal ash discharged from a thermal power plant. Bottom ash has limited research on recycling because it has more porous and higher water absorption ratio than fly ash. In this paper, the bottom ash was pulverized to a specific surface area of $4,000cm^2/g$ in order to use as a binder, and the flow, compressive strength test and microstructure analysis of the bottom ash based geopolymer mortar were performed. The flow measurement results of the geopolymer mortar showed that the flow rate was improved by increasing mixing water as the molar concentration of activator was increased. Compressive strength increased with increasing curing temperature and molar concentration. Through the microstructure analysis, we could confirm the geopolymer gel produced by the reaction of the condensation polymerization. It is considered that it is possible to make the bottom ash based geopolymer concrete through proper molar concentration of activator and high temperature curing.