• 한국재료학회지
• /
• 제21권1호
• /
• pp.28-33
• /
• 2011

This paper describes the fabrication of AlN thin films containing iron and iron nitride particles, and the magnetic and electrical properties of such films. Fe-N-Al alloy films were deposited in Ar and $N_2$ mixtures at ambient temperature using Fe/Al composite targets in a two-facing-target DC sputtering system. X-ray diffraction results showed that the Fe-N-Al films were amorphous, and after annealing for 5 h both AlN and bcc-Fe/bct-$FeN_x$ phases appeared. Structure changes in the $FeN_x$ phases were explained in terms of occupied nitrogen atoms. Electron diffraction and transmission electron microscopy observations revealed that iron and iron nitride particles were randomly dispersed in annealed AlN films. The grain size of magnetic particles ranged from 5 to 20 nm in diameter depending on annealing conditions. The saturation magnetization as a function of the annealing time for the $Fe_{55}N_{20}Al_{25}$ films when annealed at 573, 773 and 873 K. At these temperatures, the amount of iron/iron nitride particles increased with increasing annealing time. An increase in the saturation magnetization is explained qualitatively in terms of the amount of such magnetic particles in the film. The resistivity increased monotonously with decreasing Fe content, being consistent with randomly dispersed iron/iron nitride particles in the AlN film. The coercive force was evaluated to be larger than $6.4{\times}10^3Am^{-1}$ (80 Oe). This large value is ascribed to a residual stress restrained in the ferromagnetic particles, which is considered to be related to the present preparation process.

• 한국재료학회지
• /
• 제7권12호
• /
• pp.1083-1088
• /
• 1997

RF스퍼터링법으로 제작한 비정질(Fe$_{1-x}$ Co$_{x}$)$_{89}$Zr$_{11}$자성박막의 자기특성을 Co농도 X에 따라 조사하였다. 130 Oe의 인가자기중 1$50^{\circ}C$에서 90분간 열처리하였을 때 X=0.4, 0.5부근의 박막은 높은 자왜를 나타냄에도 불구하고 양호한 연자기 특성을나타내었다. 특히 X=0.4의 박막에서는 0.25 Oe의 낮은 보자력이 나타났으며, 1MHz, 50mOe의 여기자기장에서 측정된 교류투자율은 900정도였다. 본 연구의 박막에서 얻어진 우수한 자기특성은 외부자기장의 인가에 의해 특성의 변화가 가능한 표면탄성파(surface acoustic wave)소자에 응용될 수 있을 것으로 기대된다.된다..된다.

• Journal of Magnetics
• /
• 제15권4호
• /
• pp.169-172
• /
• 2010

The coercivity mechanism in permanent magnets was analyzed according to the effects of domain nucleation and domain wall pinning. The coercivity mechanism of a TbCo thin film with high perpendicular magnetic anisotropy was considered in terms of the local inhomogeneity in the thin film. The initial magnetization curves of the TbCo thin films demonstrated domain wall pinning to be the main contributor to the coercivity mechanism than domain nucleation. Based on the coercivity model proposed by Kronmuller et al., the inhomogeneity size acting as a domain wall pinning site was determined. Using the measured values of perpendicular anisotropy constant ($K_u$), saturation magnetization ($M_s$), and coercivity ($H_c$), the inhomogeneity size estimated in a TbCo thin film with high coercivity was approximately 9 nm.

• 한국자기학회지
• /
• 제8권4호
• /
• pp.210-215
• /
• 1998

Ball Mill을 이요하여 Ar 분위기에서 기계적합금법으로 Nd15Fe77B8과 Nd16Fe76B8 분말을 제조하고, 제조된 분말을 연속 진공열처리 시킨 후 열처리온도에 따른 상변화 및 자기적 성질을 조사하엿다. 450시간 볼밀도처리한 Nd15Fe77B8과 Nd16Fe76B8 합금 분말에서 Nd와 B의 피크는 보이지 않고 전체적으로 $\alpha$-Fe 결정상만 존재하고 있었으며, 이를 $700^{\circ}C$에서 30분간 열처리를 시키면 고상반응에 의하여 Nd2Fe14B와 소량의 NdB6이 흔재된 상을 얻을 수 있었다. $700^{\circ}C$로 열처리 한 Nd16Fe76B8 합금 분말은 iHc9.9kOe, Bs, 12.9 KG, (BH)max 10.1 MGOe의 자기적 성질을 나타내었다.

• 한국재료학회지
• /
• 제18권10호
• /
• pp.552-556
• /
• 2008

Modified thermal annealing was applied to the activation of the polycrystalline silicon films doped as p-type through implantation of $B_2H_6$. The statistical design of experiments was successfully employed to investigate the effect of rapid thermal annealing on activation of polycrystalline Si doped as p-type. In this design, the input variables are furnace temperature, power of halogen lamps, and alternating magnetic field. The degree of ion activation was evaluated as a function of processing variables, using Hall effect measurements and Raman spectroscopy. The main effects were estimated to be furnace temperature and RTA power in increasing conductivity, explained by recrystallization of doped ions and change of an amorphous Si into a crystalline Si lattice. The ion activation using rapid thermal annealing is proven to be a highly efficient process in low temperature polycrystalline Si technology.

• E2M - 전기 전자와 첨단 소재
• /
• 제8권2호
• /
• pp.229-236
• /
• 1995

Multimedia has created a system environment that needs a combination of diverse peripherals, faster I/O, and easier configuration. The sheer volume of data one can expect with multimedia hardware and applications storage systems of higher capacity and faster data transfer rate. Unlike the magneto-optical(MO)disk technology which uses bias magnetic field in writing, both the reading and the writing in the phase change (PC) technology are performed only by laser light. In PC optical media, an active layer is reversibly converted between amorphous state and crystalline state by changing irradiation conditions of focused laser beam. Thus, as compared with MO disk, the PC disk has such great advantages that signals can be reproduced by change of reflectance of laser beams in the same manner as the compact disc. The reflectivity of a phase-change spot can be altered in a single pass under the head only through modulation of laser power. The principles and the current status of phase-change optical recording media combined with possible applications are discussed in the present article.

• 한국자기학회지
• /
• 제5권5호
• /
• pp.641-644
• /
• 1995

We have studied the effect of the nitrogen on the microstructure, thermomagnetic properties and corrosion resistance of Fe-Hf-C-N nanocrystalline thin films with high permeability and high saturation magnetization. These films were fabricated by reactive sputtering in $Ar+N_{2}$ plasma using an rf magnetron sputtering apparatus. As $P_{N2}$ increases, the microstructure changes from amorphous to crystalline $\alpha$-Fe phase and again returns to amorphous one. Spin wave stiffness constant increases with $P_{N2}$ until 5% $P_{N2}$, and then decreases with the further increase. This trend corresponds well with that of the microstructure with increasing $P_{N2}$. The Fe-Hf-C-N films with over 3% $P_{N2}$ show higher corrosion resistance than the N-free Fe-Hf-C films. The Fe-Hf-C-N films are considered to have high potentials for the head core materials suitable for high density recording systems, owing to their excellent soft magnetic properties and corrosion resistance.

• Macromolecular Research
• /
• 제13권6호
• /
• pp.521-528
• /
• 2005

Electrospun polyacrylonitrile (PAN) nanofibers were carbonized with or without iron (III) acetylacetonate to induce catalytic graphitization within the range of 900-1,500$^{circ}C$, resulting in ultrafine carbon fibers with a diameter of about 90-300 nm. Their structural properties and morphologies were investigated. The carbon nanofibers (CNF) prepared without a catalyst showed amorphous structures and very low surface areas of 22-31 $m^{2}$/g. The carbonization in the presence of the catalyst produced graphite nanofibers (GNF). The hydrogen storage capacities of these CNF and GNF materials were evaluated through the gravimetric method using magnetic suspension balance (MSB) at room temperature and 100 bar. The CNFs showed hydrogen storage capacities which increased in the range of 0.16-0.50 wt$\%$ with increasing carbonization temperature. The hydrogen storage capacities of the GNFs with low surface areas of 60-253 $m^{2}$/g were 0.14-1.01 wt$\%$. Micropore and mesopore, as calculated using the nitrogen gas adsorption-desorption isotherms, were not the effective pore for hydrogen storage.

• Journal of Magnetics
• /
• 제9권4호
• /
• pp.101-104
• /
• 2004

The crystallization behaviours of nanocomposite made by a function of quenching rate (roller speed) were studied. The results showed that there was one step c$\mathbb{r}$ystallization process for the alloy quenched at roller speed of 32 m/s, which could be shown as, Am (amorphouse) + ${\alpha}-Fe/Nd_2Fe_{14}B$ ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{14}B$ . For the alloy quenched at roller speed of 40 m/s, there was steps crystallization process taking place at different temperatures, which could be shown as, Am ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{23}B_3+Nd_2Fe_{14}B+Am`$ ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{14}B$. The presence of transition phase ($Nd_2Fe_{23}B_3$) was harmful to get fine and uniform grain size during crystallization process. Uniform microstructures and high magnetic properties could be attained for the as-quenched alloy containing less amorphous phase and no presence of transition phase during annealing treatment. For the alloy prepared at roller speed of 32 m/s, the following properties were obtained, $B_r= 0.904 T,_iH_c = 801 kA/m, (BH)_{max} = 122 kJ/m^3 and M_r/M_s = 0.6$.

• 융합정보논문지
• /
• 제7권5호
• /
• pp.123-128
• /
• 2017

나노구조를 갖는 물질들은 나노구조물이 갖는 고유의 체적 대비 높은 표면적 비와 양자 갇힘 효과에 기인하는 독특한 전기적, 광학적, 광전기적, 자기적 특성으로 인하여 많은 주목을 받아왔다. 열화학 기상 증착 공정은 나노 구조물의 성장과정에서 다양한 구조를 갖는 나노소재의 합성 능력 때문에 더욱 주목을 받아왔다. 본 연구에서는 두 영역 열화학 기상 증착법과 소스 물질 $TiO_2$ 파우더를 이용하여 VLS 공정으로 Si\$SiO_2$(300 nm)\Pt(5~40 nm) 기판 위에 실리콘 옥사이드 나노와이어를 성장시켰다. 성장된 실리콘 옥사이드 나노와이어의 형상과 결정학적 특성을 전계방출 주사전자현미경과 투과전자현미경으로 분석하였다. 분석결과, 성장된 실리콘 옥사이드 나노와이어의 형상인 지름과 길이는 촉매 박막의 두께에 의존하여 다른 모양을 나타내었다. 또한 성장된 실리콘 옥사이드 나노와이어는 비정질 상을 갖는 것으로 분석되었다.