• Title/Summary/Keyword: ammonia nitrogen removal

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Estimation of Nitrifiable Nitrogen Compounds in Municipal Wastewater by Respirometry (호흡률법에 의한 하수의 질산화성 질소화합물 추정)

  • Kim, Dong Han
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.3
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    • pp.295-303
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    • 2007
  • Nitrogen compounds in municipal wastewater can be divided into biodegradable and nonbiodegradable fractions with biodegradability. Biodegradable nitrogen compounds can be removed through biological nitrification and denitrification processes, and nonbiodegradable nitrogen compounds affect the effluent quality of biological nutrient removal processes. The amount of nitrifiable nitrogen compounds, which are the sum of ammonia and biodegradable organic nitrogen, has been estimated by respirometry. Respirometry shows good estimation of the concentration of nitrifiable nitrogen when a synthetic sample of ammonium chloride is dosed. The estimated concentration of nitrifiable nitrogen compounds in municipal wastewater is close to ammonia concentration in municipal wastewater, but it is lower than that for the synthetic sample. If nitrogen assimilated into cell synthesis of nitrifiers and heterotrophs is considered, the total amounts of nitrifiable nitrogen compounds, which are nitrified and assimilated, could be more accurately estimated. The concentration of nitrifiable nitrogen compounds, which are biodegradable, is about 31 mg N/l, and this is 119% of ammonia and 94% of total nitrogen. Ammonia, nitrate, biodegradable organic nitrogen, and nonbiodegradable nitrogen are about 79%, 1%, 15%, and 5% of the total nitrogen in municipal wastewater, respectively.

Ammonia removal rate on ammonia loading rates in seawater filtering system using rotating biological contactor (RBC) (회전원판을 이용한 해수 순환여과 시스템에서 암모니아 부하율에 따른 암모니아 제거율)

  • SON Maeng Hyun;JEON Im Gi;CHO Kee Chae;KIM Kang Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.4
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    • pp.367-372
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    • 2000
  • A series of experiment was conducted to investigate the relationship between ammoia removal rate and ammonia loading rates in seawater filtering system using rotating biological contactor (RBC). In this experiment, RBC system was consisted of rotating polyvinyl film disks, which provided $12 m^2$ of total effective surface area in $0.075 m^3$ of volume. $NH_4Cl$ was added by $10{\~}150 g$ as a ammonia nitrogen source to determine ammonia removal rate in RBC system. Relationship between time required for ammonia removal (y: hour) and nitrogen inputted ($x: NH_4-N mg/l$) in RBC system was as followed: $y=3.51+7.76 lnx (r^2=0.936)$. At ammonia concentration $2 mg/l$, it took 10 hour for removal of ammonia in the RBC system. However, at ammonia concentration of $5 and 16.5 mg/l$, it took 16 and 27 hours, respectively. There was a decreasing tencency of an increasing ammonia in the rearing water. Finally, the ammonia removal rate in the RBC system increased with the rise of total ammonia concentration up to $16.5 mg/l$.

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Estimation of influening factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater (고농도 암모니아성 질소 폐수의 효과적인 혐기성 처리를 위한 영향 인자 평가)

  • Park, Seyong;Park, Junghoon;Na, Hoysung;Kim, Moonil
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.5
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    • pp.649-658
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    • 2012
  • In this study, the influencing factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater removal were investigated by testing biochemical methane potential test. In the influencing factors, the trace metals which could increase activity of anaerobic microorganisms, microbial concentration and types were evaluated. In the results, trace metals supplementation showed gas production amount higher than those without addition of trace metals. Among the tested trace metals, B, Ni, and Se were preferable to gas production. In the result of gas production according to the microbial concentration, the amount of gas production was proportional to the microbial concentration. In addition, the shortest lag time and the fastest gas production rate were achieved when the highest microbial concentration was tested. granule-type microorganism produced more gas than suspended-type microorganism. In conclusion, the efficient anaerobic digestion for high strength ammonia-nitrogen wastewater removal could be achieved by applying necessary trace metals injection and high concentration granule type microorganism.

Nitrite Accumulation Characteristics and Quantitative Analyses of Nitrifying and Denitrifying Bacteria in a Sequencing Batch Reactor (연속회분반응기의 아질산 축적 특성과 질산화 및 탈질 미생물의 정량적 분포 연구)

  • Kim, Dong-Jin;Kwon, Hyun-Jin;Yoon, Jung-Yee;Cha, Gi-Cheol
    • Journal of Korean Society on Water Environment
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    • v.24 no.3
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    • pp.383-390
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    • 2008
  • Recently, the interests on economical nitrogen removal from wastewater are growing. As a method of the novel nitrogen removal technology, nitrogen removal via nitrite pathway by selective inhibition of free ammonia and free nitrous acid on nitrite oxidizing bacteria have been intensively studied. The inhibition effects of free ammonia and free nitrous acid are low when domestic wastewater is used, however, because of its relatively lower nitrogen concentration than the wastewater from industry and landfill, etc. In this study, a sequencing batch reactor (SBR) is proposed for nitrogen removal to investigate the effect of the low nitrogen concentration on nitrite accumulation. Nitrification efficiency reached almost 100% during the aerobic cycle and the maximum specific nitrification rate ($V_{max,nit}$) reached $17.8mg\;NH_4{^+}-N/g\;MLVSS{\bullet}h$. During the anoxic cycle, average denitrification efficiency reached 87% and the maximum specific denitrification rate ($V_{max,den}$) reached $9.8mg\;NO_3{^-}-N/g\;MLVSS{\bullet}h$. From the analysis the main reason of nitrite accumulation in the SBR was free nitrous acid rather than free ammonia. Nitrite accumulation increased with the decrease of organic content in the wastewater and the mechanism is not well understood yet. From the result of fluorescent in situ hybridization, the distribution of nitrite oxidizing bacteria was in equilibrium with ammonium oxidizing bacteria when nitrite accumulation did not occur.

Estimation of the Reactor Volume Ratio for Nitrogen Removal in Step-Feed Activated Sludge Process (단계 주입 활성슬러지공법에서 질소제거를 위한 반응기 용적비 추정)

  • Lee, Byung-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.130-136
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    • 2006
  • Theoretical total nitrogen removal efficiency and reactor volume ratio in oxic-anoxic-oxic system can be found by influent water quality in this study. The influent water quality items for calculation were ammonia, nitrite, nitrate, alkalinity, and COD which can affect nitrification and denitrification reaction. Total nitrogen removal efficiency depends on influent allocation ratio. The total nitrogen removal follows the equation of 1/(1+b). Optimal reactor volume ratio for maximum TN removal efficiency was expressed by those influent water quality and nitrification/denitrification rate constants. It was possible to expect optimal reactor volume ratio by the calculation with the standard deviation of ${\pm}14.2$.

Effects of Artificial Filaments Equipped in the Aeration Tank of Aerobic Fermentation System on the Removal Efficiency of Nitrogen of Swine Wastewater Containing High Nitrogen (담체설치가 고질소함유 양돈폐수의 호기발효에 미치는 영향)

  • 손경호;이상락;안정제;권윤정;정태영
    • Journal of Animal Environmental Science
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    • v.6 no.2
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    • pp.65-72
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    • 2000
  • This study was conducted to investigate the effects of artificial filaments equipped in the aeration tank of aerobic·fermentation system on the removal efficiency of swine wastes which were fermented an aerobically and thus containing high nitrogen. Two aerobic fermentation system each consist4s of 4 tanks ; storage tank, 1st and 2nd aeration tank and settling tank were run before and one or three weeks after equipment of artificial filament in the aeration tanks. Total solids concentration tended to increase by aerobic fermentation in all running periods. However, decreased(P<0.05) total nitrogen concentration was shown three weeks after the equipment of artificial filament. Ammonia nitrogen concentration also largely decreased(p<0.05) in both running periods of one and three weeks after equipment of artificial filaments. These results suggest that the artificial filaments may improve the removal efficiency of nitrogen in swine wastewater containing high nitrogen during aerobic fermentation.

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Evaluation of Ammonia Removal Mechanisms and Efficiencies Through Batch Experiments (배치 실험을 이용한 암모니아 제거 기작 및 효율 평가)

  • Jang, Jieun;Kang, Jiyoung;Kim, Hye Won;Shin, Kyu Jin;Jeen, Sung-Wook
    • Journal of Soil and Groundwater Environment
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    • v.27 no.6
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    • pp.37-46
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    • 2022
  • As the amount of livestock wastewater increases, ammonia contamination in surface water and groundwater is also increasing, and its treatment is urgently needed. In this study, indigenous soil bacteria was utilized for ammonia removal in artificial wastewater and associated removal mechanisms and efficiencies were evaluated. Two batch reactors were configurated to contain natural soil and artificial wastewater at 1:10 mass ratio, and incubated for 84 and 168 hours, respectively. The results showed that ammonia was completely removed within 48 and 72 hours in the first and second reactors, respectively. There were no significant changes in ammonia concentrations in the control groups without soil. Nitrate was formed in the reactors, indicating that the main removal mechanism of ammonia was nitrification by nitrifying bacteria. Nitrate was further converted to nitrogen gas by denitrification in the anaerobic environment, which was caused by consumption of oxygen during the nitrification process.

Removal of Ammonia Nitrogen and Organics from Piggery Wastewater Using BACC Process-II. Effect of COD/N on Removal of NItrogen and Organics (BACC를 이용한 축산폐수의 암모니아성 질소 및 유기물의 제거 II. COD/N비가 질소 및 유기물 제거에 미치는 영향)

  • 성기달;류원률;김인환;조무환
    • KSBB Journal
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    • v.16 no.2
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    • pp.140-145
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    • 2001
  • To treat piggery wastewater containing refractory compounds including nitrogen, physical treatments using zeolite and biological processes were investigated. In biogical treatment, the removal efficiencies of organics and nitrogen in bioreador using BACC (Biological Activated Carbon Cartridge) media filled with granule activated carbon were examined. The best removal efficiencies achieved for TKN and COD(sub)cr were 82% and 53% respectively, when zeolite dosage was 300 g/L. Specific nitrogen removal ability was 3.2 mg/g at a zeolite dosage of 50 g/L, whereas specific nitrogen removal ability was 1.8 mg/g at a zeolite dosage of 300 g/L. The increased of C/N ratio resulting from the removal of nitrogen using zeolite led to an increase in removal efficiency of organics. As C/N ratio was increased to 2.0, 2.44 and 6.58 at a HRT of 48 hours in a BACC bioreactor, removal efficiencies of COD(sub)cr were increased to 53.5%, 57.4% and 80.6%. The removal efficiency of wastewater using a zeolite dosage of 399 g/L was increased by 27.1% compared to that of control treatment.

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Feasibility Study of Applying EMMC Process to Recirculation Water Treatment System in High Density Seawater Aquaculture Farm through Laboratory Scale Reactor Operation (실험실규모 반응조 운전을 통한 고밀도 해산어 양식장 순환수 처리공정으로서 EMMC공정의 적용 가능성 연구)

  • Jeong Byung Gon;Kim Byung Hyo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.3
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    • pp.116-121
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    • 2004
  • Treatability tests were conducted to study the feasibility of EMMC process as a recycling-water treatment system in high density seawater aquaculture farm. To study the effect of organic and ammonia nitrogen loading rate on system performance, hydraulic retention time was reduced gradually from 12hr to 10min. The conclusions are can be summarized as follows. When the system HRT was reduced from 12hr to 2hr gradually, there was little noticeable change(reduction) in ammonia nitrogen removal efficiencies. However, removal efficiencies were decreased dramatically when the system was operated under the HRT of less than 2hr. In case of organics(COD), there was no dramatic change in removal efficiencies depending on HRT reduction. COD removal efficiencies were maintained successfully higher than 9% when the system was operated at tile HRT of 10 min. System performances depending on media packing ratio in the reactors were also evaluated. There were little differences in each reactor performances depending on media packing ratio in reactor when the reactors were operated under the HRT of longer than 1hr. However, differences in reactor performances were considerably evident when the reactors were operated under the HRT of shorter than 1hr. When comparing reactor performance among 25%, 50%,7 5% packed reactor, it can be judged that media packing ratio more than 50% plays no significant role in increasing reactor performance. For this reason, packing the media less than 50% is more reasonable way in view of economic. Such a tendency shown in COD removal efficiencies well agreed with the variation of ammonia-nitrogen removal efficiencies according to the media packing ratio in reactors at each HRT. Difference in effluent ammonia-nitrogen concentration between 50% media packing reactor and 75% media packing reactor was negligible. When comparing with the results of 25% packing reactor, difference was not so great.

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Structure of Bacterial Communities in Biological Nitrogen Removal System (Biological Nitrogen Removal System의 세균 군집 분석)

  • Kim, Kyung-Mi;Lee, Sang-Ill;Lee, Dong-Hun
    • Korean Journal of Microbiology
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    • v.42 no.1
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    • pp.26-33
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    • 2006
  • To understand the efficient process of biological nitrogen removal (BNR) system, the structure of bacterial communities in nitrification reactors was analyzed using PCR and terminal restriction fragment length poly morphism (I-RFLP) methods. In this study, we used an advanced treatment system with plotting media, Nutrient Removal Laboratory system, or the rumination type sequencing batch reactor (SBR) system. The terminal restriction fragments of ammonia-oxidizing bacteria (AOB) and other $\beta-proteobacteria$ were observed in all of three BNR systems. The nucleotide sequence analysis of terminal restriction fragments showed that Nitrosomonas and Nitrosolobus were major populations of AOB in SBR system, whereas uncultured $\beta-proteobacteria$ and Cardococcus australiensis were the predominant groups in other two BNR systems. Also the SBR system may be more efficient to enrich AOB. These results indicate that the different structure of bacterial community may be developed depending on the wastewater treatment systems, although the same influent is used.