• 제목/요약/키워드: appearance properties

검색결과 840건 처리시간 0.022초

Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups

  • Denisenko, Yu.G.;Aleksandrovsky, A.S.;Atuchin, V.V.;Krylov, A.S.;Molokeev, M.S.;Oreshonkov, A.S.;Shestakov, N.P.;Andreev, O.V.
    • Journal of Industrial and Engineering Chemistry
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    • 제68권
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    • pp.109-116
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    • 2018
  • $Eu_2(SO_4)_3$ was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group C2/c. In the air environment, $Eu_2(SO_4)_3$ is stable up to $670^{\circ}C$. The sample of $Eu_2(SO_4)_3$ was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of $SO_4$ tetrahedra results in the appearance of the IR inactive ${\nu}_1$ mode around $1000cm^{-1}$ and ${\nu}_2$ modes below $500cm^{-1}$. The band intensities redistribution in the luminescent spectra of $Eu^{3+}$ ions is analyzed in terms of the peculiarities of its local environment.

Langmuir-Blodgett Films of Perfluoroalkyl Monomaleate Copolymers on Porous Substrate

  • Hyein Jeong;Burm-Jong Lee;Young-Soo Kwon
    • Bulletin of the Korean Chemical Society
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    • 제15권8호
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    • pp.650-654
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    • 1994
  • Stable polyion-complexed polymeric monolayers were prepared by spreading perfluoroalkyl monomaleate copolymers, $C_2F_8MA-VE_2$ and $C_2F_8MA-VE_3$, on a aqueous poly(allylamine) subphase. The monolayer properties have been studied by the surface pressure-area (${\pi}$-A) isotherms. The $C_2F_8MA-VE_3$ containing longer oligoethyleneglycol pendant showed more expanded monolayer phase than the $C_2F_8MA-VE_2$. The polyion-complexed monolayers were transferable on various substrates, and the resulting Langmuir-Blodgett (LB) films were characterized by FT-IR spectroscopy and scanning electron microscopy (SEM). Two-dimensional crosslinking to form a polymer network was achieved by amide formation through heat treatment under vacuum with concurrent removal of perfluoroalkyl tails. SEM observation of this film on a porous membrane filter showed that the four layer film was sufficiently stable to cover the filter pore size of 0.1 ${\mu}$m. The $C_2F_8MA-VE_3$ revealed better covering capability than the $C_2F_8MA-VE_2$. Immersion of this film in water or in benzene did not cause any change in its appearance and in Fl-IR spectra.

자동차 선도장용 베이스코트에서 알루미늄 입자 크기와 형태에 따른 물성 연구 (A Study on Properties with Particle Size and Type of Aluninum in Pre-painted Basecoat of Automotive)

  • 이재우;이미춘;조을룡
    • Elastomers and Composites
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    • 제49권2호
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    • pp.160-166
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    • 2014
  • 자동차 선도장용으로 알루미늄 페이스트를 사용하여 6가지 베이스코트용 포뮬레이션이 설계되었다. 알루미늄 페이스트는 pancake 형태의 금속 안료인 #501, #801, #601와 cornflake 형태의 금속 안료인 #750, #770, #790가 사용되었다. 베이스코트의 상대적인 경화 밀도는 #501, #801, #601, #750, #770, #790 순으로 증가하였다. T-bending, 내충격성, 테이핑 부착력은 경화 밀도의 증가에 따라 향상되었다. Cornflake 형태의 안료에 대한 외관(combined factor) 테스트에서 입자가 가장 작은 #790이 다른 두 가지(#750, #770)와 비교하였을 때 가장 좋은 combined factor를 보여 주었다.

사이클로스포린을 함유한 고형 지질미립구의 제조와 평가 (Preparation and Evaluation of Solid lipid Microspheres Containing Cyclosporine A)

  • 양수근;박준상;최영욱
    • 약학회지
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    • 제39권5호
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    • pp.487-494
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    • 1995
  • Solid lipid microspheres (SLMs) were prepared using various lipids and solidifying agents, in order to enhance the gastrointestinal absorption of Cyclosporine A (Cs A) which is a practically water-insoluble drug with low systemic bioavailability. Egg lecithin and HCO-60 (polyoxyethylated 60 mol, hydrogenated castor oil) were used as lipids. Stearic acid and stearyl alcohol were used as solidifying agents. Emulsion concentrates containing Cs A were prepared by mixing the melted lipid and solidifying agent with water, employing bile salts as a cosurfactant. SLMs were obtained by dispersing the warm emulsion concentrate in cold distilled water under mechanical stirring, followed by freeze drying. Physical characteristics of each SLM were investigated by particle size analysis, optical microscopy and scanning electron microscopy. Mean particle size of SLMs was in the range of 30 to 40.mu.m. The SLMs were in good appearance with spherical shape before freeze drying, but were deformed partially after freeze drying. Drug loading efficiencies of SLMs were observed as high as 80 to 90% in average. The systemic bioavailability of Cs A from different SLM formula was investigated in rats following oral administration. Cs A in whole blood was extracted and assayed by HPLC. SLMs revealed the higher bioavailabilities than the standard formula based on the marketed product. SLMs might have several advantages over standard formula for enhanced gastrointestinal absorption, controlled release properties, high loading capacity of the water-insoluble drug, and feasibility of solid dosage forms with better stability in storage.

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B20 결정구조와 MnGe와 MnSi의 전자구조 및 자기적 특성 (B20 Crystal Structure and Electromagnetic Property of MnGe and MnSi)

  • 정태성
    • 한국재료학회지
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    • 제29권8호
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    • pp.477-482
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    • 2019
  • The magnetic properties and electronic structures of the B20 crystal structure MnGe and MnSi were investigated using the density functional theory with local density approximation. The low symmetry of the B20 crystal structure plays a very important role to make electromagnetic characteristics of these materials. The important result of the calculations is that it can be observed the appearance of a pair of gaps in the density of states near the Fermi level in both compounds. These features are results from d-band splitting by the low symmetry of the crystal field from B20 crystal structure. It can be seen that there is half-metallic characteristics from the density of states in both compounds. The calculation shows that the value of magnetic moment of MnGe is 5 times bigger than that of MnSi even though they have same crystal structure. The electronic structures of paramagnetic case have a very narrow indirect gap just above the Fermi level in both compounds. These gaps acquire some significance in establishing the stability of the ferromagnetic states within the local density approximation. Calculation shows that the Mn 3d character dominates the density of states near the Fermi level in both materials.

Medical Image Watermarking Based on Visual Secret Sharing and Cellular Automata Transform for Copyright Protection

  • Fan, Tzuo-Yau;Chao, Her-Chang;Chieu, Bin-Chang
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제12권12호
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    • pp.6177-6200
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    • 2018
  • In order to achieve the goal of protecting medical images, some existing watermark techniques for medical image protection mainly focus on improving the invisibility and robustness properties of the method, in order to prevent unnecessary medical disputes. This paper proposes a novel copyright method for medical image protection based on visual secret sharing (VSS) and cellular automata transform (CAT). This method uses the protected medical image feature as well as VSS and a watermark to produce the ownership share image (OSI). The OSI is used for medical image verification and must be registered to a certified authority. In the watermark extraction process, the suspected medical image is used to generate a master share image (MSI). The watermark can be extracted by combining the MSI and the OSI. Different from other traditional methods, the proposed method does not need to modify the medical image in order to protect the copyright of the image. Moreover, the registered OSI used to verify the ownership and its appearance display meaningful information, facilitating image management. Finally, the results of the final experiment can prove the effectiveness of our method.

최적 유동시스템을 위한 실무금형교육 사례 연구 (Case Study of Practical Tool Training for Optimal Runner System)

  • 신주경
    • 실천공학교육논문지
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    • 제9권2호
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    • pp.119-124
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    • 2017
  • 사출성형 시 유압실린더의 힘으로 스크류가 앞으로 전진하는 동안, 금형의 러너시스템은 성형품 형상의 캐비티 내를 충진시키는 유로로 용융된 수지의 충진, 패킹과정에 관계되며, 이는 스프루(sprue), 러너(runner), 게이트(gate)에 의해서 성형품의 외관, 수지의 물성, 치수 정밀도 및 성형 사이클 등에 큰 영향을 준다. 러너, 게이트 설계가 잘못된 피드시스템은 다양한 성형불량을 일으키므로 이를 방지할 수 있는 최적의 러너밸런스를 유지하는 것이 중요하다. 사출금형을 제작하는 업체에서 응용할 수 있는 실무적인 금형기술 지식을 향상시키기 위해서 기술적인 애로분야에 대한 기술지도를 바탕으로 금형기술 과정의 훈련모델을 제시한다.

머위 분말 첨가 쌀쿠키의 항산화 활성 및 품질 특성 (Antioxidant Activities and Quality Characteristics of Rice Cookie with Added Butterbur (Petasites japonicus) Powder)

  • 최희원;심기현
    • 한국식품영양학회지
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    • 제34권1호
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    • pp.1-14
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    • 2021
  • This study evaluated the antioxidant activity and quality characteristics of rice cookie with added butterbur powder in a ratio of 0, 5, 10, 15, and 20% to confirm the possibility of butterbur as a functional food. The moisture content, spread factor, leavening rate, and hardness of rice cookies increased with an increase in the amount of butterbur powder; whereas a decrease in the pH and baking loss rate was observed. The L and b values decreased as the amount of butterbur powder increased, but the value was the lowest when 5% of butterbur powder was added. The sensory liking score showed the highest preference for 10% butterbur powder regarding appearance, flavor, taste, texture, and overall preference. In the principal component analysis (PCA), the addition of 10% butterbur powder positively affected the measure of food acceptance in terms of organoleptic properties of butterbur. Besides, as the amount of added butterbur powder increased, the antioxidant activity of rice cookies increased. Based on these results, it appears that the addition of butterbur powder to rice cookies in a 10% ratio can produce rice cookies with excellent antioxidant activity, overall quality, and high preference.

벽체 실물대부재실험을 통한 초 저수축 콘크리트의 균열제어 효과 분석 (Analysis of Crack Control Effect of Ultra-low Shrinkage Concrete through Wall Mock-up Test)

  • 서태석;이현승;김강민
    • 한국건축시공학회지
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    • 제22권1호
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    • pp.45-55
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    • 2022
  • 초 저수축 콘크리트는 콘크리트 구조물의 건조수축 균열을 극한으로 제어할 수 있기 때문에 콘크리트 구조물의 품질 및 외관 확보에 매우 효과적이다. 본 연구에서는 초 저수축 콘크리트의 상용화를 목적으로 실내실험을 통해 최적의 팽창재 및 수축저감제 투입량을 정하였고, 콘크리트 벽체 실물대부재실험을 실시하여 초 저수축 콘크리트의 수축 특성 및 균열제어 효과 등을 검토하였다. 그 결과 벽체 시험체에는 건조수축 변형이 거의 발생하지 않았고 균열도 발생하지 않음을 확인할 수 있었다.

비닐술폰형 반응성 염료를 이용한 오크 무늬목의 염색성 및 견뢰도 특성 (Dyeing and Fastness Properties of Oak Veneer Dyed with Vinyl Sulfone Type Reactive Dyes)

  • 조항성;심의진
    • 한국염색가공학회지
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    • 제34권4호
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    • pp.234-240
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    • 2022
  • Use of processed timber can help reduce environmental damage and the economic burden of resources (important problems with use of raw timber) and can meet the needs of various fields where the sensibility of raw timber is required. Veneer wood is positioned as a high-value-added product due to its luxury and beauty, and it is used in various fields as a building-related material, such as interior decoration, furniture, flooring, building interior materials, and lumber. Dyeing is necessary to enhance the aesthetic appearance of this pattern and to expand its use. Therefore, in this study, we compared and analyzed the dye ability of oak-patterned materials with reactive dyes, and evaluated their performance as interior materials. As a result, the oak pattern was dyed with 9 kinds of reactive dyes and a comparative analysis was performed. The most suitable conditions are 50℃, 2 hours, and 0.5% o.w.f. In addition, evaluating resilience to daylight, resilience to rubbing, fire resistance, and flame retardance, yielded results suitable for use as an interior material. In this study, the dyeability of veneer dyed under various conditions using reactive dyes was compared and analyzed the performance as an interior material was evaluated.