• Journal of Environmental Health Sciences
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• v.31 no.4 s.85
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• pp.280-286
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• 2005

The purpose of this investigation was to evaluate removal efficiency of $NH_4-N$ using the soil column. Soil, oyster shell and natural zeolite were used as a supporting media of soil column. Removal efficiencies of $NH_4-N$ were $35.9\%,\;41\%\;and\;93.4\%$ for the soil column packed with soil, natural $zeolite(20\%)$ and oyster $shell(20\%)$ at HRT of 72 hours, respectively. The addition of $20\%$ oyster shell to the soil accelerated nitrification in soil column. The influent ammonia nitrogen was mostly converted to nitrate nitrogen in the soil column and little ammonia nitrogen was found in the effluent. When the influent $NH_4-N$ concentration was 200 mg/l, the NIL-N removal was decreased at HRT of 48 hours, while nitrification was significantly increased after mechanical aeration. It was suggested that nitrification from higher $NH_4-N$ concentration was more affected by aeration in soil column process. The number of nitrifiers was approximately in a level of about $10^6\;MPN/g{\cdot}soil$ in the soil column mixed with oyster shell ($20\%$).

• Journal of Environmental Science International
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• v.12 no.3
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• pp.281-286
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• 2003

This study was conducted to evaluate the feasibility of ammonia removal by zeolite adsorption in drinking water treatment. In generally, drinking water treatment process is conducted coagulation/flocculation, sedimentation, sand filtration and disinfection. We tested feasibility with two method, one is powdered zeolite dosing to coagulation tank and the other is to substitute granular zeolite for sand of sand filter. In powdered zeolite test, raw water is used tap water with putting of 2 mg/l of NH$_4$$\^$+/-N. Filtration of granular zeolite was conducted with 80 cm of effective column high and 120 m/d of flow rate. At above 100 mg/1 of zeolite dosage, ammonia concentration was decreased below 0.5 mg/l of NH$_4$$\^$+/-N in powdered zeolite test. But, turbidity was increased to 30 NTU by powdered zeolite dosage. That turbidity was scarcely decreased in generally coagulant using condition in drinking water treatment. In granular zeolite test, ammonia was not detected in treated water until 8 days. This result suggest that using of granular zeolite in sand filter could be removal ammonia in winter. But we need regeneration at zeolite filtration for ammonia removal. So, it is to make clear that zeolite regeneration ability was compared KCl with NaCl. The result reveal that KCl was more excellent than NaCl. Optimum regeneration concentration of KCl was revealed 100 mM. Regeneration efficient was not increased at pH range 10∼12.5.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.36 no.2
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• pp.163-169
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• 2003

The floating bead filter was tested for treatment of aquacultural water in a pilot-scale recirculating aquaculture system. Performance of floating bead filter on the removal of total suspended solids (TSS) and the treatment of nitrogen sourer such as total ammonia nitrogen (TAN), nitrite nitrogen and nitrate nitrogen were evaluated. The system was stocked with Nile tilapia at an initial rearing densities of $5\%\;and\;7\%$ over 30 days. The average TSS removal rates were $43.0\;g/m^2{\cdot}day\;and\;39.5\;g/m^2{\cdot}day$ for rearing density of $5\%\;and\;7\%$, respectively. As rearing density increased from $5\%\;to\;7\%$. the TAN removal efficiency decreased from $22.0\%\;to\;17.7\%$. At the rearing densities of $5\%\;and\;7\%$, the average TAN removal rates and removal efficiencies were $38.8\;g/m^2{\cdot}day,\;15.6\%\;and\;37.8\;g/m^2{\cdot}day.\;17.7\%,$ respectively. The average TAN removal rate was $37.8-38.8\;g/m^3{\cdot}day.$ The oxygen consumption by floating bead filter was higher than theoretical oxygen consumption rate by nitrification.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.1013-1016
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• 2008

Nitrogen in the form of nitrate was electrochemically reduced with different cathode materials including Fe, Ni, Cu, and Zn. Zn cathode shows the greatest electrocatalytic activity on the transformation of nitrate ions into ammonia and the $NO_3^-$ removal efficiency has highest value at pH 8.5. Nitrogen in the form of nitrate was initially reduced into nitrite and sequentially, converted into nitrogen inside $NH_3$. Nitrogen in the form of ammonia was completely removed by the reaction with HOCl.

• Environmental Engineering Research
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• v.24 no.3
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• pp.376-381
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• 2019

In this study, a poly(vinyl) alcohol/sodium alginate (PVA/SA) mixture was used to fabricate core-shell structured gel beads for autotrophic single-stage nitrogen removal (ASNR) using aerobic and anaerobic ammonia-oxidizing bacteria (AAOB and AnAOB, respectively). For stable ASNR process, the mechanical strength and oxygen penetration depth of the shell layer entrapping the AAOB are critical properties. The shell layer was constructed by an interfacial gelling reaction yielding thickness in the range of 2.01-3.63 mm, and a high PVA concentration of 12.5% resulted in the best mechanical strength of the shell layer. It was found that oxygen penetrated the shell layer at different depths depending on the PVA concentration, oxygen concentration in the bulk phase, and free ammonia concentration. The oxygen penetration depth was around $1,000{\mu}m$ when 8.0 mg/L dissolved oxygen was supplied from the bulk phase. This study reveals that the shell layer effectively protects the AnAOB from oxygen inhibition under the aerobic conditions because of the respiratory activity of the AAOB.

• Membrane Journal
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• v.29 no.5
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• pp.237-245
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• 2019

Ammonia nitrogen is well known as a substance that causes the eutrophication with a phosphorus in the water, because it is contained in the industrial wastewater, agricultural and the stockbreeding wastewater. In addition, manganese (Mn) and arsenic (As) are included in the mine treated water, etc., and are known as a source of water pollution. Natural zeolites are used to remove ammonia nitrogen in water but it have a low adsorption capacity. In order to improve the low adsorption capacity of the natural zeolite, ion substitution was carried out with $Na^+$, $Ca^{2+}$, $K^+$ and $Mg^{2+}$. The adsorption capacity and removal rate of ammonia nitrogen ($NH_4-N$) were the highest at 0.66 mg/g and 89.8% in $Na^+$ ion exchanged zeolite. Adsorption experiments of Mn and As were performed using ion exchanged zeolites. Ion exchanged zeolite with $Mg^{2+}$ showed high adsorption capacity and removal rates of Mn and As.

• Journal of Korean Society on Water Environment
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• v.20 no.1
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• pp.24-31
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• 2004

This study was initiated to evaluate the efficiencies of DEPHANOX and Modified-DEPHANOX, which were devoloped to enhance nitrogen removal efficiency in municipal wastewater treatment. In the results, removal efficiency of organic matters was not affected much by increased loading rate of organic matters which is contained in influent. The nitrogen removal efficiencies according to the loading rate of influent TN was decreased drastically in conditions of over $0.2kg/m^3{\cdot}day$, which is T-N loading rate, and the DEPHANOX process was affected more sensitively than the M-DEPHANOX was. When the temperature was altered from $25^{\circ}C$ to $16^{\circ}C$ at HRT 6hrs, the removal efficiency of ammonia nitrogen was still over 90% and it was concluded that both DEPHANOX and M-DEPHANOX were strong enough to endure temperature variation. Moreover, both processes showed over 90% in ammonia removal efficiencies in over HRT 5hrs, so it was concluded that they were strong in HRT variation. M-DEPHANOX process showed a higher value than DEPHANOX did in T-N removal efficiency to the extent of 4~21 %, which resulted from differency of denitrification rates and the biosorption efficiency of organic matter in both processes. In the condition of HRT less than 4hrs, concentrations of ammonia nitrogen contained in effluents and nitrification reactors, might be sensitively affected by biosorption efficiency of organic matters in first separation tank. In the effect of effluent nitrate concentration in phosphorus removal, the more effluent nitrate concentration was decreased, the more phosphorus removal efficiency was increased. This result is related to the decrease of concentration of effluent nitrate which resulted from nitrification inhibition by decreased HRT.

• Journal of the Korean Applied Science and Technology
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• v.25 no.3
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• pp.355-362
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• 2008

One of the popular domestic sewage treatment process (called step feed oxic-anoxic-oxic process) for nitrogen removal was analyzed in this study by theoretical analysis based on the nitrification and denitrification reaction. Total nitrogen removal efficiency was suggested by considering influent qualities(i.e., ammonia, nitrite, nitrate, alkalinity, and COD). Total nitrogen removal efficiency depends on r (influent allocation ratio). In the case that all influent components are enough, the total nitrogen removal follows equation 100-b/(1+b), when r is 1/(1+b). Finally, it can be concluded that step feed oxic-anoxic-oxic process could be effective for nitrogen removal.

• Journal of Korean Society on Water Environment
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• v.34 no.1
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• pp.96-108
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• 2018

Large efforts have recently been made on research and development of sustainable and energy-efficient short-cut nitrogen removal processes owing to strong attention to the energy neutral/positive wastewater treatment system. Anaerobic ammonium oxidizing bacteria (anammox bacteria) have been highlighted since 1990's due to their unique advantages including 60% less energy consumption, nearly 100% reduction for carbon source requirement, and 80% less sludge production. Side-stream short-cut nitrogen removal using anammox bacteria and partial nitritation anammox (PN/A) has been well established, whereas substantial challenges remain to be addressed mainly due to undesired main-stream conditions for anammox bacteria. These include low temperature, low concentrations of ammonia, nitrite, free ammonia, free nitrous acid or a combination of those. In addition, an anammox side-stream nitrogen management is insufficient to reduce overall energy consumption for energy-neutral or energy positive water resource recovery facility (WRRF) and at the same time to comply with nitrogen discharge regulation. This implies the development of the successful main-stream anammox based technology will accelerate a conversion of current wastewater treatment plants to sustainable water and energy recovery facility. This study discusses the status of the research, key mechanisms & interactions of the protagonists in the main-stream PN/A, and control parameters and major challenges in process development.

• Journal of Korean Society on Water Environment
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• v.23 no.6
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• pp.993-997
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• 2007

The upflow anaerobic sludge blanket (UASB) reactor can be effective for treating simple organic compounds containing high concentration of ammonia nitrogen. The chemical oxygen demand (COD) removal efficiency was about 80% at ammonia nitrogen concentration up to 6,000 mg-N/L. This result also showed that it would be possible to treat propionate effectively at free ammonia nitrogen concentration up to 724 mg-N/L if sufficient time was allowed for adaptation. However the specific methanogenic activity (SMA) of granule was lower than that of granule in the reactor with lower ammonia nitrogen concentration. At 8,000 mg-N/L, the inhibition of high ammonia concentration was observed with evidence of increase of the volatile suspended solids (VSS) concentration in the effluent. It might be ascribed to the decrease in the content of extracellular polymer (ECP), which resulted to the sloughing off of obligated proton-reducing acetogens and heterogenotrophic methanogens from the exterior of granular sludge. This caused a great portion of the finely sludge to be easily washed out. Therefore, failure to maintain the balance between these two groups of microorganism cause accumulation of the hydrogen partial pressure in the reactor, which could have inhibited the growth of acetate utilizing methanogens.