• 제목/요약/키워드: aluminum polymer

검색결과 201건 처리시간 0.025초

나노초 펄스 레이저를 이용한 발광폴리머 패터닝 (Selective Ablation of Emissive Polymer Using Nanosecond-pulsed Laser)

  • 고정수;오부국;김두영;이재영;이승기;정수화;홍순국
    • 한국레이저가공학회지
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    • 제14권3호
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    • pp.7-11
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    • 2011
  • As an active emission display using emissive polymer has had much attention recently, needs for a selective patterning of emissive layer for those displays have been increased abruptly. Therefore, the various laser sources in terms of its wavelength has been used for laser direct patterning. In this work, the feasibility of those processes is examined using numerical analysis and the experimental investigation. A sample has multi-layered structure, emissive polymer on aluminum which is deposited on a glass substrate. Key factors for optimizing the laser patterning of the emissive polymer are considered into the control of ablation products, large-sized particle, and the choice of the appropriate wavelength for minimizing the heat affected zone and the remnant layer.

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알루미늄 고분자 콘덴서의 특성에 대한 절연지 탄화의 영향 (Effects of Separator Carbonization on the Characteristics of Aluminium Polymer Condenser)

  • 김재근;유형진;홍웅희;박미진;박승열
    • 공업화학
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    • 제17권5호
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    • pp.539-546
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    • 2006
  • 전도성 고분자인 polyethylenedioxythiophene (PEDOT)을 권취형 알루미늄 콘덴서의 고체 전해질 및 음극으로 적용하기 위하여 PEDOT 중합공정 및 절연지 탄화공정 연구를 수행하였다. 단량체로 ethylenedioxythiophene (EDOT), 산화제로 ferric-p-toluenesulfonate를 사용하였다. 권취된 미세 다공성 알루미늄 에칭박 피트 내부에 균일한 PEDOT 전해질 층을 생성하기 위하여 콘덴서 소자를 열처리하여 탄화함으로써 절연지의 섬유조직을 조절하고 이를 통해 중합액의 절연지 집중현상을 억제하여 에칭 피트 내부로의 중합액 함침이 용이하도록 하였다. 탄화온도, 탄화시간에 따라 콘덴서의 용량, 손실, 등가직렬저항, 내열특성이 좌우되었다. 절연지의 두께, 밀도는 탄화공정의 중요한 변수이며 이들 변수에 따라 콘덴서의 특성이 영향을 받는 것을 확인하였다.

양이온 중합을 이용한 폴리알파올레핀의 미세구조 조절에 관한 연구 (A Study on the Control of Microstructures of Polyalphaolefins via Cationic Polymerization)

  • 고영수;권완섭;노명한;임진형
    • 폴리머
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    • 제39권2호
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    • pp.346-352
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    • 2015
  • 폴리알파올레핀(PAO)은 유동점, 점도지수, 열/산화 안정성이 광유 기반의 윤활유보다 우수한 합성 윤활유이다. 본 연구에서는 1-펜텐, 1-헥센, 1-옥텐, 및 1-도데센을 단량체로 사용하고 세가지 종류의 알루미늄계 루이스 산촉매로 양이온 중합을 수행하여 다양한 PAO를 합성하였다. PAO 중합 성능과 제조된 PAO의 분자량, 동점도, 유동점과 점도지수를 다양한 중합 조건에서 조절할 수 있었다. 알킬 알루미늄 할라이드계 촉매가 기존의 $AlCl_3$계 촉매에 비하여 촉매 성능이 우수하였다. PAO의 미세구조를 비행-시간형 질량분석기(TOF-MS) 해석을 통하여 PAO의 미세구조와 윤활유로의 성능(점도지수, 유동점)과의 상관관계를 규명하였다. 특히, PAO의 점도지수는 알파 올레핀의 탄소수 증가에 따라 상승하여, PAO의 분지길이가 점도지수와 밀접한 상관관계가 있음을 확인하였다.

긴급시공이 가능한 FRP 내진보강재 개발 및 최적 보강량 산정을 위한 해석적 연구 (Analytical Study for Optimal Reinforcement Amount and Development of FRP Seismic Reinforcement that can be Emergency Construction)

  • 김진섭;권민호;서현수;임정희;김동영
    • 한국구조물진단유지관리공학회 논문집
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    • 제17권5호
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    • pp.136-145
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    • 2013
  • 최근 발생한 대규모 지진으로 구조물의 내진보강에 대한 사회적 관심도가 높아지고 있다. 특히 내진 설계가 반영되지 않은 기둥은 취성적인 파괴로 구조물 전체붕괴를 유발하기 때문에 내진보강이 적용 되어야한다. 과거에는 단면증설법, 강판보강법등이 주로 적용되었고 최근에는 복합재료의 장점을 이용한 섬유보강법이 선호되고 있다. 그러나 이러한 보강법들은 구조물의 물리적 손상을 유발하며, 작업공간과 시간소비가 크다는 단점이 있다. 본 연구에서는 기존 보강법의 단점을 보강하여 복합재료 (Fiber reinforced polymer)와 Aluminum 체결부 이용한 FRP 내진보강재를 개발하였다. 비선형 유한요소 해석프로그램을 통해 개발된 FRP 내진보강재의 최적 보강량을 결정하였다.

Basic Design of High-Speed Riverine Craft Made of Carbon Fiber Reinforced Polymer

  • Han, Zhiqiang;Choi, Jung-kyu;Hwang, Inhyuck;Kim, Jinyoung;Oh, Daekyun
    • 대한조선학회논문집
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    • 제57권4호
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    • pp.241-253
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    • 2020
  • The Small-Unit Riverine Craft (SURC) is a small high-speed vessel used by navies and marine corps in relatively shallow waterway environments, such as riverine areas or littoral coasts. In the past, SURCs have primarily been rigid-hulled inflatable boats constructed using composite materials such as glass fiber reinforced plastics. More recently, single-hull SURCs have been manufactured using aluminum for weight reduction. In this study, a Carbon Fiber Reinforced Polymer (CFRP) material was applied instead to examine its feasibility in the basic design of an SURC with a hull length of 10 m. The CFRP structural design was obtained using the properties of a marine CFRP laminate, determined in a previous study. Next, the designed CFRP SURC was modeled to confirm its functionality, then compared with existing aluminum SURCs, indicating that the CFRP SURC was 41.49 % lighter, reduced fuel consumption by 30 %, and could sail 50 NM further for every hour of engine operation. A method for reducing the high cost of carbon fiber was also proposed based on the adjustment of the carbon fiber content to provide the optimum strength where required. The data developed in this study can be used as a basis for further design of CFRP craft.

세라믹 방열 복합체의 열전도도 분석 및 Wetting Process를 이용한 SiC/에폭시 복합체 (Thermal Conductivity of Thermally Conductive Ceramic Composites and Silicon Carbide/Epoxy Composites through Wetting Process)

  • 황용선;김주헌;조원철
    • 폴리머
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    • 제38권6호
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    • pp.782-786
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    • 2014
  • 세라믹 방열 복합체의 특성 비교를 위해 casting method로 제작하였으며, 이들의 광학적 이미지와 단면 FE-SEM 분석을 실시하였다. 각각의 복합체의 열전도성 특성을 비교 분석하였으며, silicon carbide(SiC)의 분산도 문제를 해결하기 위해 wetting process를 도입하여 SiC/epoxy 복합체를 제작하였다. 기존의 방법에서 발견된 복합체 내공극과 분산도 문제가 wetting process를 통해 향상되었으며, 충전제 함량에 따른 열전도성 특성을 분석하였다. SiC 복합체의 함량에 따른 공극률 해석을 통해 70 wt% SiC 복합체에서 가장 높은 열전도도 값을 보였으며, 이들의 단면 FE-SEM 분석을 통해 복합체 내의 충전제 분산도를 확인하였다.

Light-emitting devices with polymer-organic heterostructure

  • Do, Lee-Mi;Hwang, Do-Hoon;Choi, Kang-Hoon;Lee, Hyang-Mok;Jung, Sang-Don;Zyung, Taehyoung
    • Journal of the Optical Society of Korea
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    • 제1권2호
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    • pp.116-119
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    • 1997
  • Highly quantum efficient and multi-color emissible polymer light emitting devices have been realized utilizing poly (1-dodecyloxy-4-methyl-1, 3-phenylene)(2, 5"-terthienylene)(hereafter, mPTTh polymer) as an emitting layer and tris(8-hydroxyquinoline) aluminum (Alq3) as an electron transport layer. A single layer EL device of mPTTh polymer emits orange-colored light. EL efficiency increases as the thickness of Alq3 layer increases, but the emission color becomes visually broad when the Alq3 layer thickness is greater than 30nm since the relative peak intensity of green EL from Alq3 layer grows. EL color is changed from orange to greenish orange as the thickness of Alq3 layer grows. EL color is changed from orange to greenish orange as the thickness of Alq3 layer increases. EL efficiency of the double layer device was greatly enhanced by 3000 times compared with that of a single layer device. Alq3 layer in device acts as a hole blocking electron transporting layer and an emitting layer as a function of the thickness of Alq3 layer.ayer.

Enhanced Performance of Induction Cookers by the Use of Polymer Composites

  • Nam, Yoon-Jae;Lee, Dong-Ki;Kwon, Jong-Han;Shin, K.H.;Lim, S.H.
    • Journal of Magnetics
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    • 제15권3호
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    • pp.123-127
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    • 2010
  • The use of a cooling fan in an induction cooker raises a reliability issue due to the attraction of dust causing a malfunction of the cooling fan and also increases the noise level and power consumption of the device. The purpose of this study is to attempt to solve these problems by molding the Cu coil of an induction cooker with polymer composites that have a low electrical conductivity but a high thermal conductivity. Among the several polymer composites tested in this study, an aluminum nitride-based composite showed the best performance. The results show that the new induction cooker with the molded composite can operate for an extended period of time without the use of a cooling fan. A further advantage of this new type of induction cooker is that the temperature of the substance in the cooking pot increases more rapidly, indicating an increased efficiency of the induction cooker.

폴리머 배터리 전극제조용 압연 고온롤 표면의 형상 및 유한요소 열변형 해석 (Shapes and Thermomechanical Analyses of a Hot Roll for Manufacturing Electrodes of Polymer Batteries)

  • 김철;장동수;유선준
    • 대한기계학회논문집A
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    • 제31권8호
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    • pp.847-854
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    • 2007
  • The battery electrode of a mobile phone is made of layered polymer coated on aluminum foils and the hot rolling process is applied to increase the density per volume of an electrode for a high capacity battery. The flatness of batteries surfaces should be less than $2{\mu}m$. To satisfy the required flatness, the deformation of roll surface due to bending and heating of the roll should be minimized. Complicated hot oil paths of $100^{\circ}C$ inside the roll are required for heating the polymer layers. FEA was used to calculate thermal deformations and temperatures distributions of the roller. Based on FEA, a modified surface curvature called a crown roll was suggested and this gave the area of 30% improved flatness compared with a flat roll. The flat roll satisfied the flatness of $2{\mu}m$ in the length of 340 mm and the crown roll resulted in the longer length of 460 mm. Experiments to measure the temperature distribution and thermal strain were performed and compared with FEA. There were only 6% difference between two results.

Modified Carrageenan. 6. Crosslinked Graft Copolymer of Methacrylic Acid and kappa-Carrageenan as a Novel Superabsorbent Hydrogel with Low Salt- and High pH-Sensitivity

  • Pourjavadi A.;Harzandi A. M.;Hosseinzadeh H.
    • Macromolecular Research
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    • 제13권6호
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    • pp.483-490
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    • 2005
  • A novel, polysaccharide-based, superabsorbent hydrogel was synthesized through crosslinking graft copolymerization of methacrylic acid (MAA) onto kappa-carrageenan ($_{k}C$), using ammonium persulfate (APS) as a free radical initiator in the presence of methylenebisacrylamide (MBA) as a crosslinker. A proposed mechanism for $_{k}C$­g-polymethacrylic acid ($_{k}C$-g-PMAA) formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy. The effect of grafting variables, including MBA, MAA, and APS concentration, was systematically optimized to achieve a hydrogel with the maximum possible swelling capacity. The swelling kinetics in distilled water and various salt solutions were preliminarily investigated. Absorbency in aqueous salt solutions of lithium chloride, sodium chloride, potassium chloride, calcium chloride, and aluminum chloride indicated that the swelling capacity decreased with increased ionic strength of the swelling medium. This behavior can be attributed to the charge screening effect for monovalent cations, as well as ionic crosslinking for multivalent cations. The swelling of super absorbing hydrogels was measured in solutions with pH ranging from 1 to 13. In addition, the pH reversibility and on-off switching behavior, at pH levels of 3.0 and 8.0, give the synthesized hydrogels great potential as an excellent candidate for the controlled delivery of bioactive agents.