• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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• pp.80-81
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• 2017

The study conducted a thermal conductivity test of magnesium oxide to manufacture boards using absorbent to produce board of radon gas molecules that are absorbed into the indoor air pollutants, which are currently in question, among other indoor air pollutants. Using material are the vermiculite and anthracite, in case of the vermiculite, which results in large porosity due to the expansion, in case of the anthracite, which characteristic generates pore on the matrix. As a result of the experiment, the lowest value was given to 0.6161 kcal/mh℃ which adding vermiculite 10% and anthracite 40%. However, adding vermiculite 40% and anthracite 10%, slightly higher 0.7229 kcal/mh℃, it is deemed the anthracite has more porosity than the vermiculite and, it judged that pore occurrence during the mixing process, appeared that the heat conductivity go down.

• 대한환경공학회지
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• 제22권3호
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• pp.557-564
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• 2000

본 연구에서는 수용액 중의 유독성 유해물질로 미량으로 존재하여도 치명적 독성을 가진 난용성 유기오염물(sparingly soluble organic compounds, SSOCs)의 제거를 위한 흡착제 개발을 목표로 양이온 계면활성제(cetyltrimetylammonium bromide, CTAB)로 표면 개질된 organo-anthracite의 유기화합물 제거능을 조사하고, 흡착 특성을 분배계수 (partition coefficient, $K_d$) 로 평가함으로써 organo-anthracite의 유기물질 흡착메카니즘을 규명하고자 히였다. Organo-anthracite는 CTAB가 흡착됨에 따라 전 pH 범위에서 표면전위가 양의 값으로 상닫히 증가되었으며, 또한 표면의 소수성이 증가되어 표면전하가 pH에 비의존적으로 나타났다. pH 2~10의 용액을 탈리액으로 하여 organo-anthracite의 탈착성을 실험한 결과 0% 의 탈착율을 나타내어 전 pH 범위에서 안정함을 알 수 있었고, 이를 이용한 제거실험에서 츠기 농도 $6{\times}10^{-4}M$인 클로로포름과 벤젠이 전 pH범위에서 95% 이상 제거되었다. Organo-anthracite와 유기화합물간의 분배계수 $K_d$값은 실측치가 이론치보다 4~25배의 높은 값으로 나타났다. 이는 다른 흡착제에 비해 organo-anthracite내에서 SSOCs의 분배가 더 쉽게 이루어짐을 의미한다. 따라서, 유독성 유기오염물질을 포함하는 폐수의 처리시 흡착제로써 이용이 가능하며 또한 organo-anthracite를 매립지의 차수막으로 이용시 유독성 유기 오염물질의 이동을 보다 효과적으로 지연시킬 수 있을 것으로 사료된다.

• 한국환경보건학회지
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• 제22권3호
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• pp.28-36
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• 1996

The objects of this study were to investigate emissions of air pollutant the particles as well as the combustibility of the low grade domestic anthracite coal and imported high-calorific bituminous coal in the fluidized bed coal combustor. The production of air pollution from anthracite-bituminous coal blend combustion in a fluidized bed coal combustor was evaluated. The effects of air velocity and anthracite fraction on the reaching time of steady state condition was also evaluated. We used coal samples the domestic low grade anthracite coal with heating value of 2,010 kcal/kg and the imported high grade bituminous coal with heating value of 6,520 kcal/kg. The experimental results are presented as follows. The time of reaching to steady state was affected by the temperature variation. The steady state time was about 120 minute at 0.3 m/s which was the fastest. It has been found that $O_2$ and $CO_2$ concentration were reached steady state at about 100 minute. As the height of fluidized bed becomes higher, the concentration s of $SO_2$ and $NO_x$ mainly increased. The concentration of freeboard was the highest and emission concentration was diminished. Also, as anthracite fraction increased, the emission of $SO_x$ concentration was increased. But, it has been found that the variation of $NO_x$ concentration with anthracite fraction was negligible and the difference of emission concentration according to air flow rates was negligible, too. It has been found that $O_2$ concentration decreased and $CO_2$ concentration increased as the height of fluidized bed increased. As anthracite fraction increased, the mass of elutriation particles increased, and $CO_2$ concentration decreased. Also, as air velocity increased, $O_2$ concentration decreased and $CO_2$ concentration increased. Regardless-of anthracite fraction and flow rate, the combustible weight percentage in elutriation particles were high in the case of fine particles.

• 한국환경과학회지
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• 제6권3호
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• pp.267-276
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• 1997

It has been studded that combustion and the production of air pollution of anthracite - bituminous coal blend In a fluidized bed coal combustor, The objects of thIns study were to investigate mixing characteristics of the particles as well as the combustibility of the low grade domestic anthracite coal and Imported h19h calorific bltununous coal in the fluidized bed coal combustor. They were used as coal samples ; the domestic low grade anthracite coal with heating value of 2,010kca1/kg and the Imported high grade bituminous coal with beating value of 6,520kca1/kg. Also, the effects of air flow rate and anthracite fraction on the reaching time of steady state condition have been studied. The experimental results are presented as follows. The time of reaching to steady state was affected by the temperature variation. The steady state time was about 120 minute at 300sc1h which was the fastest. It has been found that $O^2$ and $CO^2$ concentration were reached steady state at about 100 minute. It has been found that $O^2$ concentration decreased and $CO^2$ concentration increased as the height of fluidlzed bed Increased. It was found that splash zone was mainly located from 25cm to 35cm above distributor. Also, as anthracite traction Increased, the mass of elutrlatlon particles Increased, and $CO^2$ concentration decreased. As gk flow rate Increased,$O^2$ concentration decreased and $CO^2$ concentration increased. Regardless of anthracite fraction and flow rate, the uncombustible weight percentage according to average diameter of elutriation particles were approldmately high In the case of One Particles. As anthracite traction and k now rate Increased, elutriation ratio Increased. As anthracite fraction was increased, exit combustible content over feeding combustible content was Increased. Regardless of anthracite fraction, size distribution of Ued material from discharge was almost constant. Over bed temperature 85$0^{\circ}C$ and excess air 20% , the difference of combution efficiencies were little. It is estimate that the combustion condition In anthracite-bituminous coal blend combustion is suitable at the velocity 0.3m/s, bed temperature 85$0^{\circ}C$, the excess air 20%.

• 한국기후변화학회지
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• 제4권1호
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• pp.27-39
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• 2013

본 연구에서는 국내에서 사용되는 무연탄을 국내무연탄, 원료용 수입무연탄, 연료용 수입무연탄으로 분류하여 각각의 발열량 및 온실가스 배출계수를 산정하였다. 본 연구에서 산정된 온실가스 배출계수는 국내무연탄이 $111,477{\pm}4,508kg\;CO_2/TJ$, 원료용 수입무연탄이 $108,358{\pm}4,033kg\;CO_2/TJ$, 연료용 수입무연탄이 $103,927{\pm}8,367kg\;CO_2/TJ$로 산정되었다. 산정된 배출계수를 이용한 온실가스 배출량은 $6,216,942ton\;CO_2$로 무연탄을 상세히 구분하지 않고 산정한 온실가스 배출량보다 12.7% 적게 나타났다. 이에 따라, 무연탄을 상세히 분류하여 활동자료를 수집하는 것이 무연탄의 활동자료를 통합하여 수집하는 것보다 정확한 온실가스 배출량을 산정할 수 있다고 판단된다. 또한, 국내에서 사용되고 있는 무연탄의 경우 IPCC에서 제시하고 있는 무연탄과 특성이 다르기 때문에 국가 온실가스 인벤토리 향상을 위해 무연탄을 용도별로 분류하여 산정해야 한다.

• 한국연소학회지
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• 제10권3호
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• pp.1-9
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• 2005

The characteristics of co-combustion of Korean anthracite and bituminous coal was determined in a TGA and a lab-scale CFB reactor. The combustion reactivity of Korean anthracite (E = 51.2 kcal/mol) was much lower than that of bituminous coal (E = 14.5 kcal/mol). As the addition amount of the bituminous coal into the anthracite was increased, the reactivity of the anthracite was found to be improved. The effluent rate of the emission gases from the CFB reactor was not changed appreciably when each coal burned. As the bituminous coal was added, however, the effluent rate of the emissions was increased. The unburned carbon in fly ash from the CFB reactor was decreased with increasing the ratio of bituminous coal in co-combustion. But as the ratio of the bituminous coal was larger than 40 %, the combustion reactivity was not increased any more.

• KDI Journal of Economic Policy
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• 제37권2호
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• pp.40-63
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• 2015

Anthracite exports have special value within the DPRK's economy. In this paper, we focus on what determines the DPRK's anthracite exports to China. We use panel data consisting of cross-section data from 30 provinces in China and quarterly time-series data from 1998 to 2013. Controlling for all other variables that affect anthracite imports, the variable for steel production in China is robust and statistically significant. This is consistent with on-site interviews which indicate that much of North Korean anthracite is consumed by China's steel industry. This implies that the North Korean authorities need to make adjustments to the foreign trade structure, as the import demand for anthracite in China may decline further.

• 대한화학회지
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• 제19권4호
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• pp.252-257
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• 1975

無煙炭 炭分을 肥料로서 利用하기 爲하여 硏究를 하였다. 無煙炭 炭粉은 2% 시트르산 溶液中에서는 可溶物質이 大端히 적으나 ?燒된 dolomite를 添加한 無煙炭炭粉은 마그네슘, 칼슘, 황, 無水珪酸 等의 拘溶性 可溶分이 많아 지므로 肥料로서의 效果가 있음을 알았다.

• 대한화학회지
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• 제19권3호
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• pp.193-197
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• 1975

無煙炭의 燃燒에 있어서 $SO_2 가스의 發生을 抑制하기 위하여 小量의 알칼리 혹은 알칼리 土金屬의 水酸化物을 添加 시키는 것이 效果的이라는 것을 알았다. 그것은 燃燒時에 無煙炭中의 黃分의 大部分이 黃化物 혹은 黃酸鹽의 形態로 炭分中에 固着되기 때문이라고 생각된다. $1000^{\circ}C$로 加熱할 때는 添加劑를 가한 無煙炭中의 黃分의 약 20%가 SO_2$ 가스로 發生한다.

• 자원리싸이클링
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• 제13권2호
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• pp.16-23
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• 2004

무연탄 석탄회의 재활용 향상을 위하여, 무연탄 석탄회의 특성을 유연탄 석탄회의 특성과 비교하였다. 특히, 무연탄 석탄회를 소성블릭의 원료로 활용하기 위하여, 무연탄 석탄회의 고온 특성이 열분석, 고온현미경 및 X선 회절 분석에 의해 조사되었다. 무연탄석탄회의 $A1_2$$O_3$/SiO$_2$ 비는 평균 0.62이고 유연탄 석탄회는 $A1_2$$O_3$/$SiO_2$ 비가 0.34로 무연탄 석탄회 중 A1$_2$$O_3$ 성분의 조성이 높았다. 무연탄 석탄회 중 $SiO_2$는 석탄회 중의 $A1_2$$O_3$와 반응하여 $1000^{\circ}C$의 고온에서 새로운 뮬라이트 결정을 형성하였고, 그 결과 우수한 내화도를 나타내었다. 또한, 무연탄 석탄회의 첨가량 변화에 따른 혼합시료의 압출 성형 특성을 평가하기 위하여 고령토와의 혼합시료가 제조되었고, 무연탄 석탄회 첨가 성형 벽돌의 압출속도는 혼합시료 중 석탄회의 첨가량이 증가할수록 감소하였으며, 압출 성형가능한 무연탄 석탄회의 최대 첨가량은 60wt%이었다.