• 분석과학
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• 제24권2호
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• pp.94-104
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• 2011

본 연구에서는 양쪽성 메조 다공성 실리카를 다양한 조건(용매, 계면활성제와 올리고머의 량, 용액의 pH)에서 합성하였다. 메조 다공성 실리카를 사용하여 염소 소독으로 인해 음용수 중에 미량 존재하는 변이원성 물질인 MX (3-chloro-4-(dichloromethyl)-5-hydroxy-2-(5H)-furanone)의 흡착에 관한 특성을 연구하였다. 소수성과 친수성의 양쪽성 폴리우레탄 올리고머를 사용하여 합성된 메조다공성 실리카의 경우 뛰어난 흡착특성을 나타내었다. 그리고 보조 계면 활성제의 경우에는 비이온성이며 분자량이 큰 폴리 에틸렌 프로필렌 옥사이드(PEO-PPO)를 사용하여 합성된 메조 다공성 실리키가 가장 좋은 흡착 특성을 보였다.

• Bulletin of the Korean Chemical Society
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• 제26권11호
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• pp.1653-1668
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• 2005

Assembly of hybrid mesophases through the combination of amphiphilic block copolymers, acting as structuredirecting agents, and silicon sources using low acid catalyst concentration regimes is a versatile strategy to produce large quantities of high-quality ordered large-pore mesoporous silicas in a very reproducible manner. Controlling structural and textural properties is proven to be straightforward at low HCl concentrations with the adjustment of synthesis gel composition and the option of adding co-structure-directing molecules. In this account, we illustrate how various types of large-pore mesoporous silica can easily be prepared in high phase purity with tailored pore dimensions and tailored level of framework interconnectivity. Silica mesophases with two-dimensional hexagonal (p6mm) and three-dimensional cubi (Fm$\overline{3}$m, Im$\overline{3}$m and Ia$\overline{3}$d) symmetries are generated in aqueous solution by employing HCl concentrations in the range of 0.1−0.5 M and polyalkylene oxide-based triblock copolymers such as Pluronic P123 $(EO_{20}-PO_{70}-EO_{20})$ and Pluronic F127 $(EO_{106}-PO_{70}-EO_{106})$. Characterizations by powder X-ray diffraction, nitrogen physisorption, and transmission electron microscopy show that the mesoporous materials all possess high specific surface areas, high pore volumes and readily tunable pore diameters in narrow distribution of sizes ranging from 4 to 12 nm. Furthermore, we discuss our recent advances achieved in order to extend widely the phase domains in which single mesostructures are formed. Emphasis is put on the first synthetic product phase diagrams obtained in $SiO_2$-triblock copolymer-BuOH-$H_2O$ systems, with tuning amounts of butanol and silica source correspondingly. It is expected that the extended phase domains will allow designed synthesis of mesoporous silicas with targeted characteristics, offering vast prospects for future applications.