• 한국토양비료학회지
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• 제46권4호
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• pp.296-302
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• 2013

This study was carried out to investigate the effect of organic content level on ultimate methane potential and anaerobic biodegradability of substrate by biochemical methane potential assay. Three organic matters (whole sludge and liquid and solid fraction of sludge) of the same origin, which had different organic contents, were fermented at the batch anaerobic reactor for 70 days. Ultimate methane potential and anaerobic biodegradability were determined by the terms of volatile solid (VS) and chemical oxygen demand (COD). Volatile solid contents of whole sludge and solid and liquid fraction of sludge were 2.4, 18.8, and 0.2% and COD were 5.3, 30.4, and 0.5%, respectively. Ultimate methane potentials ($B_u$-COD) and anaerobic biodegradability ($D_{VS}$) determined by VS content were $0.5Nm^3kg^{-1}-VS_{added}$, 76.3% for whole sludge, $0.5Nm^3kg^{-1}-VS_{added}$, 76.3% for the liquid fraction of sludge, and $0.6Nm^3kg^{-1}-VS_{added}$, 77.0% for the solid fraction of sludge. Ultimate methane potentials ($B_u$-COD) and anaerobic biodegradability ($D_{COD}$) determined by COD were $0.2Nm^3kg^{-1}-COD_{added}$, 73.4% for whole sludge, $0.2Nm^3kg^{-1}-VS_{added}$, 74.0% for the liquid fraction of sludge, and $0.33Nm^3kg^{-1}-COD_{added}$, 99.1% for the solid fraction of sludge. In conclusion, ultimate methane potential and anaerobic biodegradability given by the VS term showed more reasonable results because COD might be underestimated by the interference of $NH_4{^+}$ in the case of highly concentrated organic material.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.514-517
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• 2009

Anaerobic biodegradability(AB), which can be determined with the ultimate methane yield by the decomposition of organic materials, is one of the important parameters for the design and the operation of anaerobic digestion plant. In this study, Biochemical Methane Potential(BMP) test has been carried out to evaluate the methane yield of agro-industrial biomasses such as cattle manure, Italian ryegrass(IRG), Oats, Rye and Barley as the forage crops, Rush, the sludges produced from milling and slaughterhouse wastewater treatment plant(SMWTP, SSWTP). In the condition of thermophilic anaerobic digestion, the ultimate methane yield and anaerobic biodegradability of forage crops ranged from 0.367 to $0.452LCH_4$/gVS of methane yield with AB having the range of about 77.0 to 87.3%. On the other hand, that of other substrate showed low figures compared with the forage crops because of low VS content and C/N ratio. Therefore, the forage crops could be used as a good substrate to produce much more the methane in anaerobic digestion.

• 환경위생공학
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• 제16권2호
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• pp.24-31
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• 2001

This study was aimed to evaluate biodegradability for various food waste using anaerobic batch digestion. In the anaerobic biodegradability study of each food waste according to occurrence source, the cumulative methane productions of water melon and melon were 375, and 354ml and that of cucumber, fresh cabbage, radish, sprouted bean were 366, 364, 374, 384, 355ml and that of noodle, boiled rice and fish were 432, 409 and 477ml $CH_{4/g}$ VS add, respectively. And methane yield rate was about 84.1~97.2%. The reaction rate coefficiency(k) was $0.00495~0.2022day^{-1}$.

• 상하수도학회지
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• 제24권5호
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• pp.603-608
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• 2010

More than 8 millions of chemical have been used for human activities and lots of chemicals can not be degraded by microbial activities in this world. To show the biodegradability of a chemical, biodegradability index (B.I.) is suggested using aerobic biodegradability by $BOD_5$/COD, anaerobic biodegradability by methane potential (M.P.) and toxicity by the luminiscent bacteria. In this study, PVA (polyvinyl alcohol), HEC (hydroxy ethyl cellulose), 2,4,6-TCP (tri-chloro phenol) and 2,4-DCP (di-chloro phenol) are used for test chemicals. Though they show little toxicity, PAV and HEC have low B.I. because they are polymers having high molecular weight. That means that there are no bacteria that has enzyme to degrade polymer molecules. Also, anaerobic treatment is suggested better than aerobic treatment from B.I. 2,4,6-TCP and 2,4-DCP show high toxicity and have low B.I. Their low biodegradabilities seem to be originated from their toxicities. If B.I. is used in wastewater treatment, better treatment process can be suggested and finally it can lead our society to make more environment-friendly chemicals.

• 한국토양비료학회지
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• 제47권3호
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• pp.155-164
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• 2014

Recently interest on production of biogas from biomass resources has increased because of climate change in worldwide. In this study, anaerobic digestion efficiency of 17 different types of agricultural waste was evaluated using biochemical methane production potential estimated from the International biochemical methane potential standard method (Germany VDI4630). As a result, theoretical biochemical methane potential ($B_{th}$) of agricultural waste biomass ranged from 0.266 to $0.488Nm^3kg^{-1}$-Volatile Solid $(VS)_{added}$. Ultimate biochemical methane potential ($B_u$) of agricultural waste biomass ranged between 0.176 and $0.417Nm^3kg^{-1}-VS_{added}$. The agricultural waste biomass anaerobic biodegradability with $B_u/B_{th}$ and VDI4630 determined by VS contents was 36.0~95.9% and 30.8~91.1%, respectively. Ultimate methane potential and anaerobic biodegradability given by the VS term showed more reasonable results.

• 상하수도학회지
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• 제25권4호
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• pp.611-616
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• 2011

The impacts of ultrasonic pretreatment on the biodegradability of domestic sewage sludge were evaluated through a series of anaerobic digestion experiments in batch system. The gas and methane production from the sludge samples pretreated by an ultrasonic tool with different durations were measured with time. Although the biogas production increased with the extent of sludge solubilization and the period of ultrasonic pretreatment, the enhancement of sludge biodegradability was much more sensitive to the pretreatment for the relatively short periods. Most of the enhanced biodegradability by the pretreatment was appeared in the early stage of anaerobic digestion, less than 6 days. The maximum biogas production per day was observed between 4 to 6 days when the sludge was pretreated less than 10 minutes while it was obtained in the beginning for the sludge pretreated longer periods. The results suggest that the repeated alternation of low strength ultrasonic pretreatment and anaerobic digestion may be more effective than the combination of one time pretreatment for a relatively long period and following anaerobic digestion.

• 유기물자원화
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• 제16권3호
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• pp.83-90
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• 2008

하수슬러지의 초음파 전처리시 용존성 유기물의 증가와 혐기성 생분해도 향상을 평가하였다. 하수슬러지의 초음파에 의한 가용화는 세포벽의 파괴로 인하여 용해성 화학적 산소요구량, 단백질 및 탄수화물의 농도 증가와 입자크기를 감소시켰다. 혐기성 생분해도 측면에서초음파 전처리는 메탄가스 발생량을 증가시켜 혐기성 생분해를 향상시키는 것으로 나타났다. 하수슬러지의 생화학적 메탄 잠재 발생량 실험결과 초음파 전처리 후 슬러지의 최종 메탄 수율은 294.3 ml $CH_4/gVS$로 나타나 전처리를 하지 않은 경우 211.3 ml $CH_4/gVS$에 비해 약 40 % 향상된 값을 보였다. 이와 같은 결과를 고려 시 하수슬러지의 가용화는 혐기성 생분해도 향상에 효과적인 것으로 나타났다.

• 신재생에너지
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• 제4권4호
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• pp.56-64
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• 2008

Anaerobic biodegradability (AB), which can be determined with the ultimate methane yield by the decomposition of organic materials, is one of the important parameters for the design and the operation of anaerobic digestion plant. In this study, Biochemical methane potential (BMP) test has been carried out to evaluate the methane yields of animal manures such as pig and cattle slurries, and different forage crops cultivated at the reclaimed tideland such as maize, sorghum, barley, rye, Italian ryegrass (IRG), rape, rush, and waste sludge produced from slaughterhouse wastewater treatment plant (SSWTP). In the ultimate methane yield and biodegradability of animal manure, those of pig slurry were 345 $mlCH_4/gVS_{fed}$ and 44.7% higher than 247 $mlCH_4/gVS_{fed}$ and 46.4% of cattle slurry (Cat. 2). The ultimate methane yield and biodegradability of spike-crop rye (Rye 1) were 442.36 $mlCH_4/gVS_{fed}$ and 86.5% the highest among different forage crops, those of the other forage crops ranged from 306.6 to 379 $mlCH_4/gVS_{fed}$ of methane yield with the AB having the range of about 60 to 77%. Therefore the forage crops could be used as a good substrate to increase the methane production and to improve the biodegradability in anaerobic co-digestion together with animal manure.

• 상하수도학회지
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• 제21권3호
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• pp.315-322
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• 2007

The purpose of this study was to investigate the biodegradability and performance of organic removal and methane production rate when treating piggery wastewater using a granule of two-phase anaerobic process applied UASB. BMP test was conducted as simple means to monitor relative biodegradability of substrate and to determine methane production of an organic material. The two-phase anaerobic process is consisted of a continuous flow stirred-tank reactor (CFSTR) for the acidification phase and an Upflow Anaerobic Sludge Blanket reactor (UASB) for the methanogenesis. The acidogenic reactor played key roles in reducing the periodically applied shock-loading and in the acidification of the influent organics. A stable maximum biogas production rate was 400mL. The methane contents ranged from 73 to 80% during the experimental period. It is known that most of the removed organic matter was converted to methane gas, and the produced biogas might be high quality for its subsequent use.

• 상하수도학회지
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• 제28권1호
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• pp.25-32
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• 2014

In order to investigate the effective pretreatment methods in WAS(=waste activated sludge) solubilization, the values of SCOD yield per unit SS (SCOD/gSS.hr) were compared. After the hydrodynamic cavitation with pH of 12.5, SCOD increased to 7800 mg/L, SS decreased to 45 % and the solubilization rate was 29 %. Combination of alkality (pH 12.5) and the cavitation seems to be the optimal condition for sludge solubilization. After the cavitational pretreatment, efficiencies of anaerobic digestion of the unfiltered sludge(the control), raw sludge and pretreated sludge were evaluated with BMP(=biochemical methane potential) tests. For evaluation of the biodegradability characteristics of pretreated sewage sludge, the methane production has been measured for 6 months. The methane production of pretreated sludge increased 1.4 times than that of untreated sludge. The result indicates that the cavitationally pretreated sludge was a better biodegradability substrate in anaerobic condition compared to raw sludge. It is obvious that cavitational pretreatment could enhance not only solubilization but also biodegradability of WAS. In conclusion, cavitational pretreatment of WAS to convert the particulate into soluble portion was shown to be effective in enhancing the digestibility of the WAS.