• Applied Chemistry for Engineering
• /
• v.16 no.2
• /
• pp.267-274
• /
• 2005

Preparation of cellulose type underwater non-segregation admixture was attempted and the hardening characteristics of underwater concrete according to the addition of this admixture was investigated in order to make underwater concrete with the compressive strength ratio of 0.8 to that of concrete manufactured in common atmosphere. The proposed underwater non-segregation admixture consisted of methyl cellulose of 0.4% by weight, silicon type antifoaming agent of 20% by weight, and sodium aluminate of 0.1% by weight to the amount of cement as setting accelerant, respectively. As the proposed non-segregation admixture was increased, the amount of suspended solid decreased, air content in concrete was increased but the flow loses by elapsed time did not change. The proper amount added of the proposed non-segregation adimixture was 0.8 wt% to the amount of cement. The compressive strength of the test sample underwater concrete manufactured by the addition of the proposed admixture was $325Kg/cm^3$, and the ratio of compressive strength of this sample concrete to that of a concrete manufactured in air was 0.94.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.21 no.4
• /
• pp.124-131
• /
• 2017

The purpose of this study is to evaluate the basic performance of cement mortar for repair using alumina cement and nitrite can be cured in low temperature environment. For this purpose, the repair mortar used in the domestic construction site was selected and the experimental evaluation was carried out by adjusting the mixing amount by substituting alumina cement and nitrite for the blending ratio. The experimental test results confirmed that alumina cement and nitrite were replaced with the repair mortar, the initial strength was improved. Also, the chemical resistance was improved, the shrinkage behavior was decreased, and the resistance to freezing and thawing was increased. As a result, applying alumina cement and nitrite at a ratio of 2:1 at 7.5%, the surface condition was maintained for 5 months or longer and it was judged to be excellent in practical use for external structures.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.18 no.3
• /
• pp.125-132
• /
• 2014

Steel fiber is a effective composite for crack resistance and improve structural performance under tensile loading. This study presents an evaluation of crack resistance and structural performance in cement mortar with steel fiber and expansion agent through internal chemical prestressing. For this work, cement mortar samples with 10% replacement of cement binder with CSA (Calcium-Sulfo-Aluminate) expansion agent and 1% volume ratio of steel fiber are prepared. Including basic mechanical properties, initial cracking load and fracture energy are evaluated in cement mortar beam with notch. Initial cracking load and fracture energy in cement mortar with CSA and steel fiber increase by 1.75 and 1.41~1.53 times compared with those in cement mortar with steel fiber. With optimum mix design for steel fiber and CSA expansive agent, the composite with chemical prestressing can be applied to various members and effectively improve crack resistance to external loading.

• Resources Recycling
• /
• v.3 no.3
• /
• pp.27-31
• /
• 1994

We tested the limestone sludge produced in Pohang Iron & Steel Co., Ltd. as a filler powder for the effective use of portland cement. Hydration process was investigated by measuring the hydration rate, the amounts of non-evaporable water and compressive strength of cement-limestone sludge paste prepared by mixing limes-tone sludge with cement. The results obtained in this study can be summarized as follows: 1. There is no significant difference between the cases of adding up to 10% limestone sludge and those of unmixed cement system. However the reaction rate increases in the 5% limestone sludge system(due to the effects of fine). 2. The compressive strength increases proportionally with increasing the measured amount of non-evaporable water, Adding 5% limestone sludge also increases the strength a little higher, and the compressive strength and calcium silicate hydrates. In the case of the mixed limestone sludge, $2\theta$=$11.7^{\circ}$ peak appears in the samples of 28 days hydration. This peak indicted the presence of calcium carboaluminate hydrate. Although limestone sludge is generally regarded as a inert materials, some kinds of cement can produce a calcium carboaluminate by reacting with aluminate in cement pastes.

• Journal of the Korea Concrete Institute
• /
• v.29 no.4
• /
• pp.389-397
• /
• 2017

Friedel's salt is an important product of chemical adsorption between cement hydrate and chloride ions because it contains chlorine in its structure. When cement reacts with water in the presence of chloride ions, the $C_3A$ phase, and $C_4AF$ phase react with chloride to produce Friedel's salt. If chloride ions penetrate into concrete from external environments, many calcium aluminate hydrates, including AFm, can bind chloride ions. It is very important, therefore, to investigate the chloride binding isotherm of $C_3A$ phase, $C_4AF$ phase, and AFm phase to gain a better understanding of chloride binding in cementitious materials. Meanwhile, the adsorption isotherm can provide us with the fundamental information for the understanding of adsorption process. The experimental results of the isotherm can supply not only the quantitative knowledge of the cement-Friedel's salt system, but also the mechanism of adsorption and the properties of their interactions. The purpose of this study is to explore the time dependant behaviors of chloride ions adsorption with $C_3A$, $C_4AF$ and AFm phases. The chloride adsorption isotherm was depicted with Langmuir isotherm and the adsorption capacity was low in terms of the stoichiometric point of view. However, the chloride adsorption of AFm phase was depicted with Freundlich isotherm and the value was very low. Since the amount of the adsorption was governed by temperature, the affecting parameters of isotherm were expressed as a function of temperature.

• Restorative Dentistry and Endodontics
• /
• v.48 no.1
• /
• pp.3.1-3.14
• /
• 2023

Objectives: This study evaluated the effect of different nanoparticulated zinc oxide (nano-ZnO) and conventional-ZnO ratios on the physicochemical properties of calcium aluminate cement (CAC). Materials and Methods: The conventional-ZnO and nano-ZnO were added to the cement powder in the following proportions: G1 (20% conventional-ZnO), G2 (15% conventional-ZnO + 5% nano-ZnO), G3 (12% conventional-ZnO + 3% nano-ZnO) and G4 (10% conventional-ZnO + 5% nano-ZnO). The radiopacity (R_ad), setting time (S_et), dimensional change (D_c), solubility (S_ol), compressive strength (C_st), and pH were evaluated. The nano-ZnO and CAC containing conventional-ZnO were also assessed using scanning electron microscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy. Radiopacity data were analyzed by the 1-way analysis of variance (ANOVA) and Bonferroni tests (p < 0.05). The data of the other properties were analyzed by the ANOVA, Tukey, and Fisher tests (p < 0.05). Results: The nano-ZnO and CAC containing conventional-ZnO powders presented particles with few impurities and nanometric and micrometric sizes, respectively. G1 had the highest Rad mean value (p < 0.05). When compared to G1, groups containing nano-ZnO had a significant reduction in the S_et (p < 0.05) and lower values of D_c at 24 hours (p < 0.05). The C_st was higher for G4, with a significant difference for the other groups (p < 0.05). The S_ol did not present significant differences among groups (p > 0.05). Conclusions: The addition of nano-ZnO to CAC improved its dimensional change, setting time, and compressive strength, which may be promising for the clinical performance of this cement.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.17 no.6
• /
• pp.88-94
• /
• 2013

The hexavalent chromium (Cr(VI)) is well known as a hazardous ion, presumably inducing dermatic diseases and if serious cancer. The present study concerns the binding capacity of Cr(VI) ions in the cement powder and matrix for a quantitative technique of Cr(VI) ions in cement to influence human health. Both the water-soluble and acid-soluble Cr(VI) ions present in 3 types of ordinary Portland cement (OPC), pulverised fuel ash (PFA), ground granulated blast furnace slag (GGBS), and silica fume (SF) were measured using the spectrophotometer. As a result, it was found that the concentration of water-soluble Cr(VI) ion in cement ranged from 10.5 to 18.9mg/kg-cement, and in the additional materials a very low value of Cr(VI) ion was measured. Acid-soluble Cr(VI) ion was even higher than water-soluble Cr(VI) ion, ranging from 172.4 to 318.2mg/kg-cement. Nevertheless, the concentration of acid-soluble Cr(VI) ion is not proportional to addition of acid. It depends rather the variable pH of solvent involving cement paste. As enough cement hydration occurs, the binding capacity of Cr(VI) ion increases, inhibiting this ions from leaching out in the presence of hydration products such as ettringite or tri-calcium aluminate which bind Cr(VI) ion by ion-exchange.

• Journal of the Korea Concrete Institute
• /
• v.22 no.5
• /
• pp.633-640
• /
• 2010

This study was performed to get basic information about properties of high blaine cement for shotcrete use. Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of high blaine cement. Setting time of high blaine cement was shorter and compressive strength was higher than those of ordinary portland cement (OPC). Results of analysis showed early hydration products of high blaine cement is smaller and spread widely due to increased specific surface. From the SEM observation and analysis of DSC and XRD results, it was seen that the aluminates accelerators promoted calcium aluminium hydrates while the alkali free accelerators increased ettringite and monosulfates formation. Strength and setting time measurement of cement paste with aluminate accelerator is more effective than the alkali free accelerator in reducing the setting time and increasing early strength while alkali free accelerator is more effective in increasing the strength after 7 days.

• Geomechanics and Engineering
• /
• v.15 no.4
• /
• pp.1005-1016
• /
• 2018

This paper presents an investigation on the properties of two types of cement kiln dust (CKD)-stabilized dredged sediments, silt and clay with a comparison to hydrated lime stabilization. Unconfined compressive strength (UCS) and California bearing ratio (CBR) tests were conducted to examine the optimal stabilizer content and classify the type of highway material. A strength development model of treated dredged sediments was performed. The influences of various stabilizer types and sediment types on UCS were interpreted with the aid of microstructural observations, including X-ray diffraction and scanning electron microscopy analysis. The results of the tests revealed that 6% of lime by dry weight can be suggested as optimal content for the improvement of clay and silt as selected materials. For CKD-stabilized sediment as soil cement subbase material, the use of 8% CKD was suggested as optimal content for clay, whereas 6% CKD was recommended for silt; the overall CBR value agreed with the UCS test. The reaction products calcium silicate hydrate and ettringite are the controlling mechanisms for the mechanical performance of CKD-stabilized sediments, whereas calcium aluminate hydrate is the control for lime-stabilized sediments. These results will contribute to the use of CKD as a sustainable and novel stabilizer for lime in highway material applications.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.10a
• /
• pp.386-391
• /
• 1998

Recently, high performance concrete developed has a good quality at fresh and hardened state, but high binder contents results in spending much money on manufacturing and many cracks by drying and autogenous shrinkage. Therefore, in this paper, not only prevention of cracks caused by drying and autogenous shrinkage, but improvement of quality and accmplishment of economy by applying F.A(fly ash), S.F(silica fume) and CSA(calcium sulfa aluminate) expansive additives as an inorganic admixtures in W/B 35% are discussed. According to the experimental results, when 5% of CSA Expansive additives and 15:5 (F.A:S.F)are replaced at unit cement content, high performance concrete with both good compensation of drying and autogenous shrinkage at hardened state is accomplished.