• KSBB Journal
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• 제20권6호
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• pp.431-437
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• 2005

1. 고온 CSTR은 비교적 짧은 start-up 기간과 높은 $H_2$ 수율을 나타내었다. $H_2$ 생산속도와 $H_2$ 수율의 안정화를 근거로 판단컨대 start-up 기간은 30일 이내이었으며, 최고 $H_2$ 수율은 2.4 mol $H_2/mol$ glucose이었다. 2. 비교적 긴 HRT와 침전조를 이용한 biomass의 재순환에도 불구하고, 유입 포도당의 농도가 낮아 biomass 농도는 다른 중온 반응기에서 보고된 것에 비해 낮은 편이었다. 3. 운전 초기에 $CH_4$이 발생하였으나 8일 이후부터는 pH를 1.0 이하로 유지하였더니 14일 이후로는 거의 검출되지 않는 것으로 봐서 메탄생성균이 식종균에 남아 있더라도 반응기 운전조건을 통해 $CH_4$ 발생을 억제할 수 있었다. 4. 식종 미생물과 반응기로부터 취한 시료의 DGGE band 패튼이 다른 것으로 보아 고온 CSTR 조건에서 식종된 미생물 군집의 조성이 변화하였음을 알 수 있었다. 5. DGGE 분석결과 초기 43일간의 운전기간 동안에 관찰된 미생물 군집조성은 동적인 변화를 나타내었다. 약 14일부터는 biogas 조성이 거의 일정하였으나 미생물 군집은 동적 변화를 나타내었다. F. gondwanens와 T. Thermoanaerobacterium과 계통발생학적으로 가장 연관이 있는 개체군들이 운전 21일과 41일째에 각각 우점으로 나타났다. 6. 본 연구에서 식종 슬러지를 열처리하는데 사용한 조건은 메탄생성균을 완전히 제거하는데 불충분하다는 것은 운전 초기에 $CH_4$이 biogas에서 검출되었고, 식종 슬러지와 반응기로부터 취한 시료에서 메탄생성균이 가지는 mcrA 유전자가 PCR로 증폭되었으므로 알 수 있었다. 7. 메탄생성균의 주요 목에 특이적인 primers를 사용하여 PCR을 실시한 결과 식종슬러지에 있는 메탄생성균들은 주로 Methanosarcinales와 Methanomicrobiales 목에 속하였으며, $CH_4$이 발생했던 때의 반응기에 있는 메탄생성균들은 주로 Methanobacteriales 목에 해당되는 것으로 나타났다.

• 한국작물학회지
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• 제46권4호
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• pp.266-271
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• 2001

Soybean can produce high-N residue due to N-fixation, so soybean rotation may increase yield of subsequent corn and reduce N fertilizer on the corn fairly. To find out the contribution of nitrogen to subsequent corn following soybean cultivation, soil nitrate, corn yield, and nitrogen uptake were measured for three continuous corn cropping years after soybean rotation. Three N rates of 0, 80, and 160 kg/ha were applied to three continuous corn following soybean cropping. At 6-leaf stage, soil nitrate amount at the soil depth of 0-30cm ranged from 60 to 80 kgN/ha higher in the first corn cropping year than that in the second and third corn cropping years. Judging from corn N status such as SPAD value, N concentration of ear-leaf and stover at silking stage, N contribution of previous soybean to corn in the first corn year was N fertilizer of approximately 80 kg N/ha. Stover N uptake at silking stage increased from 47 to 52 kg N/ha at the 0, and 80 kg N/ha of N rates in the first corn cropping year compared with those in the second and third corn cropping years. Corn grain yield at the 0 kg N/ha of N rate was 6-7 ton/ha higher in the first corn cropping year than that in the second and third corn cropping years, respectively. When compared the first corn year following soybean cropping with the second and third corn cropping years, N uptake of grain and stover at harvest with low N rates such as 0 and 80 kg N/ha increased from 45 to 67kg N/ha, from 35 to 60 kg N/ha, respectively. N uptake of whole plant by soybean rotation increased from 93 to 118 kg N/ha in the first year compared with that in the second and third corn cropping years. However, the N contribution by soybean cropping was small in the second and third continuous corn cropping years. Therefore, it was concluded that the nitrogen fertilizer of 80-100 kg N/ha in the first corn cropping year could be saved by soybean rotation and annual alternative corn-soybean rotation could be the best rotation system.

• 미생물학회지
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• 제25권4호
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• pp.333-338
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• 1987

아세트알데히드 공장폐수의 생물학적 처리를 위하여 중화제 및 응집제의 효과를 검토하고, 4개 균주 Micrococcus roseus AW-6. Micrococcus luteus, AW -22. Microbacterium lacticum AW-38. Microbacterium laevaniformans AW-41을 혼합 배양하여 미생물의 영양요구량 및 성장에 미치는 환경인자 둥을 조사한 결과는 다음과 같다. 아세트알데히드 폐수를 잘 자화시키는데 필요한 온도는 $30^{\circ}C$였고 pH는 7.0이였으며 96시간째에 COD 제거율이 최대에 달하였다. 폐수처리를 위한 중화제로서는 NaOH가 가장 좋았고 응집제의 처리 효과는 인정되지 않았으며 폐수처리를 위한 최적 희석배수는 10배 정도로 나타났다. 균 생육을 위한 영양원으로서는 $NH_{2}NO_{3}$ 200ppm, $KH_{2}PO_{4}$, 50ppm, $CaCl_{2}$ 15ppm. $MgSO_{4} \cdot 7H_{2}O $ ppm을 보충하였을 때 COD 제거율이 향상되었다. 회분배양 실험결과 속도계수 Kl은 4. 5X 10-6이었으며, BOD 제거융을 85%로 하기 위한 체류시간은 45시간 이었다. 연속배양 결과 COD 제거율은 85%로 나타났으며 처리수의 수질은 COD 60ppm. BOD 40ppm, pH7.0 정도로서 환경기준치 이하였다.

• 한국물환경학회지
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• 제24권2호
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• pp.185-194
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• 2008

There is increased soil erosion potential at highland agricultural crop fields because of its topographic characteristics and site-specific agricultural management practices performed at these areas. The agricultural upland fields are usually located at the sloping areas, resulting in higher soil loss, pesticides, and nutrients in case of torrential rainfall events or typhoon, such as 2002 Rusa and 2003 MaeMi. At the highland agricultural fields, the soil reconditioning have been performed every year to decrease damage by continuous cropping and pests. Also it has been done to increase crop productivity and soil fertility. The increased amounts of soil used for soil reconditioning are increasing over the years, causing significant impacts on water quality at the receiving water bodies. In this study, the field investigation was done to check soil reconditioning status for potato, carrot, and cabbage at the Doam-dam watershed. With these data obtained from the field investigation, the Soil and Water Assesment Tool (SWAT) model was used to simulate the soil loss reduction with environment-friendly and agronomically enough soil reconditioning. The average soil reconditioning depth for potato was 34.3 cm, 48.3 cm for carrot, and 31.2 cm for cabbage at the Doam-dam watershed. These data were used for SWAT model runs. Before the SWAT simulation, the SWAT ArcView GIS Patch, developed by the Kangwon National University, was applied because of proper simulation of soil erosion and sediment yield at the sloping watershed, such as the Doam-dam watershed. With this patch applied, the Coefficient of Determination ($R^2$) value was 0.85 and the Nash-Sutcliffe Model Efficiency (EI) was 0.75 for flow calibration. The $R^2$ value was 0.87 and the EI was 0.85 for flow validation. For sediment simulation, the $R^2$ value was 0.91 and the EI was 0.70, indicating the SWAT model predicts the soil erosion processes and sediment yield at the Doam-dam watershed. With the calibrated and validated SWAT for the Doam-dam watershed, the soil erosion reduction was investigated for potato, carrot, and cabbage. For potato, around 19.3 cm of soil were over applied to the agricultural field, causing 146% of more soil erosion rate, approximately 33.3 cm, causing 146% of more soil erosion for carrot, and approximately 16.2 cm, causing 44% of more soil erosion. The results obtained in this study showed that excessive soil reconditioning are performed at the highland agricultural fields, causing severe muddy water issues and water quality degradation at the Doam-water watershed. The results can be used to develop soil reconditioning standard policy for various crops at the highland agricultural fields, without causing problems agronomically and environmentally.

• 자원환경지질
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• 제28권3호
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• pp.199-211
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• 1995

The deep sea camera system could render it possible to obtain the detailed information of the nodule distribution, but difficult to estimate nodule abundance quantitatively. In order to estimate nodule abundance quantitatively from deep seabed photographs, the nodule abundance equation was derived from the box core data obtained in KODOS area(long.: $154^{\circ}{\sim}151^{\circ}W$, lat.: $9^{\circ}{\sim}12^{\circ}N$) during two survey cruises carried out in 1989 and 1990. The regression equation derived by considering extent of burial of nodule to Handa's equation compensates for the abundance error attributable to partial burial of some nodules by sediments. An average long axis and average extent of burial of nodules in photographed area are determined according to the surface textures of nodules, and nodule coverage is calculated by the image analysis method. Average nodule abundance estimated from seabed photographs by using the equation is approximately 92% of the actual average abundance in KODOS area. The measured sampling points by box core or free fall grab are in general very sparse and hence nodule abundance distribution should be interpolated and extrapolated from measured data to uncharacterized areas. The another goal of this study is to depict continuous distribution of nodule abundance in KODOS area by using PC-version of geostatistical model in which several stages are systematically proceeded. Geostatistics was used to analyse spatial structure and distribution of regionalized variable(nodule abundance) within sets of real data. In order to investigate the spatial structure of nodule abundance in KODOS area, experimental variograms were calculated and fitted to a spherical models in isotropy and anisotropy, respectively. The spherical structure models were used to map out distribution of the nodule abundance for isotropic and anisotropic models by using the kriging method. The result from anisotropic model is much more reliable than one of isotropic model. Distribution map of nodule abundance produced by PC-version of geostatistical model indicates that approximately 40% of KODOS area is considered to be promising area(nodule abundance > $5kg/m^2$) for mining in case of anisotropy.

• Journal of Animal Science and Technology
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• 제49권2호
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• pp.279-286
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• 2007

반응물을 연속적으로 내부 순환시키는 생물막 연속회분식모래여과 공정을 고안하고 외부 탄소원이 전혀 사용되지 않는 조건하에서의 돈사폐수 처리특성을 평가하였다. 수직형과 경사형 모래여과조에서의 NOx-N 부하량에 따른 탈질율은 각각 19%와 3.8%로 수직형에서 5배 정도 높은 효율을 보임에 따라 수직형태의 모래여과조를 생물막 연속회분식 공정과 연계하여 운전하였다. 처리공정을 HRT 15일, 내부순환율 105L/hr.m3, 평균 암모니아성 질소 부하량 54g/m3.d 조건에서 운전하였을 때 STOC, NH4- N, TN의 처리효율은 각각 75%, 97%, 85%이었다. 생물막 연속회분식 반응조와 모래여과조간의 내부순환으로 TN의 제거효율이 약 14%증진되는 것으로 나타났으며 얻어진 질소제거효율 증진은 주로 모래여과조에서의 탈질에 의한 것으로 밝혀졌다. 또한 용해성 인의 경우 내부순환이 수행되지 않았을 시에는 유출수내 농도가 오히려 증가하였으나 내부순환시에는 약 57% 정도가 제거되는 것으로 나타남에 따라 반응물의 내부순환이 용해성 인의 제거효율 증진에도 기여함을 알 수 있었다. 시스템에서의 질소제거 양상을 분석해본 결과 최종 유출수내의 NH4-N은 부하량 60g/m3.d 수준에서 약 20mg/L 이하로 비교적 일정하였고 부하량이 100g/m3.d. 이상의 수준으로 상승함에도 80% 이상의 질소 제거효율을 보였다. 그러나 부하량 100g/m3.d 수준 이상에서부터 처리효율이 감소하는 것으로 나타나 외부탄소원이 전혀 사용되지 않는 운전조건에서의 질소의 적정 부하량은 약 100g/m3.d 정도인 것으로 판단되었다.

• 대한화학회지
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• 제26권3호
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• pp.160-164
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• 1982

단결정을 키우기에 적절한 용해도를 가진 $[U(PW_{11}O_{39})_2]^{10-}$의 구아니딘윰염을 합성하였다. 이 염 혹은 칼륨염을 사용하여 $[U(PW_{11}O_{39})_2]^{10-}$의 안정도를 용액의 pH의 함수로 조사하였으며, pH 3~7에서 안정함을 발견하였다. 이 영역에서 $PW_{11}O_{39}^{7-}$대 $U^{4+}$의 몰비가 2이상 되게 $PW_{11}O_{39}^{7-}$를 가하고 22.7kK band (${\varepsilon}$ 1030 M-1cm-1)띠의 세기를 측정함으로써 $U^{4+}$를 비색정량하는 방법을 개발하였다.$PW_{11}O_{39}^{7-}$ 를 사용하여 우라늄을 회수하는 방법을 개발하기 위해,$[U(PW_{11}O_{39})_2]^{10}$- 를 두 다른 방법으로 분해시켜 분리된$PW_{11}O_{39}^{7-}$ 를 정량하였다. $PW_{11}O_{39}^{7-}$의 회수율은 염기를 가해 분해시켰을 때 약 70%, $K_2S_2O_8$로 산화시켜 분해시켰을 때 약 80%이었다. 본 연구를 위해 $VOSO_4$를 이용한$PW_{11}O_{39}^{7-}$ 의 비색정량법도 개발하였다.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1210-1210
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• 2001

On farm analysis of protein, moisture and oil in cereals and oil seeds is quickly being adopted by Australian farmers. The benefits of being able to measure protein and oil in grains and oil seeds are several : $\square$ Optimize crop payments $\square$ Monitor effects of fertilization $\square$ Blend on farm to meet market requirements $\square$ Off farm marketing - sell crop with load by load analysis However farmers are not NIR spectroscopists and the process of calibrating instruments has to the duty of the supplier. With the potential number of On Farm analyser being in the thousands, then the task of calibrating each instrument would be impossible, let alone the problems encountered with updating calibrations from season to season. As such, NIR technology Australia has developed a mechanism for \ulcorner\ulcorner\ulcorner their range of Cropscan 2000G NIR analysers so that a single calibration can be transferred from the master instrument to every slave instrument. Whole grain analysis has been developed over the last 10 years using Near Infrared Transmission through a sample of grain with a pathlength varying from 5-30mm. A continuous spectrum from 800-1100nm is the optimal wavelength coverage fro these applications and a grating based spectrophotometer has proven to provide the best means of producing this spectrum. The most important aspect of standardizing NIB instruments is to duplicate the spectral information. The task is to align spectrum from the slave instruments to the master instrument in terms of wavelength positioning and then to adjust the spectral response at each wavelength in order that the slave instruments mimic the master instrument. The Cropscan 2000G and 2000B Whole Grain Analyser use flat field spectrographs to produce a spectrum from 720-1100nm and a silicon photodiode array detector to collect the spectrum at approximately 10nm intervals. The concave holographic gratings used in the flat field spectrographs are produced by a process of photo lithography. As such each grating is an exact replica of the original. To align wavelengths in these instruments, NIR wheat sample scanned on the master and the slave instruments provides three check points in the spectrum to make a more exact alignment. Once the wavelengths are matched then many samples of wheat, approximately 10, exhibiting absorbances from 2 to 4.5 Abu, are scanned on the master and then on each slave. Using a simple linear regression technique, a slope and bias adjustment is made for each pixel of the detector. This process corrects the spectral response at each wavelength so that the slave instruments produce the same spectra as the master instrument. It is important to use as broad a range of absorbances in the samples so that a good slope and bias estimate can be calculated. These Slope and Bias (S'||'&'||'B) factors are then downloaded into the slave instruments. Calibrations developed on the master instrument can then be downloaded onto the slave instruments and perform similarly to the master instrument. The data shown in this paper illustrates the process of calculating these S'||'&'||'B factors and the transfer of calibrations for wheat, barley and sorghum between several instruments.

• 한국수소및신에너지학회논문집
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• 제28권4호
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• pp.377-383
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• 2017

This paper presents the performance characteristics of a 1 kW solid oxide fuel cell (SOFC) stack under various internal reforming and fuel utilization conditions. The Research Institute of Industrial Science & Technology (RIST) developed the 9-cell stack using a $20{\times}20cm^2$ anode supported planar cell with an active area of $324cm^2$. In this work, current-voltage characteristic test, fuel utilization test, continuous operation, and internal reforming test were carried out sequentially for 765 hours at a furnace temperature of $700^{\circ}C$. The influence of fuel utilization and internal reforming on the stack performance was analyzed. When the 1 kW stack was tested at a current of 145.8 A with a corresponding fuel utilization of 50-70% (internal reforming of 50%) and air utilization of 27%, the stack power was approximately 1.062-1.079 kW. Under continuous operation conditions, performance degradation rate was 2.16%/kh for 664 hours. The internal reforming characteristics of the stack were measured at a current of 145.8. A with a corresponding fuel utilization of 60-75%(internal reforming of 50-80%) and air utilization of 27%. As fuel utilization and internal reforming ratio increased, the stack power was decreased. The stack power change due to the internal reforming ratio difference was decreased with increasing fuel utilization.

• 대한토목학회논문집
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• 제36권1호
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• pp.105-114
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• 2016

수도권에는 1일 약 2000만 건의 대중교통카드 전수자료가 생성되고 있으며, 이 자료를 이용하여 시설운영 및 정책방안을 개선하고 도출하려는 시도가 다양해지고 있다. 본 연구는 교통카드에서 생성되는 동적인 수요변화의 예측 가능성을 모형화하는 시도로서 동적 통행수요배정모형을 구축하는 것이 목적이다. 버스의 경우 승객 이동상황이 카드태그(tag)를 통해 비교적 정확하게 파악되므로, 본 연구에서는 버스를 제외한 수도권 도시철도에 대해, 7개 운송기관이 운영하는 노선을 대상으로 적용되는 모형 및 알고리즘을 구축하였다. 구축된 모형은 교통카드자료의 Big Data 속성에 적합하게 연속 시간형 모형으로 구축되었으며, 승객의 경로선택행태를 효과적으로 나타내기 위하여 환승 횟수 증가에 따른 인지파라메타를 구성하였다. 수도권 도시철도 약 800만 쌍에 대하여 모델링한 결과, 연속형 시간기반 모형의 장점이 반영되어 어떤 시간 시점에서도 동적 수요를 분석할 수 있는 특성을 파악하였다. 특히 기존 철도운영기관의 목측조사자료와 비교한 혼잡도 변화를 파악할 때, 모형에서 도출된 혼잡도와 운영기관이 제시한 혼잡도 간에 유사한 추세를 보이고 있어 높은 신뢰도를 보여주고 있다. 본 연구는 철도기관에 한정한 모형으로 향후, 버스-도시철도와 통합된 모형체계 구축과 같은 연구가 필요할 것으로 파악된다.