• 제목/요약/키워드: analytical methods

검색결과 3,048건 처리시간 0.027초

Characterization of Korean Porcelainsherds by Neutron Activation Analysis

  • Lee, Chul;Kang, Hyung-Tae;Kim, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • 제9권4호
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    • pp.223-231
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    • 1988
  • Some pattern recognition methods have been used to characterize Korean ancient porcelainsherds using their elemental composition as analyzed by instrumental neutron activation analysis. A combination of analytical data by means of statistical linear discriminant analysis(SLDA) has resulted in removal of redundant variables, optimal linear combination of meaningful variables and formulation of classification rules. The plot in the first-to-second discriminant scores has shown that the three distinct territorial regions exist among porcelainsherds of Kyungki, Chunbuk-Chungnam, and Chunnam, with respective efficiencies of 20/30, 22/27 and 14/15. Similar regions have been found to exist among punchong porcelain and ceradonsherds of Kyungki, Chungnam and Chunbuk, with respective efficiencies of 7/9, 15/16 and 6/6. Classification has been further attempted by statistical isolinear multiple component analysis(SIMCA), using the sample set selected appropriately through SLDA as training set. For this purpose, all analytical data have been used. An agreement has generally been found between two methods, i.e., SLDA and SIMCA.

Mixture of dimethylaminobenzaldehyde and cyanoacrylate to develop fingerprints with fluorescence: a preliminary test

  • Lee, Wonyoung;An, Jaeyoung;Yu, Jeseol
    • 분석과학
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    • 제35권1호
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    • pp.1-7
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    • 2022
  • This study suggests a new one-step fluorescent cyanoacylate-fuming method for developing fingerprints by using a CAB mixed with dimethylaminobenzalde (DMAB) and cyanoacylate (CA) in a specific ratio. CAB is prepared by mixing 2.5 % (w/w) DMAB with CA and fumigated at 180 ℃. Under these conditions, developing fingerprints showed the best results. The fuming method using CAB develops latent fingerprints into fluorescence and has a higher sensitivity than CA, and it showed comparable or better contrast to existing fluorescence enhancement methods. It was also applicable on a variety of non-porous surfaces that can be encountered at ordinary times. This method is more useful than conventional fluorescent dyeing methods in that it minimizes damage to fingerprints or samples, makes it easy to manufacture, saves time, and can use existing current equipment as it is.

열평형적분법에 의한 사다리꼴단면의 직선휜에서의 열전달해석 (Heat Transfer Analysis in a Straight Fin of Trapezoidal Profile by the Heat Balance Integral Method)

  • 조종철;조진호
    • 대한설비공학회지:설비저널
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    • 제11권3호
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    • pp.1-8
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    • 1982
  • When exact analytical solutions to certain type of heat conduction problems are quite cumbersome or not obtainable, it is important to introduce approximate analytical methods which are simple and useful compared with numerical methods. In this study, therefore, the Heat Balance Integral Method is applied to analysis of steady-state conduction in a straight fin of trapezoidal profile, and the two-dimensional temperature distribution in the fin and the approximate fin efficiency are obtained. Results are compared with those by the one- dimensional analysis and two-dimensional numerical analysis for a wide range of Biot numbers. It is shown that the two-dimensional temperature distribution obtained by the integral method is in good agreement with that by the finite element method at Biot numbers for which the result by the one-dimensional analysis is unreliable.

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Extraction and separation of glabridin from licorice by reversed phase high performance liquid chromatography

  • Choi, Du Young;Row, Kyung Ho
    • 분석과학
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    • 제19권6호
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    • pp.455-459
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    • 2006
  • The extraction and separation of glabridin from licorice root by HPLC was performed in this work. First, by investigating the different extraction solvents, extraction methods and extraction times, a one-hour ultrasonic extraction procedure with ethyl acetate as the extraction solvent was optimized. Then the ethyl acetate extraction was applied to RP-HPLC for separation of glabridin. The column efficiencies and resolutions were experimentally investigated with different mobile phase compositions. Baseline separation of glabridin was obtained under the mobile phase composition of 50/50 vol.% (ACN/water). The retention time of glabridin was 20.3 min. The peak of glabridin was collected from the HPLC elution for several times and identified by LC/MS. Under the optimum extraction and HPLC separation methods, 1.26 g of glabridin per kg licorice root could be extracted.

Free vibration analysis of FG carbon nanotube reinforced composite plates using dynamic stiffness method

  • Shahabeddin Hatami;Mohammad Reza Bahrami
    • Steel and Composite Structures
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    • 제50권2호
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    • pp.135-148
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    • 2024
  • This paper analytically investigates the free vibration analysis of functionally graded-carbon nanotube reinforced composite (FG-CNTRC) plates by dynamic stiffness method (DSM). The properties of CNTRC are determined with the extended rule of mixture. The governing differential equations of motion based on the first-order shear deformation theory of CNTRC plate are derived using Hamilton's principle. The FG-CNTRC plates are studied for a uniform and two different distributions of carbon nanotubes (CNTs). The accuracy and performance of the DSM are compared with the results obtained from closed closed-form and semi-analytical solution methods in previous studies. In this study, the effects of boundary condition, distribution type of CNTs, plate aspect ratio, plate length to thickness ratio, and different values of CNTs volume fraction on the natural frequencies of the FG-CNTRC plates are investigated. Finally, various natural frequencies of the plates in different conditions are provided as a benchmark for comparing the accuracy and precision of the other analytical and numerical methods.

Non-Gaussian analysis methods for planing craft motion

  • Somayajula, Abhilash;Falzarano, Jeffrey M.
    • Ocean Systems Engineering
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    • 제4권4호
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    • pp.293-308
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    • 2014
  • Unlike the traditional displacement type vessels, the high speed planing crafts are supported by the lift forces which are highly non-linear. This non-linear phenomenon causes their motions in an irregular seaway to be non-Gaussian. In general, it may not be possible to express the probability distribution of such processes by an analytical formula. Also the process might not be stationary or ergodic in which case the statistical behavior of the motion to be constantly changing with time. Therefore the extreme values of such a process can no longer be calculated using the analytical formulae applicable to Gaussian processes. Since closed form analytical solutions do not exist, recourse is taken to fitting a distribution to the data and estimating the statistical properties of the process from this fitted probability distribution. The peaks over threshold analysis and fitting of the Generalized Pareto Distribution are explored in this paper as an alternative to Weibull, Generalized Gamma and Rayleigh distributions in predicting the short term extreme value of a random process.

ANALYTICAL SOLUTION OF SINGULAR FOURTH ORDER PARABOLIC PARTIAL DIFFERENTIAL EQUATIONS OF VARIABLE COEFFICIENTS BY USING HOMOTOPY PERTURBATION TRANSFORM METHOD

  • Gupta, V.G.;Gupta, Sumit
    • Journal of applied mathematics & informatics
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    • 제31권1_2호
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    • pp.165-177
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    • 2013
  • In this paper, we apply Homotopy perturbation transform method (HPTM) for solving singular fourth order parabolic partial differential equations with variable coefficients. This method is the combination of the Laplace transform method and Homotopy perturbation method. The nonlinear terms can be easily handled by the use of He's polynomials. The aim of using the Laplace transform is to overcome the deficiency that is mainly caused by unsatisfied conditions in other semi-analytical methods such as Homotopy perturbation method (HPM), Variational iteration method (VIM) and Adomain Decomposition method (ADM). The proposed scheme finds the solutions without any discretization or restrictive assumptions and avoids the round-off errors. The comparison shows a precise agreement between the results and introduces this method as an applicable one which it needs fewer computations and is much easier and more convenient than others, so it can be widely used in engineering too.

Numerical and analytical study of aeroelastic characteristics of wind turbine composite blades

  • Ghasemi, Ahmad Reza;Jahanshir, Arezu;Tarighat, Mohammad Hassan
    • Wind and Structures
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    • 제18권2호
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    • pp.103-116
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    • 2014
  • Aeroelasticity is the main source of instability in structures which are subjected to aerodynamic forces. One of the major reasons of instability is the coupling of bending and torsional vibration of the flexible bodies, which is known as flutter. The presented investigation aims to study the aeroelastic stability of composite blades of wind turbine. Geometry, layup, and loading of the turbine blades made of laminated composites were calculated and evaluated. To study the flutter phenomenon of the blades, two numerical and analytical methods were selected. The finite element method (FEM), and JAR-23 standard were used to perform the numerical studies. In the analytical method, two degree freedom flutter and Lagrange's equations were employed to study the flutter phenomena analytically and estimate the flutter speed.

Critical thrust force and feed rate determination in drilling of GFRP laminate with backup plate

  • Heidary, Hossein;Mehrpouya, Mohammad A.;Saghafi, Hamed;Minak, Giangiacomo
    • Structural Engineering and Mechanics
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    • 제73권6호
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    • pp.631-640
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    • 2020
  • Using backup plate is one of the most commonly used methods to decrease drilling-induced delamination of composite laminates. It has been shown that, the size of the delamination zone is related to the vertical element of cutting force named as thrust force. Also, direct control of thrust force is not a routine task, because, it depends on both drilling parameters and mechanical properties of the composite laminate. In this research, critical feed rate and thrust force are predicted analytically for delamination initiation in drilling of composite laminates with backup plate. Three common theories, linear elastic fracture mechanics, classical laminated plate and mechanics of oblique cutting, are used to model the problem. Based on the proposed analytical model, the effect of drill radius, chisel edge size, and backup plate size on the critical thrust force and feed rate are investigated. Experimental tests were carried out to prove analytical model.

압타머 광학 바이오센서 (Aptamer-based optical switch for biosensors)

  • 이주운;조정환;조은정
    • 분석과학
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    • 제27권3호
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    • pp.121-139
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    • 2014
  • In this review, we will discuss aptamer technologies including in vitro selection, signal transduction mechanisms, and designing aptamers and aptazyme for label-free biosensors and catalysts. Dye-displacement, a typical label-less method, is described here which allows avoiding relatively complex labeling steps and extending this application to any aptamers without specific conformational changes, in a more simple, sensitive and cost effective way. We will also describe most recent and advanced technologies of signaling aptamer and aptazyme for the various analytical and clinical applications. Quantum dot biosensor (QDB) is explained in detail covering designing and adaptations for multiplexed protein detection. Application to aptamer array utilizing self-assembled signaling aptamer DNA tile and the novel methods that can directly select smart aptamer or aptazyme experimentally and computationally will also be finally discussed, respectively.