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Synthesis and Optical Property of TiO2 Nanoparticles Using a Salt-assisted Ultrasonic Spray Pyrolysis Process (염 보조 초음파 분무 열분해법을 이용한 TiO2 나노입자의 합성 및 광학적 성질)

  • Ji, Myeong-Jun;Park, Woo-Young;Yoo, Jae-Hyun;Lee, Young-In
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.34-39
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    • 2019
  • Current synthesis processes for titanium dioxide ($TiO_2$) nanoparticles require expensive precursors or templates as well as complex steps and long reaction times. In addition, these processes produce highly agglomerated nanoparticles. In this study, we demonstrate a simple and continuous approach to synthesize $TiO_2$ nanoparticles by a salt-assisted ultrasonic spray pyrolysis method. We also investigate the effect of salt content in a precursor solution on the morphology and size of synthesized products. The synthesized $TiO_2$ nanoparticles are systematically characterized by X-ray diffraction, transmission electron micrograph, and UV-Vis spectroscopy. These nanoparticles appear to have a single anatase phase and a uniform particle-size distribution with an average particle size of approximately 10 nm. By extrapolating the plots of the transformed Kubelka-Munk function versus the absorbed light energy, we determine that the energy band gap of the synthesized $TiO_2$ nanoparticles is 3.25 eV.

Study on Consumer Exposure to Sun Spray and Sun Cream in South Korea

  • Oh, Mihyun;Kim, Seoyoung;Han, Jieun;Park, Sodam;Kim, Go Un;An, Susun
    • Toxicological Research
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    • v.35 no.4
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    • pp.389-394
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    • 2019
  • When conducting risk assessments of cosmetic ingredients, it is important that reliable exposure information is obtained for cosmetic products. As cosmetics are becoming more diverse, continuous effort must be made to obtain exposure data that reflect their growth and usage trends. The usage pattern of cosmetics, such as the application area and amount used, may differ by product type and also by country. We conducted a survey to compare the amount of sun spray and sun cream used in a usage environment in South Korea. The study was conducted on Haeundae Beach, one of the most popular beaches in South Korea. A total of 1,255 beachgoers participated in this study; 604 and 651 participants used the sun spray and sun cream, respectively, while sunbathing and enjoying water activities on the beach for one day. Exposure was analyzed following a probabilistic method. On comparing all subjects, it was found that the group that used sun spray (mean: 44.52 g/day) used significantly more product (p = 0.000) than those who used sun cream (mean: 20.51 g/day). By analyzing the daily exposure of sun spray and sun cream per unit body weight according to age and gender, the exposure amount of sun spray and sun cream was found to be highest among 2~9 year-old girls (mean for sun spray: 2.51 g/kg/day, p95: 5.50 g/kg/day, mean for sun cream: 0.79 g/kg/day, p95: 1.79 g/kg/day). The amount of sun spray used is approximately twice that of sun cream. Among both the sun spray and sun cream groups, the exposure amount per unit body weight was highest in girls younger than 10. These factors should be considered when conducting risk assessments of sun spray and sun cream.

Figure of merit and bending characteristics of Mn-SnO2/Ag/Mn-SnO2 tri-layer film (Mn-SnO2/Ag/Mn-SnO2 3중 다층막의 성능지수와 밴딩 특성)

  • Cho, Youngsoo;Jang, Guneik
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.4
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    • pp.190-195
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    • 2021
  • Typical Mn-SnO2/Ag/Mn-SnO2 tri-layer films were prepared on a PET substrate by RF/DC magnetron sputtering method at room temperature. Based on EMP simulation, the thicknesses of the top and bottom Mn-doped SnO2 layers were kept at 40 nm and the Ag layer was maintained at 13 nm for continuous electrical conduction. The experimentally measured optical transmittances at 550 nm wavelength were ranged from 82.9 to 88.1 % and sheet resistances were varied from 5.9 to 6.9 Ω/☐. The highest value of figure of merit, ϕTC was 48.1 × 10-3 Ω-1. Based on bending test under 4 and 5 mm of inner and outer curvature radius condition, tri-layer film resistance varies only by approximately 1.5 % after 10,000 bending cycles, showing excellent mechanical flexibility.

Synthesis and Evaluation of Superhydrophobic ODA/PDMS Dip Coating on PET for Liquid-Solid Contact Electrification (액체-고체 접촉대전을 위한 PET 기판 기반 ODA/PDMS 딥 코팅 제조 및 평가)

  • Park, Sunyoung;Kang, Hyungyu;Byun, Doyoung;Cho, Dae-Hyun
    • Tribology and Lubricants
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    • v.37 no.2
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    • pp.71-76
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    • 2021
  • As opposed to using fossil fuels, we need to use eco-friendly resources such as sunlight, raindrops and wind to produce electricity and combat environmental pollution. A triboelectric nanogenerator (TENG) is a device that converts mechanical energy into electricity by inducing repetitive contact and separation of two dissimilar materials. During the contact and separation processes, electron flow occurs owing to a change in electric potential of the contacting surface caused by contact electrification and electrostatic induction mechanisms. A solid-solid contact TENG is widely known, but it is possible to generate electricity via liquid-solid contact. Therefore, by designing a hydrophobic TENG, we can gather electricity from raindrop energy in a feasible manner. To fabricate the superhydrophobic surface of TENGs, we employ a dip coating technique to synthesize an octadecylamine (ODA)- and polydimethylsiloxane (PDMS)-based coating on polyethylene terephthalate (PET). The synthesized coating exhibits superhydrophobicity with a contact angle greater than 150° and generates a current of 2.2 ㎂/L while water droplets fall onto it continuously. Hence, we prepare a box-type TENG, with the ODA/PDMS coating deposited on the inside, and place a 1.5 mL water droplet into it. Resultantly, we confirm that the induced vibration causes continuous impacts between the ODA/PDMS coating and the water, generating approximately 100 pA for each impact.

Saltwater Intrusion Monitoring Evaluation through Automatic Vertical Line Method in a Costal Aquifer of the Eastern Part of Jeju Island (수직 라인 관측시스템을 이용한 제주 동부 해안대수층에서 해수침투 모니터링 평가)

  • Jang, Hojune;Ha, Kyoochul;Hwang, Inuk;Kim, Gee-Pyo;Park, Won-Bae
    • Journal of Soil and Groundwater Environment
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    • v.26 no.3
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    • pp.1-13
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    • 2021
  • Groundwater monitoring is commonly practiced with real-time sensors placed in several depth spots in aquifer. However, this method only provides monitoring data at the point where the sensors are installed. In this study, we developed a vertical line monitoring system (VLMS) that can provide continuous data of groundwater parameters along the vertical depth. The device was installed in a well located on the coast of the eastern part of Jeju island to monitor electrical conductivity, temperature, salinity, pH, dissolved oxygen, and oxidation-reduction potential over approximately 3 months from September 11 to December 3, 2020. The results indicated that the groundwater levels fluctuated with the tidal change of seawater level, and the upper and lower boundaries of the freshwater and saltwater zone in the groundwater were located at below 16 m and 36 m of mean sea level, respectively. There was a large variation in EC values during the high tide and temperature change was the greatest during flow tide. Although further investigation is needed for improvement of the device to obtain more accurate and reliable data, the device has a potential utility to provide fundamental data to understand the seawater intrusion and transport mechanisms in coastal aquifers.

High-Speed Maritime Object Detection Scheme for the Protection of the Aid to Navigation

  • Lee, Hyochan;Song, Hyunhak;Cho, Sungyoon;Kwon, Kiwon;Park, Sunghyun;Im, Taeho
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.16 no.2
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    • pp.692-712
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    • 2022
  • Buoys used for Aid to Navigation systems are widely used to guide the sea paths and are powered by batteries, requiring continuous battery replacement. However, since human labor is required to replace the batteries, humans can be exposed to dangerous situation, including even collision with shipping vessels. In addition, Maritime sensors are installed on the route signs, so that these are often damaged by collisions with small and medium-sized ships, resulting in significant financial loss. In order to prevent these accidents, maritime object detection technology is essential to alert ships approaching buoys. Existing studies apply a number of filters to eliminate noise and to detect objects within the sea image. For this process, most studies directly access the pixels and process the images. However, this approach typically takes a long time to process because of its complexity and the requirements of significant amounts of computational power. In an emergent situation, it is important to alarm the vessel's rapid approach to buoys in real time to avoid collisions between vessels and route signs, therefore minimizing computation and speeding up processes are critical operations. Therefore, we propose Fast Connected Component Labeling (FCCL) which can reduce computation to minimize the processing time of filter applications, while maintaining the detection performance of existing methods. The results show that the detection performance of the FCCL is close to 30 FPS - approximately 2-5 times faster, when compared to the existing methods - while the average throughput is the same as existing methods.

QFD-Based Integrated Model of Dismantling Method Selection and FMEA Risk Assessment for Work Stage (QFD 기반의 해체공사 공법선정과 FMEA 위험성평가 통합 모델)

  • Lee, Hyung-Yong;Cho, Jae-Ho;Son, Bo-Sik;Chae, Myung-Jin;Kim, Hyun-Soo;Chun, Jae-Youl
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.6
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    • pp.629-640
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    • 2021
  • According to statistics from the Ministry of Land, Infrastructure and Transport in 2018, approximately 37% of residential buildings in Korea need to be reconstructed. Due to the rapid growth of the demolition industry, many side effects such as environmental destruction and safety accidents are becoming a problem in the demolition of existing buildings. This study proposes a decision-making process for selecting the most suitable dismantling method for field application by comprehensively considering safety, economic feasibility, and environmental characteristics. In particular, field applicability is evaluated by evaluating risk factors for the selected method. To this end, this study proposes the TOPSIS method for the selection of the dismantling method using the QFD development concept, and the FMEA method as a continuous development process of the selected method.

Characteristics of Anaerobic Digestion using Food waste leachate under Increased Organic Loading rate (유기물부하량 증가에 따른 음폐수 혐기성소화의 특성 분석)

  • Jae-Hoon Jeung;Woo-Jin Chung;Soon-Woong Chang;Jin-Tea Kim;Seong-Yeob Jeong;Seung-Youn Yang
    • Journal of Environmental Science International
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    • v.31 no.12
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    • pp.1127-1134
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    • 2022
  • Herein , the effect of changes in the organic loading rate in anaerobic digestion was evaluated. The experiment was carried out by a laboratory -scale semi-continuous stirred tank reactor, and feedstock was food-waste leached. The organic loading rate was increased by 0.5 kgVS/m3 in each phase from 1.0 kgVS/m3 to 4.0 kgVS/m3. At the end of the operation, to check the failure of the reactor, the organic loading rate was increased by 1.0 kgVS/m3 in each phase and reached 6.0 kgVS/m3. This shows that the biogas yield decreased as organic loading rate increased. Biogas production seemed to be unstable at 3.5-6.0 kgVS/m3. Moreover, biogas production dramatically fell to approximately 0 mL at 6.0 kgVS/m3, which was decided as the operation failure on the 16th day of the las tphase. The result of the reactor analysis shows that the cumulation of volatile fatty acid increased as the organic loading rate increased. This seems to occur due to the decreasein pH in the reactor and led to extinction of anaerobic bacteria, which were the biogas products. Although the buffer compound (alkalinity) could prevent the decline in pH, the concentration of alkalinity was found to be lacking at a high organic loading rate

Awareness and attitudes regarding oral care intervention program based on community care for older adults at home : focusing on the grounded theory (커뮤니티케어 기반의 방문구강건강관리 중재 수혜자의 프로그램 운영 관련 인식 및 태도: 근거이론적 접근)

  • Myeong-Hwa Park;Ji-Won Park;Seul-Ah Lee;Jong-Hwa Jang
    • Journal of Korean society of Dental Hygiene
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    • v.23 no.5
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    • pp.351-360
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    • 2023
  • Objectives: This study is based on a visiting oral health care intervention program in the community care. This qualitative study was conducted through in-depth interviews to identify awareness and attitudes regarding intervention program among older adults. Methods: The research team visited the homes of the target older adults and conducted in-depth interviews for approximately an hour using a semi-structured questionnaire. The collected voice recordings were transcribed using Clova Note, and AI program by Naver. Using the 'Word Cloud Generator 3.7' program, words of high importance and interest from interview answers were extracted, visualized, and analyzed. Results: Participating older adults acknowledged that their quality of life related to oral health could be improved by increasing the level of oral health awareness and oral health knowledge through the intervention program. In addition, the older adults indicated that their oral hygiene management ability improved compared to before the intervention through expert oral hygiene management and oral health education. Further, as the level of oral health knowledge increased, so too did satisfaction with the intervention program increase. Conclusions: The intervention program for visiting oral health care showed a positive effect on the awareness and attitude of older adults. Thus, it is suggested that education for continuous competency enhancement of dental hygienists and multidisciplinary education for the improvement of general health and quality of life of older adults should be promoted.

Analysis of Offshore Aquaculture Detection Techniques Using Synthetic Aperture Radar Images (레이더 영상을 이용한 연안 양식장 탐지 기법 분석)

  • Do-Hyun Hwang;Hahn Chul Jung
    • Korean Journal of Remote Sensing
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    • v.39 no.6_1
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    • pp.1401-1411
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    • 2023
  • In the face of escalating utilization of the marine spatial domain, conflicts have emerged among stakeholders, necessitating effective management strategies beyond conventional government permits and regulations. Particularly within the domain of aquaculture, operational oversight relies on a localized licensing system, posing challenges in accurately assessing the prevailing circumstances. This research employs synthetic aperture radar (SAR) imagery as a tool to monitor coastal aquaculture fish farms, aimed at enhancing insights into management protocols. Leveraging Sentinel-1A imagery and time series SAR data integration, a superimposition technique is utilized, facilitating noise reduction while retaining crucial information regarding smaller-scale facilities, such as fish farms. Through analysis of VH polarization data, a detection overall accuracy of approximately 88% for coastal fish farms was achieved. The findings of this study offer potential applications in the continuous monitoring of aquaculture farms in correspondence with seasonal variations in aquaculture yields, thereby proposing frameworks for the establishment of effective management cycles for marine space utilization.