• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.125.2-125.2
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• 2015

The evolution of oxidation states of vanadium is monitored with ambient pressure X-ray photoemission spectroscopy. As the pressure of oxygen gas and surface temperature change, the formations of various oxidation states of vanadium are observed on the surface. Under 100mTorr of the oxygen gas pressure and 523K of sample temperature, VO2 and V2O5 are formed on the surface. The temperature-dependent resistance measurement on grown sample shows a clear metal-insulator transition near 350K. In addition, the measurement of Raman spectroscopy displays the structural change from monoclinic to rutile structures across the phase transition temperature.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.E3
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• pp.75-85
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• 2005

A mathematical sensitivity analysis of the flow-through dynamic flux chamber technique, which has been utilized usually for various trace gas flux measurement from soil and water surface, was performed in an effort to provide physical and mathematical understandings of parameters essential for the NO flux calculation. The mass balance equation including chemical reactions was analytically solved for the soil NO flux under the steady state condition. The equilibrium concentration inside the chamber, $C_{eq}$, was found to be determined mainly by the balance between the soil flux and dilution of the gas concentration inside the chamber by introducing the ambient air. Surface deposition NO occurs inside the chamber when the $C_{eq}$ is greater than the ambient NO concentration ($C_{0}$) introducing to the chamber; NO emission from the soil occurs when the $C_{eq}$ is less than the ambient NO concentration. A sensitivity analysis of the significance of the chemical reactions of NO with the reactive species (i.e. $HO_{2},/CH_{3}O_{2},/O_{3}$) on the NO flux from soils was performed. The result of the analysis suggests that the NO flux calculated in the absence of chemical reactions and wall loss could be in error ranges from 40 to $85\%$ to the total flux.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2003.10a
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• pp.157-163
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• 2003

A systematic numerical experiment has been conducted to study droplet gasification in high pressure environments with pressure oscillations. The general frame of previous rigorous model[1] is retained but tailored for flash equilibrium calculation of vapor-liquid interfacial thermodynamics. Time-dependent conservation equations of mass, momentum, energy, and species concentrations are formulated in axisymmetric coordinate system for both the droplet interior and ambient gases. In addition, a unified property evaluation scheme based on the fundamental equation of state and empirical methods are used to find fluid thermophysical properties over the entire thermodynamic domain of interest. The governing equations with appropriate physical boundary conditions are numerically time integrated using an implicit finite-difference method with a dual time-stepping technique. A series of calculation have been carried out to investigate the gasification of an isolated n-pentane droplet in a nitrogen gas environment over a wide range of ambient pressures and frequencies. Results show that the mean pressures and frequencies of the ambient gas have strong influences on the characteristics of the droplet gasification. The amplitude of the response increases with increasing pressure, and the magnitude of the vaporization response increases with the frequency.

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.1
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• pp.25-30
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• 2000

In present paper, mass transfer over a flat plate with film condensation including noncondesable gas is analyzed with the help of similarity methods. Couette flow was assumed in liquid film and boundary-layer approximation was used in the ambient flow. Governing equations were transformed into the ordinary differential equtions by the similarity methods. Runge-Kutta and shooting method were used in order to fine the effect of mass transfer on the velocity and concentrations at the liquid-vapor interface.

• Journal of environmental and Sanitary engineering
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• v.10 no.3
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• pp.124-130
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• 1995

Air pollution problem by air craft was reviewed from emission gas components from air craft and pollutants amount generated in airport with the compareness of domestic transportation data by airplane and foreign data. It is reported that concentration of emission gas from air craft is lower than that of pollutants from automobile and factory. But transportation frequency is increasing rapidly in Korea. It is recommended that concerns should be taken on long- term of counterplan device about it.

• Journal of ILASS-Korea
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• v.13 no.3
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• pp.117-125
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• 2008

The correlations for the prediction of maximum liquid-phase penetration in diesel spray are reviewed in this study. The existing models developed for the prediction of maximum liquid-phase penetration can be categorized as the zero-dimensional (empirical) model, the multi-dimensional model and the other model. The existing zero-dimensional model can be classified into four groups and the existing multidimensional models can be classified into three groups. The other model includes holistic hydraulic and spray model. The maximum liquid-phase penetration is mainly affected by nozzle diameter, fuel volatility, injection pressure, ambient gas pressure, ambient gas density and fuel temperature. In the case of empirical correlations incorporated with spray angle, the predicted results will be different according to the selection of correlation for spray angle. The research for the effect of boiling point temperatures on maximum liquid-phase penetration is required. In the case of multidimensional model, there exist problems of the grid and spray sub-models dependency effects.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.3
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• pp.201-206
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• 2009

The focus of this work is placed on the analysis of the mixture formation process under the evaporative diesel-free spray conditions. In order to examine homogeneity of mixture within the vapor phase region of the injected spray, image analysis was carried out based on the entropy of statistical thermodynamics. As an experimental parameter, the injection pressure and ambient gas density were selected, and effects of the injection pressure and density variation of ambient gas on the mixture formation process in the evaporative diesel spray were investigated. In the case of application of the thermodynamic entropy analysis to evaporative diesel spray, the value of the dimensionless entropy always increases with increase in time from injection start. Consequently, the dimensionless entropy in the case of the higher injection pressure is higher than that of lower injection pressure during initial injection period.

• Journal of Mechanical Science and Technology
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• v.19 no.4
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• pp.1027-1035
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• 2005

Thermophoresis in dense gases is studied by using a multi-scale approach and Born- Yvon­Green (BYG) equation. The problem of a particle movement in an ambient dense gas under temperature gradient is divided into inter and outer ones. The pressure gradient in the inner region is obtained from the solutions of BYG equation. The velocity profile is derived from the conservation equations and calculated using the pressure gradient, which provides the particle velocity in the outer problem. It is shown that the temperature gradient applied to the quiescent ambient gas induces some pressure gradient and thus flow tangential to the particle surface in the interfacial region. The mechanism that induces the flow may be the dominant source of the thermophretic particle movement in dense gases. It is also shown that the particle velocity has a nonlinear relationship with the applied temperature gradient and decreases with increasing temperature.

• The Bulletin of The Korean Astronomical Society
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• v.36 no.2
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• pp.104.2-104.2
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• 2011

We study X-ray characteristics of shocked ambient gas of the Galactic core-collapse supernova remnant Cas A. Using 1 Msec observation with Chandra X-ray Observatory, we identify thermal emissions from the shocked ambient gas along the outer boundary of the remnant. Our results show that Cas A is expanding into a circumstellar wind with a wind density n ~ 1 $cm^{-3}$ at the current outer radius of the remnant (~ 3 pc). We suggest that the progenitor star of Cas A, which exploded as a Type~IIb SN, had an initial mass ~16 Msun, and have lost ~10 Msun as a RSG wind. We discuss the implications of our results for the mass loss of massive stars and the resulting supernova type.

• Journal of ILASS-Korea
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• v.7 no.3
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• pp.18-23
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• 2002

An evaporating diesel spray of a common rail lnjector was visualized by LIEF technique. This technique makes it possible to separate the vapor and liquid phase images. The experiment was conducted in a constant volume vessel to make a high temperature and high pressure condition. Three images(vapor and liquid phase images from LIEF and a liquid phase image from Mie scattering) were taken simultaneously in one spray event. The major experimental parameters are the injection pressure and the ambient gas pressure. Also, a relative SMD distribution in a liquid phase was obtained by the ratio of the intensities of the fluorescence and the Mie scattering. The results show that the injection pressure and the ambient gas pressure have a close relation with the spray development and air-fuel muting process.