• Journal of the Korea Institute of Building Construction
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• v.10 no.5
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• pp.37-44
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• 2010

This study examined the practical application of ground granulated blast-furnace slag (GGBS) based alkali-activated (AA) binders for the development of cementless environmental-friendly secondary products of concrete, such as brick, shore protection blocks and interlocking blocks. The addition amount and type of alkaline ion to activate GGBS varied according to the diverse qualities of the secondary products of concrete required in Korean industrial standards (KS) and other specifications. Test results showed that the secondary products of concrete using GGBS-based AA binders surpassed the demanded capacities of KS and other specifications. In addition, shore protection block had a pH value close to neutral, enabling an advantageous environment for marine life. Therefore, the GGBS-based AA binders can be effectively applied to develop eco-friendly secondary products of concrete with reduced $CO_2$.

• Resources Recycling
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• v.28 no.1
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• pp.32-39
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• 2019

The present study investigated hydration of alkali activated slag incorporating sulfate as a form of anhydrite by employing thermodynamic modeling using the Gibbs free energy minimization approach. Various parameters were evaluated in the thermodynamic calculations, such as presence of sulfide, precipitation/dissolution of AFt/AFm phase, and the effect of oxic condition on the predicted reaction. The calculations suggested no significant difference in the void volume and chemical shrinkage, which might influence the performance of the mixtures, in spite of various changes of the parameters. Although the types of hydration products and their amount varied according to the input conditions, their variations were smaller range than that induced by water-to-binder ratio. Moreover, it did not affect the amount of C-(N-)A-S-H which was the most important hydration product.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.363-364
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• 2010

Recently, various researchers have studied alkali-activated concrete that do cementless as the binder. This study analyzed the effect on cementless mortar by flay ash and blast furnace slag of blast slag as the binder with no use of cement, by observing compressive strength and micro-structure.

• Resources Recycling
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• v.21 no.3
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• pp.28-38
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• 2012

The purpose of this paper is to develop the alkali-activated concrete which uses 100% fly ash as a binder without any cement. The compressive strength of the mortar was examined depending on the chemical change in alkali-activator through SEM and SEM/EDS observations and the XRD analysis. It was found from the test that the higher molar concentration induced the greater effect on the initial strength, and that $Si^{4+}$ and $Al^{3+}$ were eluted relative to the compressive strength of mortar. In addition, it was confirmed that Al and Si were determined to be most influential ingredients on the microstructural development of the mortar, and that the different ingredient of the activator was almost no change in solidity from the XRD analysis.

• Journal of the Korea Concrete Institute
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• v.25 no.6
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• pp.593-599
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• 2013

The unrestrained shrinkage strain of alkali-activated (AA) slag concrete was examined and compared with design equations specified in code provisions and empirical equations proposed by Yang et al. The main parameters investigated were the water-to-binder ratio (W/B), unit water content and fine aggregate-to-total aggregate ratio (S/a). Test results revealed that shrinkage strain of AA slag concrete is nearly proportional to the W/B ratio, whereas its time function is independent of the W/B ratio. The shrinkage strain of AA slag concrete increased significantly when the unit water content is above $185kg/m^3$, whereas it is marginally affected by the S/a ratio. The design equation of ACI 209 considerably overestimates the shrinkage behavior of AA slag concrete, whereas CEB-FIP equation tends to underestimate the shrinkage at the age more than 28 days. The empirical equation of Yang et al. is in better agreement with test results, showing that values of mean and standard deviation of error coefficients obtained from each specimen are 016 and 0.07, respectively.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.2
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• pp.117-125
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• 2014

This paper examines the fundamental properties of alkali-activated slag cement (AASC) activated by sodium hydroxide (NaOH). The water to binder (W/B) ratio was 0.4 and 0.5. And concentration of activator were 2M and 4M. Five mix design of each W/B ratios was considered. The N0 mixture was KS L 5109 method and N1~N4 were varied in different mixing time, mix step and entering points of fine aggregate. Test results clearly showed that the flow value, strength and drying shrinkage development of AASC were significantly dependent on the entering point of fine aggregate. The flow value tended to decreases with delaying entering point of fine aggregate. The compressive strength and flexural strength increases with delaying entering point. Moreover, the XRD analysis confirmed that there were sustain these results. The drying shrinkage increases with delaying entering point of fine aggregate. Futhermore, a modified mixing method incorporating all hereby experimentally derived parameters, is proposed to improvement the physical properties of AASC.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.05a
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• pp.96-97
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• 2015

In this search, by evaluating the field applicability of soil mixed pavement of Red mud is mixed into the soil mixed pavement field applicability, and tries to present the basic data about the site application of recycling of red mud and low carbon construction material to. As a result, the conventional soil concrete organization standards (SPS-KSCICO-001: 2003) meets the criteria for a bicycle road, making use of red mud, natural color as well as the natural loess is expressed.

• Advances in materials Research
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• v.4 no.1
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• pp.45-60
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• 2015

This paper aimed to investigate the effect of MWCNTs on properties of slag Geopolymeric mortar. Geopolymeric matrices containing different MWCNTs concentrations (0.0, 0.1, 0.2, 0.3 and 0.4 % by weight of the used binder) were synthesized. The Geopolymer mortar composed of aluminosilicate slag to sand (1:2), while the alumino silicate source binder composed of 50% air cooled slag and 50%water cooled slag both passing a sieve of $90{\mu}m$, while the sand passing a sieve of 1 ml. The materials prepared at water/binder ratios in a range of 0.34-0.39% depending on the added MWCNT, whereas the Gelenium Ace-30 superplasticizer used in the ratio of 1.4-2.2% from the total dry weight for better dispersion of MWCNT under sonication for 15 min. Alkaline activation of the Geopolymer mortar was carried by using of 6% NaOH. Curing was performed under temperature of $40^{\circ}C$ and 100% R.H. Results showed that the addition of MWCNTs enhanced the resulting amorphous geopolymer structure with marked decrease in the drying shrinkage as well as water absorption specially when using 0.1% MWCNT, while further increase in MWCNTs results in agglomeration in MWCNT within the matrix and so hinder the propagation of Geopolymerization reaction and negatively affect the formed geopolymer structure.

• Journal of the Korean Applied Science and Technology
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• v.30 no.3
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• pp.494-503
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• 2013

In this study, $CO_2$ adsorbent was produced for minimizing energy loss due to ventilation within the building. For improved selectivity about low concentration of $CO_2$ in multiple-use facilities, the ball type adsorbent was modified from a commercial zeolite, alumina, alkali metals and activated carbon with mixing LiOH, binder, and $H_2O$. We measured specific surface area, pore characteristic, and crystal structure of the modified adsorbent. Effects of alkalization on the absorptive properties of the adsorbents were investigated. Continuous column tests (2,000 ppm) and batch chamber tests ($4m^3$, 5,000ppm) showed that the modified adsorbent indicated about the selectivity of $CO_2$ more than 9.7% (0.613 mmol/g) compared with ordinary adsorbents and $CO_2$ removal efficiency of 88.8% within l hour, respectively. It was estimated that the modified adsorbent was applicable to indoor environments.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.1
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• pp.33-40
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• 2013

The cement industry brought very severe environment problems with massive carbon dioxide during its production. To solve this problem, attempts on Alkali-Activated Slag (AAS) concrete that perfectly substitutes industrial by-products such as ground granulated blast furnace slag (GGBFS) for cement are being actively made. AAS concrete is possible to have high strength development at room temperature, however, it is difficult to ensure the working time due to the fast setting time and the loss of workabillity because of the alkali reaction. In this study, the early age properties of alkali activated slag mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The water-binder ratio (W/B) was fixed at 0.35 and sodium hydroxide and waterglass as alkali activator was used. The compressive strength, the flow and the ultrasonic pulse velocity were measured according to the type of superplasticisers, which were naphthalene(N), lignin(L), melamine(M) and PC(P), up to a maximum of 2 percent by the mass of GGBFS. The results showed that adding melamine type of superplasticizer improved the fluidity of AAS mortar without decreasing the compressive strength, while naphthalene and polycarbonate type of superplasticizer had little effect on the fluidity of AAS mortar.