• Korean Chemical Engineering Research
• /
• 제44권5호
• /
• pp.528-534
• /
• 2006

고온 플라즈마가 적용된 플라즈마트론을 이용하여 바이오가스 개질을 통해 수소를 생산하는데 있어서 최적 운전 조건에 대해 연구하였다. 음식물 쓰레기의 혐기성 발효조에서 생성된 바이오가스 구성비($CH_4/CO_2$)가 1.03, 1.28, 2.12인 바이오가스로 개질실험을 수행하고, 수소 생산과 메탄 전환율을 향상시키기 위해 바이오가스 유량비, 수증기 유량비, 입력전력 변화와 같은 변수별 연구를 수행하였다. 바이오가스 유량비(biogas/TFR : total flow rate), 수증기 유량비($H_2O/TFR$: total flow rate), 입력전력이 각각 0.32~0.37, 0.36~0.42, 8 kW일 때 메탄의 전환율이 81.3~89.6％인 최적운전조건을 보였다. 이때 합성가스 중의 수소와 일산화탄소의 농도는 27.11~40.23％, 14.31~18.61％이며, 수소 수율은 40.6~61％, 에너지 전환율은 30.5~54.4％, $H_2/CO$ 비는 1.89~2.16이다.

• 대한기계학회논문집B
• /
• 제33권11호
• /
• pp.869-875
• /
• 2009

The purpose of this paper is to investigate the optimal condition of the syngas production by reforming of propane using Gliding arc plasma reformer. The gliding arc plasma reformer in 3 phases has been newly designed and developed with a quick starting and fast response time. It can be applicable to the various types of fuels (Hydrocarbons $C_xH_y$), and it has a high conversion rate of fuels and high production of hydrogen. The parametric screening studies were carried out according to the changes of a steam feed amount i.e., steam/carbon ratio, total gas flow rate and input electric power. The optimum operating conditions were S/C ratio 2.8, total gas flow rate of 14 L/min and input electric power of 2.4 kW. The result of optimum operating conditions showed the 55 % $H_2$, 14 % CO, 15 % $CO_2$, 10 % $C_3H_8$ and 4 % $CH_4$. Also, $C_3H_8$ conversion, $H_2$ yield and $H_2$ selectivity were 90 %, 42 %, 15 %, respectively. The energy efficiency and specific energy requirements were 37 % and 334 kJ/mol respectively.

• 농업과학연구
• /
• 제42권1호
• /
• pp.23-27
• /
• 2015

The study was conducted to determine the effect of corssbred Korean native chickens (CKNC) on growth performance indices for hatch to 28 days. A total of 192 1-day-old birds were divided into one of 4 CKNC groups by 5 Korean native pure strains. Diets used in the study consisted of 2 phases with corn and soybean meal basis as earlier (1~2 weeks; crude protein 18.5%, metabolizable energy 3,000 kcal/kg), and grower (2~4 weeks; crude protein 15.0%, Metabolizable Energy 2,850 kcal/kg). Body weight and feed intake were measured bi-weekly. Crossbred 1G (group of family line) had higher body weight and average daily gain whereas crossbred 5Y had greater average daily feed intake and feed conversion ratio than other crossbred Korean native chicken for hatch to 28 days. The results in the current study indicated that crossbred 1G had higher growth performance indices compared with other crossbred Korean native chicken for hatch to 28 days.

• Current Photovoltaic Research
• /
• 제11권3호
• /
• pp.67-74
• /
• 2023

The earth-abundant element-based Cu₂ZnSn(S,Se)₄ (CZTSSe) thin film solar cells (TFSCs) have attracted greater attention in the photovoltaic (PV) community due to their rapid development in device power conversion efficiency (PCE) >13%. In the present work, we demonstrated the fine-tuning of the bandgap in the CZTSSe TFSCs by altering the sulfur (S) to the selenium (Se) chalcogenide ratio. To achieve this, the CZTSSe absorber layers are fabricated with different S/(S+Se) ratios from 0.02 to 0.08 of their weight percentage. Further compositional, morphological, and optoelectronic properties are studied using various characterization techniques. It is observed that the change in the S/(S+Se) ratios has minimal impact on the overall Cu/(Zn+Sn) composition ratio. In contrast, the S and Se content within the CZTSSe absorber layer gets altered with a change in the S/(S+Se) ratio. It also influences the overall absorber quality and gets worse at higher S/(S+Se). Furthermore, the device performance evaluated for similar CZTSSe TFSCs showed a linear increase and decrease in the open circuit voltage (V_oc) and short circuit current density (J_sc) of the device with an increasing S/(S+Se) ratio. The external quantum efficiency (EQE) measured also exhibited a linear blue shift in absorption edge, increasing the bandgap from 1.056 eV to 1.228 eV, respectively.

• 방사성폐기물학회지
• /
• 제4권2호
• /
• pp.153-159
• /
• 2006

우라늄 변환시설 가동 중 발생하여 라군(lagoon)에 저장중인 방사성 슬러지 폐기물에 대한 처리는 시설 해체과정에서 매우 중요한 업무 중 하나이다. 슬러지 구성성분 중 다량을 차지하는 질산암모늄의 폭발 위험성 등으로 인해 미생물을 이용한 질산염의 분해는 질산염을 안정적으로 처리할 수 있는 효과적인 방법이라 할 수 있다. 본 연구에서는 라군 슬러지의 약 60 wt%를 차지하는 질산염을 혐기성 균주의 하나인 Pseudomonas halodenidificans를 이용하여 탈질하기위한 공정 변수에 대한 영향을 평가하였다. 온도, 질산염 농도, 전자공여체의 영향, C/N 비율, 초기 접종하는 균주의 비율, pH등의 공정변수에 대하여 실험한 이번 결과는 향후 연속식 공정 설계를 위한 기초 자료로 사용될 것이다.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2002년도 하계학술대회 논문집 B
• /
• pp.1358-1360
• /
• 2002

This paper presents a modeling and simulation of a utility-connected wind energy conversion system with a link of a rectifier and an inverter. It discusses the maximum power control algorithm for the wind turbine and presents the relationship of wind turbine output, rotor speed, power coefficient, tip-speed ratio and wind speed when the wind turbine is operated under the maximum power control algorithm. The control objective is to extract maximum power from wind and transfer the power to the utility. This is achieved by controlling the pitch angle of the wind turbine blades. Pitch control method is mechanically complicated, but the control performance is better than that of the stall regulation method. The simulation results performed on MATLAB will show the variation of generator's rotor speed, pitch angle, and generator output.

• Journal of Power Electronics
• /
• 제16권6호
• /
• pp.2035-2044
• /
• 2016

In order to match the voltages between high voltage battery stacks and low voltage super-capacitors with a high conversion efficiency in hybrid energy sources electric vehicles (HESEVs), a high ratio bidirectional DC-DC converter with a synchronous rectification H-Bridge is proposed in this paper. The principles of high ratio step-down and step-up operations are analyzed. In terms of the bidirectional characteristic of the H-Bridge, the bidirectional synchronous rectification (SR) operation is presented without any extra hardware. Then the SR power switches can achieve zero voltage switching (ZVS) turn-on and turn-off during dead time, and the power conversion efficiency is improved compared to that of the diode rectification (DR) operation, as well as the utilization of power switches. Experimental results show that the proposed converter can operate bidirectionally in the wide ratio range of 3~10, when the low voltage continuously varies between 15V and 50V. The maximum efficiencies are 94.1% in the Buck mode, and 93.6% in the Boost mode. In addition, the corresponding largest efficiency variations between SR and DR operations are 4.8% and 3.4%. This converter is suitable for use as a power interface between the battery stacks and super-capacitors in HESEVs.

• 한국수소및신에너지학회논문집
• /
• 제29권2호
• /
• pp.170-180
• /
• 2018

After $MoS_2$ catalyst was prepared at 1, 30, and 70 atm, the hydrothermal pressure effect over preparation of $MoS_2$ was investigated in terms of catalyst characterization and direct methanation. Multifaceted characterization techniques such as XRD, BET, SEM, TPR, EDS, and XPS were used to analyze and investigate the effect of high pressure over the preparation of surface and bulk $MoS_2$ catalyst. Result from XRD, SEM, and BET demonstrated that $MoS_2$ was more dispersed as preparation pressure was increased, which resulted finer $MoS_2$ crystal size and higher surface area. EDS result confirmed that bulk composition was $MoS_2$ and XPS result showed that S/Mo mole ratio of surface was about 1.3. TPR showed that $MoS_2$ prepared at 30 atm possessed higher active surface sites than $MoS_2$ prepared at 1 atm and these sites could contribute to higher CO yield during methanation. Direct methanation was used to evaluate the CO conversion of the both catalysts prepared at 1 atm and 30 atm and reaction condition was at feed mole ratio of $H_2/CO=1$, GHSV=4800, 30 atm, temperature($^{\circ}C$) of 300, 350, 400, and 450. $MoS_2$ prepared at 30 atm showed more stable and higher CO conversion than $MoS_2$ prepared at 1 atm. Faster deactivation was occurred over $MoS_2$ prepared at 1 atm, which indicated that preparation pressure of $MoS_2$ catalyst was the dominant factor to improve the yield of direct methanation.

• 신재생에너지
• /
• 제5권2호
• /
• pp.9-14
• /
• 2009

Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

• 한국생물공학회:학술대회논문집
• /
• 한국생물공학회 2003년도 생물공학의 동향(XII)
• /
• pp.164-168
• /
• 2003

유채유를 사용하여 바이오디젤 생산을 위한 1단 전이에스테르화 공정에 있어서 반응온도 $60^{\circ}C$, 유지에 대한 메탄올 몰비 1:10 이상, 1.0 % (w/w) 포타슘 하이드록시드의 조건에서 98.5% 이상의 전화율을 얻을 수 있었다.