• Journal of Community Nutrition
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• v.1 no.2
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• pp.88-97
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• 1999

The purpose of this study was to investigate the nutritional status of serum minerals, ceruloplasmin, and ferroxidase activity in female adolescent students according to their smoking status. The subjects were 87 non-smokers and 88 smokers, who were female high school students. The smokers were divided into tow groups by smoking status, 35 light smokers(pack-year<1) and 53 smokers(pack-year$\geq$1). The serum concentrations of 6 minerals were determined by ICP emission spectroanalyzer. The serum concentration of ceruloplasmin and ceruloplasmin ferroxidase activity were determined. All data were statistically analyzed by SAS PC package program. The serum minerals concentrations of all subjects were in a normal range. There were significantly differences in the concentrations of serum copper, zinc, magnesium, and phosphorus by smoking status while there were no significant differences in the concentrations of serum iron and manganese by smoking status. Furthermore there were no significant differences in the ceruloplasmin concentration and ferroxidase activity by smoking status. In conclusion, smoking status altered the serum levels of some minerals in healthy young women. The minerals levels in light smokers with relatively short pack-year(pack-year<1) were altered compared to those in non-smokers or smokers. This finding seemed to be consistent with the results of previously published data related to antioxidant vitamin and lipid peroxide levels. However further research is needed to clarify these findings in female adolescent smokers.

• The Journal of Engineering Geology
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• v.23 no.4
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• pp.399-407
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• 2013

Some groundwater in Korea contains high U concentrations, especially where two-mica granite occurs in the Daejeon area. The elemental U in the two-mica granite is lower than that in normal granites elsewhere in the world, and U-minerals have yet to be reported in the two-mica granite in the Daejeon area. This study focuses on investigating the occurrence of U-minerals serving as the U source in groundwater. In situ gamma ray spectrometry and mineralogical analyses using EPMA were performed. U-count anomalies were identified in a granitic dyke and in hydrothermally altered granite. Uraniferous granitic dykes occur along the contact zone between the two-mica granite and mica-schist. The uraniferous parts within the two-mica granite are developed in the hydrothermally altered zone, which contains numerous quartz veinlets within a fracture zone. Hydrothermal alteration is dominated by potassic and prophylitic alteration. Uraninite is a common U-mineral in granitic dykes and hydrothermally altered granite. Coffinite and uranophane occur in the hydrothermally altered granite. All of these U-minerals are commonly accompanied by hydrothermal alteration minerals such as muscovite, chlorite, epidote, and calcite. It is concluded that granitic dyke and hydrothermally altered granite are the main source rocks of U in groundwater.

• Economic and Environmental Geology
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• v.44 no.6
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• pp.463-474
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• 2011

The Haenam epithermal mineralized zone is located in the southwestern part of South Korea, and hosts low sulfidation epithermal Au-Ag deposit (Eunsan-Moisan) and clay quarries (Okmaesan, Seongsan, and Chunsan). Epithermal deposits and accompanying hydrothermal alteration related to Cretaceous volcanism caused large zoned assemblages of hydrothermal alteration minerals. Advanced argillic-altered rocks with mineral assemblages of alunite-quartz, alunite-dickite-quartz, and dickite-kaolinite-quartz exposed on the Okmaesan, Seongsan, and Chunsan area. Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), with three visible and near infrared bands, six shortwave infrared bands, and five thermal infrared bands, was used to identify advanced argillic-altered rocks within the Haenam epithermal mineralized zone. The distinct spectral features of hydrothermal minerals allow discrimination of advanced argillic-altered rocks from non-altered rocks within the study area. Because alunite, dickite, and kaolinite, consisting of advanced argillic-altered rocks within the study area are characterized by Al-O-H-bearing minerals, these acid hydrothermal minerals have a strong absorption feature at $2.20{\mu}m$. The band combination and band ratio transformation cause increasing differences of DN values between advanced argillic-altered rock and non-altered rock. The alunite and dickite-kaolinite of advanced argillic-altered rocks from the Okmaesan, Seongsan, and Chunsan have average DN values of 1.523 and 1.737, respectively. These values are much higher than those (1.211 and 1.308, respectively) of non-altered area. ASTER images can remotely provide the distribution of hydrothermal minerals on the surface. In this way good relation between ASTER spectra analysis and field data suggests that ASTER spectral analysis can be useful tool in the initial steps of mineral exploration.

• Economic and Environmental Geology
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• v.22 no.4
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• pp.315-326
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• 1989

The pottery stone diposits of the Cheongsong area consist of abundant quartz with clay minerals such as mica/smectite interstratified mineral, tosudite, kaolinite and sericite. The occurrence and mineralogical properties of the clay minerals were investigated by X-ray diffraction method, chemical analysis, DTA and IR. The mineral transformation by hydrothermal alteration was also discussed. Tosudite occurs in the Beopsoo pottery stone deposit, it seem to be Li-beraing tosudite. Mica/smectite interstratified minerals with less than about 20% expandable layers are commonly observed in the pottery stone deposits of the area. The mica/smectite interstratified minerals tend to increase the expandable layers as the progress of alteration. The pottery stones from this area seem to be altered from rhyolite or welded tuff by hydrothermal solution.

• 한국해양학회지
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• v.30 no.4
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• pp.271-278
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• 1995

A study of heavy mineral sands in terms of heavy mineral group and concentration has been carried out by analyzing 88 grab samples from the continental shelf off the southeast coast of Korea. Heavy mineral groups seem to be outlined and classified into four regions in the study area: 1) the western region; high concentrations of stable minerals, such as opaque mineral, magnetite, garnet and ZTR, 2) Korean Trough region; moderate concentrations of stable minerals, 3) the eastern region; abundant altered mineral and amphibole with minor of pyroxene concentration, and 4) the northeastern shelf-break region; low concentration of stable minerals with abundant altered minerals. The sedimentologic natures of four major heavy mineral regions (groupings) seem to be influenced by physical, dynamic and hydraulic milieu and also aerial and/or subaqueous weathering processes. It seems to be, further, plausible that shallow marine waves and currents associated with neritic dynamic condition of transgressive sea might be very effective on the concentration and groupings (sorting) of heavy min-erals in the surficial sediments of the continental shelf. The pyroxene-abundant heavy mineral suite (group), in fact, seems to suggest a sediment source from Japanese Islands.

• Economic and Environmental Geology
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• v.27 no.4
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• pp.387-396
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• 1994

Mineralogical and geochemical studies on gold-bearing quartz veins and wallrock from the Mugeug mine were carried out in order to investigate the variation of mineralogical composition and the geochemical behavior of elements with distance from the gold-bearing quartz veins. Gold-bearing quartz veins occur in early Cretaceous medium- to coarse-grained biotite granite. The unaltered wallrock is composed mainly of quartz, plagioclase, orthoclase, microcline, biotite and hornblende with accessory minerals of sphene and apatite. Mineralogical changes in altered wallrock around the gold-bearing quartz veins were observed as follows; 1) biotite and hornblende altered into chlorite, and next to sericite, 2) plagioclase, orthoclase and microcline altered into sericite, and 3) calcite and quartz introduced into wallrock. Contents of $K_2O$, Rb, Cs, Au, As and Sb in altered wallrock increase, whereas those of $Na_2O$, CaO, Ba, and Sr decrease with proximity to the gold-bearing quartz veins. The loss on ignition also increases with the increase of alteration mineral. The width of primary dispersion increases in order $Au=SiO_2<As=Cs=Rb<K_2O=Sb$ and $MnO<Na_2O=CaO=Ba<Sr$. The sericitization index, $K_2O/(K_2O+Na_2O)$, is an important indicator to interpret the degree of alteration at the Mugeug mine, which is more than 0.8 in strongly and moderately altered granite, 0.5~0.8 in wea altered granite, and less than 0.5 in unaltered granite. Alteration indices for major and trace elements, and the ratio of Rb/Sr are also useful to discriminate alteration zones.

• Journal of the Mineralogical Society of Korea
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• v.13 no.3
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• pp.121-137
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• 2000

Weathering profiles which were developed under a temperate, humid environment and relatively steep geography, show a thick saprolite and soil horiaon in the Precambrian granitic gneiss of the Yoogoo area. In the weathering profiles, secondary minerals such as interstratified biotite/vermiculite, tri- or di-octahedral vermiculite, halloysite, kaolinite, illite, smectite, gibsite and geothite were observed. Kaolinization of biotite is the most prevalent mechanism but vermiculitization is a minor from all ofweathering profiles. Biotite altered to B/V mixed layer-vermiculite, to illite and to halloysite, kaolinite and gibbsite. Halloysite is the most frequently observed weathering product of biotite in these profiles. Goethite is observed at the around or opened fissures of altered biotite. Tubular halloysite aggregates was fDrmed from dissolution-precipitation of plagioclase. The occurrence of halloysite aggregates is divided into a preferentially oriented type and a wrinkled one which were resulted from the dissolved type of plagioclase. Fe-bearing minerals have also been subjected to dissolution leaving the precipitation of geothite along dissolution voids. The profile of granitic gneiss is a typical weathering pattern showing a clay minerals increase toward the surface. Weathering of minerals were controlled by locally acidic and good-drainage environment, and formed a various and complicated secondary minerals in this study area.

• Economic and Environmental Geology
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• v.27 no.1
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• pp.1-9
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• 1994

The Kyungju pyrophyllite deposits were formed by the hydrothermal alteration of andesitic rocks, which were intruded by Cretaceous granite mass. The major minerals are pyrophyllite, kaolinite and chlorite. The deposits may be zoned outward into pyrophyllite zone, silicified pyrophyllite zone and weakly altered zone (propyrilite zone) according to mineral assemblages. Chemical compositions vary in close relation with the mineralogical assemblages: $Al_2O_3$ content is high due to pyrophyllitization at the deposits and altered zones in comparison to andesitic country rocks, while the contents of $Na_2O$, CaO and MgO are generally low due to leaching during the alteration. This variation of chemical elements may be applicable in the geochemical exploration of pyrophyllite deposits.

• Korean Journal of Mineralogy and Petrology
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• v.36 no.1
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• pp.1-17
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• 2023

On painting cultural properties to which Orpiment, a traditional yellow mineral pigment, is applied, the color's degeneration is frequently observed. To identify the cause of the degeneration, this study takes a look into orpiment and the various pigments that are mixed into it (Lead White, Lead Red, and Cinnabar) in powder and painting state. The pigment was mixed with Argyo glue and then applied to korean traditional paper and silk. Considering the possibility that alum causes the discoloration, it was applied to the specimen. With a UV tester, the powders and the painted specimens were subjected to a light resistance test in three phases (96 hour). Color changes were measured with a colorimeter and minerals, chemical composition and structural changes were analysed by XRD, SEM/EDS and Raman spectrometers. While the color change of pure Orpiment powder according to the light resistance test was small, the colored specimen became darker. The color change was large in the Orpiment colored on the silk and in the alum-treated specimen. In Orpiment powder was produced white arsenolite as altered orpiment after UV test. In the mixed powder of Orpiment and Lead White were detected only the constituent minerals of Orpiment and Lead White, and no altered substances were produced. Whereas after the UV test, orpiment and arsenolite, which were altered substances of orpiment, and the constituent minerals of Lead White were detected. In the case of mixing the two pigments in the powder state, darkening did not occur even by the UV test. However, the specimens colored with the mixed powder were darkened by the UV test. The color change of Orpiment was different depending on the mixed pigment and base material. The color change was greater in the case of alum treatment than in the case without alum treatment, and it was found that alum also had an influence on the color change of Orpiment.

• Journal of the Korean Ceramic Society
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• v.12 no.4
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• pp.3-8
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• 1975

Hydration processes of the rapid hardening cement clinkers, which were synthesized from domestic alunite for major alumina source, limestone, kaolin and fluorite, were investigated by means of x-ray diffraction analysis, thermal analysis and microscopic observation etc. The clinkers were composed mainly of alite, calcium fluroaluminate (C11A7.CaF2) minerals. While the hydratio processes of the clinkers are altered by concentration of SO3 in the paste, calcium aluminate hydrates such as C4AH13, CAH10 and calcium monosulfate hydrate (C3A.CaSO4.12H2O) are formed at first and then some of them are transformed into ettringite(C3A.3CaSO4.32H2O) within 30~60 min. when the concentration of SO3 in the paste are enough. However the formed ettringite are changed slowly into calcium monosulfate hydrate as the concentration of SO3 become lowered, and the paste is hardened with these close-packed minerals. When the content of SO3 in clinker is so enough, calcium sulfoaluminate hydrates are found without any addition of anhydrite or hemi-hydrite.