• Journal of the Korean institute of surface engineering
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• v.55 no.6
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• pp.425-432
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• 2022

Antifouling paints that inhibit the attachment and contamination of marine organisms mainly use TBT compounds, but because of their toxic components, they cause ecosystem disturbance and environmental destruction problems, so It is necessary to research eco-friendly antifouling paints that are easy to maintain and effective antifouling technologies. In this study, physical surface treatment of silane coating and chemical antifouling technology were applied to the metal surface to secure the stability of the surface of the marine structure and inhibit the attachment and growth of marine organisms. Adhesion of marine organisms was evaluated according to the coating conditions through surface evaluation of the charged material for 15 months in the waters of the west coast of Korea. In accordance with ASTM D6990-05, antifouling properties fouling rates (FR) and physical degradation rates(PDR) were evaluated through visual inspection of the evaluation specimens. As a result of evaluating the antifouling performance of the coated surface, it was confirmed that the antifouling performance was maintained at the 50% level even after 15 months in the sample subjected to physical processing and silane coating.

• Journal of the Korean Society of Visualization
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• v.11 no.2
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• pp.18-26
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• 2013

An accurate and reliable performance evaluation technique is indispensable for the development of marine antifouling coatings. The existing standard practice is however, based on the visual observation of biofouling settlement area, which is prone to the subjective judgment of the inspector. In spite of the above mentioned importance, a systematic and objective fouling evaluation technique has not yet been introduced. In this study, a novel quantitative antifouling performance evaluation method for marine antifouling paints is devised based on the image analysis of panel immersion test results. The present image analysis method is to quantify settlement area for each fouling category by distinctive color. The fouling categories are set as unfouled, biofilm, green algae, brown algae, calcareous animal and spongy animal with specific HSL (Hue, Saturation, Lightness) color ranges. In order to assess the effectiveness of the proposed method, static immersion tests for three antifouling coatings were undertaken for two years.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.5
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• pp.1-8
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• 2023

Marine and hydraulic structures are subject to durability damage not only due to the penetration of sea water but also due to the attachment of marine organisms. Therefore, in this study, we tried to develop an antifouling coating agent with self-cleaning function for marine concrete. It was confirmed that the antifouling coating agent mixed with AKD, cellulose nanofibers and BADGE had sufficient antifouling performance at a well hydrophobicity of around 140° in contact angle and an inclination angle of 15°. In the abrasion resistance test of the surface, only a maximum loss of 0.015 g occurred. In the durability test, as a result of the chloride ion permeation test, almost no chloride ion permeation occurred in the variable where the coating agent was applied, and carbonation and freeze-thaw damage also rarely occurred, so it was analyzed that it was effective in securing durability of concrete.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2013.06a
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• pp.134-135
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• 2013

In this study, the physical properties and antifouling were investigated to make the Marine growth antifouling coatings by blending of synthesized silicone resin and pigment with a low surface tension. To examine the film properties and foul release of the prepared coatings, film specimens were prepared with the prepared coatings and anti corrosion coatings. The test results showed that the silicone type antifouling coatings had very excellent antifouling properties rather than any other coatings because of the coating films had followed the low surface tension and elasticity, and prevention of adhesion for marine growth and mechanical adhesions.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.378-378
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• 2006

The preparation, characterization, and bio-testing of biocide incorporated silicone coatings for marine applications have been conducted. Derivatives of the biocide, Triclosan (5-chloro-2-(2, 4-dichlorophenoxy) phenol), were used to covalently attach the biocide moiety to a silicone backbone. The synthetic process allowed for control of the resulting coating's mechanical properties as well as antifouling/fouling release performance in laboratory and ocean site testing. The test results showed significantly reduce macro fouling with sustained fouling release characteristics for the coatings produced.

• Clean Technology
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• v.23 no.2
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• pp.148-157
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• 2017

To prepare UV-curable polyurethane-acrylate oligomer, NCO-terminated urethane prepolymers with trimethylolpropane, [TMP; 0 (0), 0.1 (0.021) and 0.2 (0.043) mole (mole fraction)] as crosslinkable tri-functional chain extender were end-capped with pentaerythritol triacrylate [PETA; 2.0 (0.400), 1.7 (0.354) and 1.4 (0.304) mole (mole fraction)] with one hydroxyl group/three vinyl functionalities. The stable as-formulated UV-curable polyurethane-acrylates [stable mixtures of PETA-capped oligomer/reactive acrylic monomer diluents without/with heptadecafluorodecyl methacrylate (PFA; 0, 6 and 9 wt%)] were formed up to 0.2 (0.043) mole (mole fraction) of TMP content in the prepolymer, while homogeneous-mixing failed at 0.3 (0.068) mole (mole fraction), in which the crosslink density in NCO-terminated urethane prepolymer was too high to enable the formation of stable mixture. This study examined the effect of TMP/PETA molar ratio and heptadecafluorodecyl methacrylate (PFA) content (wt%) on the properties of UV-cured polyurethane-acrylates as marine antifouling coating materials. The properties of UV-cured polyurethane-acrylate were found to be significantly dependent on the crosslinkable TMP/PETA ratio and PFA content. With the increasing of the TMP and PFA contents, the contact angles increased, and consequently the surface tension decreased. The adhesion of algae/barnacles to PFA contained film samples were found to be sufficiently weak to allow their easy removal. These results suggest that the UV-cured samples containing PFA have strong potential as coating materials for antifouling applications.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.3
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• pp.137-142
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• 2021

In this study, the development of the room temperature curable silica-based coating compositions for anticorrosive and antifouling performance in marine environments was carried out. The marine (plant) structures with many exposed parts are operated in harsh marine environments such as strong ultraviolet rays, extreme temperature differences and salt water corrosion. Organic paints that are easily degraded under these environments and easily eroded by physical stimuli such as waves can not play a role properly. Dense ceramic coatings on marine structures provide careful protections even in saltwater environments due to their high hardness and rust resistance. Therefore, in the case of ceramic coatings, their use and application range in marine structures can be greatly improved due to their functional advantages. In the present study, silica-based coating compositions based on colloidal silica with silane coupling agents, curing salts, and ceramic fillers were developed, and their applications as protective coatings for corrosion protection and fouling prevention in seawater were also studied.

• Journal of Environmental Health Sciences
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• v.29 no.3
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• pp.1-8
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• 2003

The development of environmentally nontoxic or non-polluting antifouling additives that can be formulated in practical coating requires assay involving target organisms. Described here are the simple laboratory assays that have been developed using the barnacle, Balanus amphitrite, a common fouling organism found throughout temperate and tropical seas. One of the assays depends on synchronous year-round mass culture, the procedure for which is described, of nauplii larvae and cyprids larvae. The laboratory assays provided quantitative estimates of toxicity and settlement inhibition of the test compounds. Laurinterol (1), isolaurinterol (2), alpysinal (3), and aplysin (4) have been isolated from the Korean red alga Laurencia okamurae. Their structures were identified by spectral data in comparison with the literature data. Compounds 1-4 inhibited larval settlement of the barnacle B. amphitrite with EC$_{50}$ values of 0.18- 36 $\mu\textrm{g}$/ml. Com-pounds 2-4 showed larval toxicity against nauplii of the barnacle B. amphitrite with 5-10 $\mu\textrm{g}$/ml, while laurinterol (1) exhibited no toxicity at even 100 $\mu\textrm{g}$/ml. Therefore, laurinterol was expected as a promising natural antifoulant.t.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.2
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• pp.120-129
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• 2023

Marine structures are subject to damage not only from sea salt but also from the adhesion of marine microorganisms and suspended particles, which cause additional damages. In order to prevent this, periodic coating is employed in the case of vessels to maintain the necessary performance. However, it is true that periodic coating is difficult for concrete or steel support structures, and there is a risk of marine environmental pollution. In this study, authors developed an anti-fouling coating agent using eco-friendly materials that possess hydrophilic cellulose nanofibers and AKD(alkyl ketene dimer). To achieve a homogeneous mixture, the content of cellulose nanofibers was fixed at 1 %, and AKD, distilled water, and waste glass were mixed using a digital mixer and homogenizer. The contact angle of the prepared coated surface was observed to be over 130°, indicating sufficient performance even in a water droplet flow test with a 15° slope, suggesting self-cleaning capability. Furthermore, through the analysis of viscosity characteristics at different temperatures, it was confirmed that the application is feasible at room temperature. Microstructure analysis also verified that the coating agent is uniformly applied to the concrete surface.

• Journal of the Society of Naval Architects of Korea
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• v.50 no.6
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• pp.399-406
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• 2013

In the present study, the flat plate model test method is developed to evaluate the skin friction of the marine coating in the cavitation tunnel. Six-component force balance is used to measure the profile drag of the flat plate and strut. LDV(laser Doppler velocimetry) technique is also employed to evaluate the drag and to figure out the reason of the drag reduction. The flow velocities above the surface can be used to assess the skin friction, combined with direct force measurement. Since the vortical structure in the coherent turbulence structure influences on the skin friction in the high Reynolds number regime, the interaction between the turbulence structure and the surface wall is paying more attention. This sort of thing is important in the passive control of the turbulent boundary layer because the skin friction can't be determined only by wall condition. As complicated flow phenomena exist around a paint film, systematic measurement and analysis are necessary to evaluate the skin friction appropriately.