• Title/Summary/Keyword: anthracene

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Monitoring of Polycyclic Aromatic Hydrocarbons in Sediments and Organisms from Korean Coast

  • Moon Hyo-Bang;Choi Hee-Gu;Kim Sang-Soo;Jeong Seung-Ryul;Lee Pil-Yong;Ok Gon
    • Fisheries and Aquatic Sciences
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    • v.4 no.4
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    • pp.219-228
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    • 2001
  • Surface sediments (0- 5 cm), mussels (Mytilus coruscus and M. edulis) and oysters (Crassostrea gigas) were sampled at 20 stations in Korean coast during a period of February to July 2000. Samples were analyzed for polycyclic aromatic hydrocarbons (PAHs) content using gas chromatography coupled to mass spectrometer detector (GC/MSD). The sediment $\sum PAH$ concentration varied from 7 to 1,214 ng/g dry weight and the level of carcinogenic PAHs of six species ranged from 1 to 563 ng/g dry weight in surface sediments. In organisms, the levels of $\sum PAH$ were in the range of 63-876 ng/g dry weight and the concentrations of carcinogenic PAHs of six species were in the range of 4-582 ng/g dry weight. The highest PAH concentrations in sediments and organisms were in samples from Station 5 in Pohang coast and Station 8 in Jinhae coast, respectively. $\sum PAH$ concentrations in sediments and organisms collected from Korean coast were slightly low or comparable to those in other countries. The contribution of ring aromatic groups to sum of 16 PAHs in sediments and organisms showed a similar pattern for most stations. In sediments, the predominant contributions were four and five ring aromatics like fluoranthene, pyrene, benzo[a]anthracene, chrysene, benzo[b]fluoranthene, benzo[k]fluoranthene and benzo[a]pyrene. In the organisms, four ring aromatics like fluoranthene, pyrene, benzo[a]anthracene and chrysene were predominant PAH species. Several molecular indices such as phenanthrene/anthracene, fluoranthene/pyrene and LMW/HMW ratio were used to identify the origin of PAH contamination in sediments. The results indicate that PAHs of Korean coast were mainly of pyro1ytic contaminants with slight petrogenic input. A high correlation within individual PAH compound in marine sediments was observed, while correlation in organisms showed a highly significant relationship for heavier molecular weight PAHs.

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Sources Apportionment Estimation of Ambient PM2.5 and Identification of Combustion Sources by Using Concentration Ratios of PAHs (대기 중 PM2.5의 오염기여도 추정 및 PAHs 농도비를 이용한 연소 오염원 확인)

  • Kim, Do-Kyun;Lee, Tae-Jung;Kim, Seong-Cheon;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.5
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    • pp.538-555
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    • 2012
  • The purpose of this study was to understand $PM_{2.5}$ chemical characteristics on the Suwon/Yongin area and further to quantitatively estimate $PM_{2.5}$ source contributions. The $PM_{2.5}$ sampling was carried out by a high-volume air sampler at the Kyung Hee University-Global Campus from November, 2010 to October, 2011. The 40 chemical species were then analyzed by using ICP-AES(Ag, Ba, Cr, Cu, Fe, Mn, Ni, Pb, Si, Ti, V and Zn), IC ($Na^+$, $K^+$, $NH_4{^+}$, $Mg^{2+}$, $Ca^{2+}$, $NO_3{^-}$, ${SO_4}^{2-}$ and $Cl^-$), DRI/OGC (OC1, OC2, OC3, OC4, OP, EC1, EC2 and EC3) and GC-FID (acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[a] pyrene, indeno[1,2,3-cd] pyrene, benzo[g,h,i]perylene and dibenzo[a,h,]anthracene). When applying PMF model after performing proper data treatment, a total of 10 sources was identified and their contributions were quantitatively estimated. The average contribution to $PM_{2.5}$ emitted from each source was determined as follows; 26.3% from secondary aerosol source, 15.5% from soil and road dust emission, 15.3% from vehicle emission, 15.3% from illegal biomass burning, 12.2% from incineration, 7.2% from oil combustion source, 4.9% from industrial related source, and finally 3.2% from coal combustion source. In this study we used the ratios of PAHs concentration as markers to double check whether the sources were reasonably classified or not. Finally we provided basic information on the major $PM_{2.5}$ sources in order to improve the air quality in the study area.

Enhancement of Glucose Oxidation Reaction in Enzyme Biofuel Cell Utilizing Anthracene Dicarboxyl acid Cross-linker (Anthracene dicarboxyl acid 가교제를 활용한 효소연료전지의 산화극의 포도당 산화반응 향상)

  • Hyun, Kyuhwan;Ji, Jungyeon;Kwon, Yongchai
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.1-4
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    • 2019
  • In this study, an anthracene cross-linker is introduced to enhance the catalytic activity of glucose oxidase (GOx) based catalysts and to increase the amount of enzyme loading. The crosslinked GOx is bonded with the CNT/PEI support using the electrostatic interaction (AC[CNT/PEI/GOx]). Electrochemical evaluations are done to evaluate the performance of this catalyst and the performance of CNT/PEI/GOx catalyst is also measured as a control. According to the measurements, it is confirmed that the amount of loaded GOx increases, while $K_m$ value calculated by Lineweaver-Burk plot shows that AC[CNT/PEI/GOx] ($K_m$ : 0.73 mM) is superior to CNT/PEI/GOx ($K_m$ : 1.71 mM) without cross-linking reaction. Based on these effects, it is demonstrated that the maximum power density of the enzymatic biofuel cell using AC[CNT/PEI/GOx] increases from $21.2{\mu}W/cm^2$ to $57.4{\mu}W/cm^2$.

이액상 시스템에서 토양으로부터 비수용성 액체로의 PAHs의 이동특성

  • 양지원;이재영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.247-249
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    • 2002
  • The transfer behaviors of three Polyarmatic hydrocarbons (PAHs) from soil to non-aqueous phase liquid (NAPL) were investigated. The three different PAHs were phenanthrene, anthracene, and pyrene. The used NAPLs were silicone oil and paraffine oil. The percentage of the remained PAHs into soil were similar without the relation to kinds of NAPLs. And the transfer of PAHs into NAPLs was fastened until 1 day as the increase of mixing rate but in the case of 450 rpm, the remained PAHs into soil was increased after 1 day because NAPLs was emulsified.

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Stereochemical Induction in the Generation of 1-Chloro-1-phenyl-2-neopentylsilene

  • Bok Ryul Yoo;Il Nam Jung;Myong Euy Lee;Chang Hwan Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.517-520
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    • 1991
  • The reaction of dichlorophenylvinylsilane with tert-butyllithium in hydrocarbon solvents at room temperature or below generated the Z and E-isomers of 1-chloro-1-phenyl-2-neopentylsilene. The intermediates were trapped by cyclopentadiene, anthracene and methoxytrimethylsilane to give a consistent 90/10 ratio for the Z-silene to E-silene adduct. This result was interpreted as an evidence for stereochemical induction in the silene generation reaction.